PMID- 30378379
OWN - NLM
STAT- MEDLINE
DCOM- 20181126
LR  - 20181126
IS  - 1872-2059 (Electronic)
IS  - 1000-8713 (Linking)
VI  - 36
IP  - 11
DP  - 2018 Nov 1
TI  - [Simultaneous determination of 28 corticosteroids in surface water by ultra-high 
      performance liquid chromatography-electrospray tandem mass spectrometry].
PG  - 1158-1166
LID - 10.3724/SP.J.1123.2018.06010 [doi]
AB  - A comprehensive analytical method was developed for simultaneous determination of 
      28 corticosteroids in surface water based on ultra-high performance liquid 
      chromatography- electrospray tandem mass spectrometry (UHPLC-ESI-MS/MS). The 
      solid-phase extraction was performed using hydrophilic-lipophilic balance (HLB) 
      cartridges, and the chromatographic separation was achieved on a reversed-phase 
      C8 column. Qualitative and quantitative analyses were performed in the dynamic 
      multiple reaction monitoring (DMRM) mode using positive and negative electrospray 
      ionization (ESI+/-). The 28 target compounds were quantified by the internal 
      standard method. Good linear relationships were obtained (R(2)>0.99) for the 28 
      analytes in the concentration range of 1.0-100 mug/L. The method limits of 
      detection and quantification were in the range of 0.21-0.48 ng/L and 0.32-0.72 
      ng/L, respectively. When the matrix spiking levels were at 5.0, 10, and 50 ng/L, 
      the average recoveries for the target compounds ranged from 68.6% to 108.7%, and 
      the relative standard deviations (RSDs) were between 0.1% and 8.1%. Because of 
      its high sensitivity, good precision, and reliability, this method can be widely 
      applied to trace monitoring of glucocorticoids and mineral ocorticoids for 
      investigating their behaviors and risks of corticosteroids in the environment.
FAU - Gong, Jian
AU  - Gong J
AD  - School of Environmental Science and Engineering, Guangzhou University, Key 
      Laboratory for Water Quality and Conservation of the Pearl River Delta, Ministry 
      of Education, Guangdong Provincial Key Laboratory of Radionuclides Pollution 
      Control and Resources, Guangzhou 510006, China.
FAU - Lin, Canyuan
AU  - Lin C
AD  - School of Environmental Science and Engineering, Guangzhou University, Key 
      Laboratory for Water Quality and Conservation of the Pearl River Delta, Ministry 
      of Education, Guangdong Provincial Key Laboratory of Radionuclides Pollution 
      Control and Resources, Guangzhou 510006, China.
FAU - Xiong, Xiaoping
AU  - Xiong X
AD  - School of Environmental Science and Engineering, Guangzhou University, Key 
      Laboratory for Water Quality and Conservation of the Pearl River Delta, Ministry 
      of Education, Guangdong Provincial Key Laboratory of Radionuclides Pollution 
      Control and Resources, Guangzhou 510006, China.
FAU - Chen, Diyun
AU  - Chen D
AD  - School of Environmental Science and Engineering, Guangzhou University, Key 
      Laboratory for Water Quality and Conservation of the Pearl River Delta, Ministry 
      of Education, Guangdong Provincial Key Laboratory of Radionuclides Pollution 
      Control and Resources, Guangzhou 510006, China.
FAU - Chen, Yongheng
AU  - Chen Y
AD  - School of Environmental Science and Engineering, Guangzhou University, Key 
      Laboratory for Water Quality and Conservation of the Pearl River Delta, Ministry 
      of Education, Guangdong Provincial Key Laboratory of Radionuclides Pollution 
      Control and Resources, Guangzhou 510006, China.
FAU - Wu, Cuiqin
AU  - Wu C
AD  - School of Environmental Science and Engineering, Guangzhou University, Key 
      Laboratory for Water Quality and Conservation of the Pearl River Delta, Ministry 
      of Education, Guangdong Provincial Key Laboratory of Radionuclides Pollution 
      Control and Resources, Guangzhou 510006, China.
LA  - chi
PT  - Journal Article
PL  - China
TA  - Se Pu
JT  - Se pu = Chinese journal of chromatography
JID - 9424804
RN  - 0 (Glucocorticoids)
RN  - 0 (Water Pollutants, Chemical)
RN  - 059QF0KO0R (Water)
SB  - IM
MH  - Chromatography, High Pressure Liquid
MH  - Glucocorticoids/*analysis
MH  - Reproducibility of Results
MH  - Solid Phase Extraction
MH  - Spectrometry, Mass, Electrospray Ionization
MH  - Tandem Mass Spectrometry
MH  - Water/*analysis
MH  - Water Pollutants, Chemical/*analysis
OTO - NOTNLM
OT  - corticosteroids
OT  - surface water
OT  - ultra-high performance liquid chromatography-tandem mass spectrometry 
      (UHPLC-MS/MS)
EDAT- 2018/11/01 06:00
MHDA- 2018/11/27 06:00
CRDT- 2018/11/01 06:00
PHST- 2018/11/01 06:00 [entrez]
PHST- 2018/11/01 06:00 [pubmed]
PHST- 2018/11/27 06:00 [medline]
AID - 10.3724/SP.J.1123.2018.06010 [doi]
PST - ppublish
SO  - Se Pu. 2018 Nov 1;36(11):1158-1166. doi: 10.3724/SP.J.1123.2018.06010.