PMID- 30317382 OWN - NLM STAT- MEDLINE DCOM- 20181217 LR - 20181217 IS - 1432-0800 (Electronic) IS - 0007-4861 (Linking) VI - 101 IP - 5 DP - 2018 Nov TI - Simultaneous Determination of 32 Polycyclic Aromatic Hydrocarbon Derivatives and Parent PAHs Using Gas Chromatography-Mass Spectrometry: Application in Groundwater Screening. PG - 664-671 LID - 10.1007/s00128-018-2462-x [doi] AB - A simple, practical and precise method for the simultaneous analysis of 32 different polycyclic aromatic hydrocarbon (PAHs) including 16 parent PAHs, 8 oxygenated-PAHs (oxy-PAHs), 4 chloro-PAHs, and 4 nitrogen-containing heterocyclic PACs (N-PACs), in groundwater was established via gas chromatography-mass spectrometry (GC-MS) combined with liquid-liquid extraction (LLE). The obtained detection method possesses instrument detection limits (at a signal to noise of 3:1) in the range of 0.05-10 ng/mL and method detection limits in the range of 1.7-13.2 ng/L. The average recoveries of the 32 analytes were in the range of 54.3%-127.0% with relative standard deviations (RSDs) < 20%, and the recoveries of 16 PAH derivatives ranged from 54.3 to 115.1% with RSDs < 17.9%. The method has been successfully applied to the screening of 64 groundwater samples from eastern China. The results revealed that 30 types of targets including 16 PAHs and 14 PAH derivatives were detected and that the groundwater in most areas is slightly polluted, while the pollution of Jiangsu Province and Shandong Province was more serious. FAU - Zhu, Tao AU - Zhu T AD - National Research Center for Geoanalysis, Chinese Academy of Geological Sciences, Beijing, 100037, China. AD - Key Laboratory of Ecological Geochemistry, Ministry of Natural Resources, Beijing, 100037, China. FAU - Rao, Zhu AU - Rao Z AD - National Research Center for Geoanalysis, Chinese Academy of Geological Sciences, Beijing, 100037, China. raozhu@126.com. AD - Key Laboratory of Ecological Geochemistry, Ministry of Natural Resources, Beijing, 100037, China. raozhu@126.com. FAU - Guo, Feng AU - Guo F AD - National Research Center for Geoanalysis, Chinese Academy of Geological Sciences, Beijing, 100037, China. AD - Key Laboratory of Ecological Geochemistry, Ministry of Natural Resources, Beijing, 100037, China. FAU - Zhan, Nan AU - Zhan N AD - National Research Center for Geoanalysis, Chinese Academy of Geological Sciences, Beijing, 100037, China. AD - Key Laboratory of Ecological Geochemistry, Ministry of Natural Resources, Beijing, 100037, China. FAU - Wang, Yuan AU - Wang Y AD - School of Chemistry, The University of New South Wales, Sydney, 2052, Australia. FAU - Arandiyan, Hamidreza AU - Arandiyan H AD - Laboratory of Advanced Catalysis for Sustainability, School of Chemistry, The University of Sydney, Sydney, 2006, Australia. hamid.arandiyan@sydney.edu.au. FAU - Li, Xiao-Jie AU - Li XJ AD - China Building Material Test & Certification Group Co., Ltd., Beijing, 100024, China. LA - eng GR - DD20189627/China Geological Survey (CN)/ GR - DD20160312/China Geological Survey (CN)/ GR - 121201105000182401/China Geological Survey (CN)/ PT - Journal Article DEP - 20181013 PL - United States TA - Bull Environ Contam Toxicol JT - Bulletin of environmental contamination and toxicology JID - 0046021 RN - 0 (Environmental Pollutants) RN - 0 (Polycyclic Aromatic Hydrocarbons) SB - IM MH - China MH - Environmental Pollutants/*analysis MH - Gas Chromatography-Mass Spectrometry/*methods MH - Groundwater/analysis MH - Limit of Detection MH - Liquid-Liquid Extraction MH - Polycyclic Aromatic Hydrocarbons/*analysis OTO - NOTNLM OT - Aromatic hydrocarbon derivatives OT - GC-MS OT - Groundwater OT - Liquid-liquid extraction OT - Polycyclic EDAT- 2018/10/15 06:00 MHDA- 2018/12/18 06:00 CRDT- 2018/10/15 06:00 PHST- 2018/06/03 00:00 [received] PHST- 2018/10/03 00:00 [accepted] PHST- 2018/10/15 06:00 [pubmed] PHST- 2018/12/18 06:00 [medline] PHST- 2018/10/15 06:00 [entrez] AID - 10.1007/s00128-018-2462-x [pii] AID - 10.1007/s00128-018-2462-x [doi] PST - ppublish SO - Bull Environ Contam Toxicol. 2018 Nov;101(5):664-671. doi: 10.1007/s00128-018-2462-x. Epub 2018 Oct 13.