PMID- 30343481
OWN - NLM
STAT- MEDLINE
DCOM- 20191118
LR  - 20191118
IS  - 1559-0720 (Electronic)
IS  - 0163-4984 (Linking)
VI  - 190
IP  - 1
DP  - 2019 Jul
TI  - Simultaneous Functionalization and Reduction of Magnetic Graphene Oxide by 
      L-Histidine and its Application for Magnetic Separation/Preconcentration of 
      Antioxidant Trace Elements.
PG  - 262-272
LID - 10.1007/s12011-018-1545-1 [doi]
AB  - In the present study, for the first time, the magnetic graphene oxide was 
      simultaneously functionalized and reduced with the aim of imidazole-based 
      L-histidine amino acid (rGO/Fe(3)O(4)-histidine). The prepared nanocomposite was 
      characterized by field emission scanning electron microscopy, energy dispersive 
      X-ray spectroscopy, Raman spectroscopy, and vibrating sample magnetometer. The 
      synthesized rGO/Fe(3)O(4)-histidine nanosheets were implied for solid phase 
      extraction of ultra-trace amounts of Zn(2+), Cu(2+)(,) and Mn(2+) from biological 
      samples prior to ICP-OES determination. The calibration curves were linear in the 
      concentration ranges of 0.4-182.0, 0.4-215.0, and 0.2-168.5 mug L(-1) for Zn(2+), 
      Cu(2+), and Mn(2+), respectively. The limits of detection were 0.12, 0.10, and 
      0.04 mug L(-1) for Zn(2+), Cu(2+), and Mn(2+), respectively. The relative standard 
      deviations (RSDs) at 50.0 mug L(-1) for single-sorbent repeatability and 
      sorbent-to-sorbent reproducibility were less than 6.7 and 9.2% (n = 5), 
      respectively. The accuracy of the method was confirmed by the analysis of a serum 
      quality control material (QCM, Seronorm Human Serum REF NO 203105) and hair 
      certified reference material (CRM, Human Hair IAEA-086).
FAU - Amiri, Mojtaba
AU  - Amiri M
AD  - Department of Chemistry, Yazd University, Safaieh, Yazd, 89195-741, Iran.
FAU - Shabani, Ali Mohammad Haji
AU  - Shabani AMH
AD  - Department of Chemistry, Yazd University, Safaieh, Yazd, 89195-741, Iran. 
      hshabani@yazd.ac.ir.
FAU - Dadfarnia, Shayessteh
AU  - Dadfarnia S
AD  - Department of Chemistry, Yazd University, Safaieh, Yazd, 89195-741, Iran. 
      sdadfarnia@yazd.ac.ir.
FAU - Sadjadi, Sodeh
AU  - Sadjadi S
AD  - Material and Nuclear Fuel Cycle School, Nuclear Science and Technology Research 
      Institute, Tehran, Iran.
LA  - eng
PT  - Journal Article
DEP - 20181020
PL  - United States
TA  - Biol Trace Elem Res
JT  - Biological trace element research
JID - 7911509
RN  - 0 (Antioxidants)
RN  - 0 (Trace Elements)
RN  - 0 (graphene oxide)
RN  - 42Z2K6ZL8P (Manganese)
RN  - 4QD397987E (Histidine)
RN  - 7782-42-5 (Graphite)
RN  - 789U1901C5 (Copper)
RN  - J41CSQ7QDS (Zinc)
SB  - IM
MH  - Antioxidants/*chemistry
MH  - Copper/chemistry
MH  - Graphite/*chemistry
MH  - Histidine/*chemistry
MH  - Manganese/chemistry
MH  - Solid Phase Extraction
MH  - Spectrometry, X-Ray Emission
MH  - Spectrum Analysis, Raman
MH  - Trace Elements/*chemistry
MH  - Zinc/chemistry
OTO - NOTNLM
OT  - Antioxidant trace elements
OT  - Functionalized graphene oxide
OT  - L-Histidine
OT  - Magnetic solid phase extraction
EDAT- 2018/10/22 06:00
MHDA- 2019/11/19 06:00
CRDT- 2018/10/22 06:00
PHST- 2018/08/19 00:00 [received]
PHST- 2018/10/08 00:00 [accepted]
PHST- 2018/10/22 06:00 [pubmed]
PHST- 2019/11/19 06:00 [medline]
PHST- 2018/10/22 06:00 [entrez]
AID - 10.1007/s12011-018-1545-1 [pii]
AID - 10.1007/s12011-018-1545-1 [doi]
PST - ppublish
SO  - Biol Trace Elem Res. 2019 Jul;190(1):262-272. doi: 10.1007/s12011-018-1545-1. 
      Epub 2018 Oct 20.