PMID- 30425984 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20240403 IS - 2296-2646 (Print) IS - 2296-2646 (Electronic) IS - 2296-2646 (Linking) VI - 6 DP - 2018 TI - SUNSPACE, A Porous Material to Reduce Air Particulate Matter (PM). PG - 534 LID - 10.3389/fchem.2018.00534 [doi] LID - 534 AB - The World Health Organization reports that every year several million people die prematurely due to air pollution. Poor air quality is a by-product of unsustainable policies in transportation, energy, industry, and waste management in the world's most crowded cities. Particulate matter (PM) is one of the major element of polluted air. PM can be composed by organic and inorganic species. In particular, heavy metals present in PM include, lead (Pb), mercury (Hg), cadmium, (Cd), zinc (Zn), nickel (Ni), arsenic (As), and molybdenum (Mo). Currently, vegetation is the only existing sustainable method to reduce anthropogenic PM concentrations in urban environments. In particular, the PM-retention ability of vegetation depends on the surface properties, related to the plant species, leaf and branch density, and leaf micromorphology. In this work, a new hybrid material called SUNSPACE (SUstaiNable materials Synthesized from by-Products and Alginates for Clean air and better Environment) is proposed for air PM entrapment. Candle burning tests are performed to compare SUNSPACE with Hedera Helix L. leafs with respect to their efficacy of reducing coarse and fine PM. The temporal variation of PM(10) and PM(2.5) in presence of the trapping materials, shows that Hedera Helix L. surface saturates more rapidly. In addition, the capability of SUNSPACE in ultrafine PM trapping is also demonstrated by using titanium dioxide nanoparticles with 25 nm diameter. Scanning electron microscope (SEM) and Transmission electron microscope (TEM) images of SUNSPACE after entrapment tests highlight the presence of collected nanoparticles until to about 0.04 mm in depth from the sample surface. N(2) physisorption measurements allow to demonstrate the possibility to SUNSPACE regeneration by washing. FAU - Zanoletti, Alessandra AU - Zanoletti A AD - INSTM and Department of Mechanical and Industrial Engineering, University of Brescia, Brescia, Italy. FAU - Bilo, Fabjola AU - Bilo F AD - INSTM and Department of Mechanical and Industrial Engineering, University of Brescia, Brescia, Italy. FAU - Borgese, Laura AU - Borgese L AD - INSTM and Department of Mechanical and Industrial Engineering, University of Brescia, Brescia, Italy. FAU - Depero, Laura E AU - Depero LE AD - INSTM and Department of Mechanical and Industrial Engineering, University of Brescia, Brescia, Italy. FAU - Fahimi, Ario AU - Fahimi A AD - INSTM and Department of Mechanical and Industrial Engineering, University of Brescia, Brescia, Italy. FAU - Ponti, Jessica AU - Ponti J AD - European Commission, Directorate General Joint Research Centre, Directorate F-Health, Consumers and Reference Materials, Consumer Products Safety Unit (F.2), Ispra, Italy. FAU - Valsesia, Andrea AU - Valsesia A AD - European Commission, Directorate General Joint Research Centre, Directorate F-Health, Consumers and Reference Materials, Consumer Products Safety Unit (F.2), Ispra, Italy. FAU - La Spina, Rita AU - La Spina R AD - European Commission, Directorate General Joint Research Centre, Directorate F-Health, Consumers and Reference Materials, Consumer Products Safety Unit (F.2), Ispra, Italy. FAU - Montini, Tiziano AU - Montini T AD - Department of Chemical and Pharmaceutical Sciences, CNR-ICCOM URT and INSTM Trieste Research Unit, University of Trieste, Trieste, Italy. FAU - Bontempi, Elza AU - Bontempi E AD - INSTM and Department of Mechanical and Industrial Engineering, University of Brescia, Brescia, Italy. LA - eng PT - Journal Article DEP - 20181030 PL - Switzerland TA - Front Chem JT - Frontiers in chemistry JID - 101627988 PMC - PMC6219005 OTO - NOTNLM OT - SUNSPACE OT - air particulate matter (PM) capture OT - azure chemistry OT - leaf OT - nanoparticles OT - porous material EDAT- 2018/11/15 06:00 MHDA- 2018/11/15 06:01 PMCR- 2018/01/01 CRDT- 2018/11/15 06:00 PHST- 2018/06/26 00:00 [received] PHST- 2018/10/12 00:00 [accepted] PHST- 2018/11/15 06:00 [entrez] PHST- 2018/11/15 06:00 [pubmed] PHST- 2018/11/15 06:01 [medline] PHST- 2018/01/01 00:00 [pmc-release] AID - 10.3389/fchem.2018.00534 [doi] PST - epublish SO - Front Chem. 2018 Oct 30;6:534. doi: 10.3389/fchem.2018.00534. eCollection 2018.