PMID- 30446126
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20181119
LR  - 20181119
IS  - 1879-1344 (Electronic)
IS  - 0144-8617 (Linking)
VI  - 205
DP  - 2019 Feb 1
TI  - Hydrophobization of chitosan films by surface grafting with fluorinated polymer 
      brushes.
PG  - 437-446
LID - S0144-8617(18)31233-5 [pii]
LID - 10.1016/j.carbpol.2018.10.044 [doi]
AB  - Chitosan with its surface-properties and biodegradability is a promising 
      biomaterial for green packaging applications. Till now, this application is still 
      limited due to chitosan high sensitivity to water. Some existing studies deal 
      with the incorporation of hydrophobic additives to enhance water-proof 
      performances of chitosan films. As these additives may impair the film 
      properties, our study focuses on chitosan efficient hydrophobization by means of 
      simple and successful surface grafting reactions. Chitosan films prepared by 
      solvent casting were modified by means of surface-initiated activators 
      regenerated by electron transfer atom radical polymerization (SI-ARGET-ATRP) of 
      2-hydroxyethyl methacrylate (HEMA) followed by esterification reaction with 
      fluorinated acyl compound. X-ray photoelectron spectroscopy (XPS), attenuated 
      total reflection Fourier transform infrared spectroscopy (ATR-FTIR) and 
      Time-of-Flight Secondary Ion Mass Spectroscopy (ToF-SIMS) highlighted the surface 
      chemical changes after each step. Surface properties were investigated by contact 
      angle measurements and surface energy calculations. Hydrophobic surfaces with low 
      surface energy and good water-repellent properties were obtained using a simple 
      handling polymerization procedure. This is the first study in applying ARGET ATRP 
      to prepare hydrophobic biopolymer films offering potential applications in 
      packaging.
CI  - Copyright (c) 2018 Elsevier Ltd. All rights reserved.
FAU - Lepoittevin, Benedicte
AU  - Lepoittevin B
AD  - Institut de Chimie Moleculaire et des Materiaux d'Orsay (ICMMO) UMR 8182, Univ 
      Paris Sud, CNRS, Universite Paris-Saclay, 91405, Orsay, France; Normandy 
      University, LCMT, UMR 6507, ENSICAEN, UNICAEN, CNRS, 14000, Caen, France. 
      Electronic address: benedicte.lepoittevin@ensicaen.fr.
FAU - Elzein, Tamara
AU  - Elzein T
AD  - Lebanese Atomic Energy Commission, National Council for Scientific Research, 
      CNRS-L, Beirut, Lebanon.
FAU - Dragoe, Diana
AU  - Dragoe D
AD  - Institut de Chimie Moleculaire et des Materiaux d'Orsay (ICMMO) UMR 8182, Univ 
      Paris Sud, CNRS, Universite Paris-Saclay, 91405, Orsay, France.
FAU - Bejjani, Alice
AU  - Bejjani A
AD  - Lebanese Atomic Energy Commission, National Council for Scientific Research, 
      CNRS-L, Beirut, Lebanon.
FAU - Lemee, Frederic
AU  - Lemee F
AD  - Normandy University, LCMT, UMR 6507, ENSICAEN, UNICAEN, CNRS, 14000, Caen, 
      France.
FAU - Levillain, Jocelyne
AU  - Levillain J
AD  - Normandy University, LCMT, UMR 6507, ENSICAEN, UNICAEN, CNRS, 14000, Caen, 
      France.
FAU - Bazin, Philippe
AU  - Bazin P
AD  - Normandy University, LCS, UMR 6506, ENSICAEN, UNICAEN, CNRS, 14000, Caen, France.
FAU - Roger, Philippe
AU  - Roger P
AD  - Institut de Chimie Moleculaire et des Materiaux d'Orsay (ICMMO) UMR 8182, Univ 
      Paris Sud, CNRS, Universite Paris-Saclay, 91405, Orsay, France.
FAU - Dez, Isabelle
AU  - Dez I
AD  - Normandy University, LCMT, UMR 6507, ENSICAEN, UNICAEN, CNRS, 14000, Caen, 
      France. Electronic address: isabelle.dez@ensicaen.fr.
LA  - eng
PT  - Journal Article
DEP - 20181018
PL  - England
TA  - Carbohydr Polym
JT  - Carbohydrate polymers
JID - 8307156
OTO - NOTNLM
OT  - Chitosan
OT  - Fluoropolymers
OT  - Polymer brush
OT  - Surface-initiated ARGET-ATRP
OT  - ToF-SIMS
EDAT- 2018/11/18 06:00
MHDA- 2018/11/18 06:01
CRDT- 2018/11/18 06:00
PHST- 2018/07/23 00:00 [received]
PHST- 2018/10/12 00:00 [revised]
PHST- 2018/10/14 00:00 [accepted]
PHST- 2018/11/18 06:00 [entrez]
PHST- 2018/11/18 06:00 [pubmed]
PHST- 2018/11/18 06:01 [medline]
AID - S0144-8617(18)31233-5 [pii]
AID - 10.1016/j.carbpol.2018.10.044 [doi]
PST - ppublish
SO  - Carbohydr Polym. 2019 Feb 1;205:437-446. doi: 10.1016/j.carbpol.2018.10.044. Epub 
      2018 Oct 18.