PMID- 30347142
OWN - NLM
STAT- MEDLINE
DCOM- 20190917
LR  - 20231213
IS  - 1520-5851 (Electronic)
IS  - 0013-936X (Linking)
VI  - 52
IP  - 22
DP  - 2018 Nov 20
TI  - Selective Uptake of Third-Hand Tobacco Smoke Components to Inorganic and Organic 
      Aerosol Particles.
PG  - 13195-13201
LID - 10.1021/acs.est.8b03880 [doi]
AB  - Third-hand smoke (THS) is an emerging route of exposure to tobacco smoke in the 
      indoor environment. Few studies have investigated the chemical behavior of THS, 
      although initial findings suggest that semivolatile components of THS can 
      partition to indoor aerosol. By exposing single-component particles to THS in an 
      environmental chamber, this study demonstrates a pronounced dependence of THS 
      uptake on aerosol composition. First, it was found that primarily reduced 
      nitrogen compounds (that produced C (x)H (y)N (z)(+) ion signal) in THS 
      partitioned strongly to acidic ammoniated sulfate particles, whereas overall THS 
      uptake to more pH-neutral sodium sulfate particles was minimal. Second, THS 
      uptake to pure hydrocarbon particles (squalane) was even greater than to 
      ammoniated sulfate particles with the uptake arising from mainly C (x)H (y) 
      compounds. The greater uptake of THS to squalane was mostly driven by the 
      dominant fraction of C (x)H (y) compounds in the side stream cigarette smoke 
      aerosol, the composition of which is likely to be broadly similar to THS in these 
      experiments. Third, oxygenated organic particles (sucrose) and solid ammonium 
      sulfate particles showed minimal uptake. These results indicate that particulate 
      THS inhalation exposure will be strongly dependent on the chemical nature of the 
      particles present in the indoor environment.
FAU - Collins, Douglas B
AU  - Collins DB
AUID- ORCID: 0000-0002-6248-9644
AD  - Department of Chemistry , University of Toronto ; 80 St. George Street , Toronto 
      , ON M5S 3H6 , Canada.
FAU - Wang, Chen
AU  - Wang C
AUID- ORCID: 0000-0001-9565-8777
AD  - Department of Chemistry , University of Toronto ; 80 St. George Street , Toronto 
      , ON M5S 3H6 , Canada.
FAU - Abbatt, Jonathan P D
AU  - Abbatt JPD
AUID- ORCID: 0000-0002-3372-334X
AD  - Department of Chemistry , University of Toronto ; 80 St. George Street , Toronto 
      , ON M5S 3H6 , Canada.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20181031
PL  - United States
TA  - Environ Sci Technol
JT  - Environmental science & technology
JID - 0213155
RN  - 0 (Aerosols)
RN  - 0 (Smoke)
RN  - 0 (Tobacco Smoke Pollution)
SB  - IM
MH  - Aerosols
MH  - Inhalation Exposure
MH  - Smoke
MH  - Nicotiana
MH  - *Tobacco Smoke Pollution
EDAT- 2018/10/23 06:00
MHDA- 2019/09/19 06:00
CRDT- 2018/10/23 06:00
PHST- 2018/10/23 06:00 [pubmed]
PHST- 2019/09/19 06:00 [medline]
PHST- 2018/10/23 06:00 [entrez]
AID - 10.1021/acs.est.8b03880 [doi]
PST - ppublish
SO  - Environ Sci Technol. 2018 Nov 20;52(22):13195-13201. doi: 
      10.1021/acs.est.8b03880. Epub 2018 Oct 31.