PMID- 30539399 OWN - NLM STAT- MEDLINE DCOM- 20190318 LR - 20200225 IS - 1614-7499 (Electronic) IS - 0944-1344 (Linking) VI - 26 IP - 4 DP - 2019 Feb TI - Preparation of chitosan/Co-Fe-layered double hydroxides and its performance for removing 2,4-dichlorophenol. PG - 3814-3822 LID - 10.1007/s11356-018-3886-x [doi] AB - Chitosan/Co-Fe-layered double hydroxides (CS/LDHs) were prepared by coprecipitation method, which is a kind of composite material with excellent properties. The structure of CS/LDHs was characterized by SEM, FTIR, and XRD, which proved that chitosan (CS) was successfully induced into hydrotalcite and CS/LDHs still possess the structural characteristics of hydrotalcite. The adsorption of 2,4-dichlorophenol (2,4-DCP) was studied with CS/LDHs and LDHs as adsorbent separately. The activity of immobilized laccase (L-CS/LDHs) with CS/LDHs as carrier is significantly better than that of the one (L-LDHs) using LDHs as carrier. Under the optimum conditions (pH = 6, 55 degrees C, 48 h), L-CS/LDHs exhibited better removal performance for 2,4-DCP (81.53%, 100 mg/L) than LDHs (63.55%); the removal of 2,4-DCP by L-CS/LDHs is excellent, exceeding 97% as its initial concentration below 60 mg/L. It includes the catalytic action of laccase and dechlorination of Fe(3+) and Co(2+), and the adsorption can be ignored under the optimal conditions. After 5 cycles, it maintained 67% (L-CS/LDHs) and 54% (L-LDHs) of the original removal. FAU - Yang, Bo AU - Yang B AD - College of Environment and Safety Engineering, Qingdao University of Science & Technology, Qingdao, 266042, Shandong, China. yangbo16@126.com. FAU - Liu, Jun AU - Liu J AD - College of Environment and Safety Engineering, Qingdao University of Science & Technology, Qingdao, 266042, Shandong, China. FAU - Liu, Zhiguo AU - Liu Z AD - College of Environment and Safety Engineering, Qingdao University of Science & Technology, Qingdao, 266042, Shandong, China. FAU - Wang, Yacheng AU - Wang Y AD - College of Environment and Safety Engineering, Qingdao University of Science & Technology, Qingdao, 266042, Shandong, China. FAU - Cai, Jiaming AU - Cai J AD - College of Environment and Safety Engineering, Qingdao University of Science & Technology, Qingdao, 266042, Shandong, China. FAU - Peng, Lingjie AU - Peng L AD - College of Environment and Safety Engineering, Qingdao University of Science & Technology, Qingdao, 266042, Shandong, China. LA - eng PT - Journal Article DEP - 20181211 PL - Germany TA - Environ Sci Pollut Res Int JT - Environmental science and pollution research international JID - 9441769 RN - 0 (Chlorophenols) RN - 0 (Environmental Pollutants) RN - 0 (Enzymes, Immobilized) RN - 17432CG1KU (hydrotalcite) RN - 3G0H8C9362 (Cobalt) RN - 5QB0T2IUN0 (Aluminum Hydroxide) RN - 9012-76-4 (Chitosan) RN - E1UOL152H7 (Iron) RN - EC 1.10.3.2 (Laccase) RN - NBZ3QY004S (Magnesium Hydroxide) RN - R669TG1950 (2,4-dichlorophenol) SB - IM MH - Adsorption MH - Aluminum Hydroxide/*chemistry MH - Chitosan/*chemistry MH - Chlorophenols/*analysis MH - Cobalt/*chemistry MH - Environmental Pollutants/*analysis MH - Enzymes, Immobilized/chemistry MH - Iron/*chemistry MH - Laccase/chemistry MH - Magnesium Hydroxide/*chemistry OTO - NOTNLM OT - 2,4-DCP OT - Chitosan/Co-Fe-layered double hydroxides OT - Immobilization OT - Laccase EDAT- 2018/12/13 06:00 MHDA- 2019/03/19 06:00 CRDT- 2018/12/13 06:00 PHST- 2018/09/14 00:00 [received] PHST- 2018/11/27 00:00 [accepted] PHST- 2018/12/13 06:00 [pubmed] PHST- 2019/03/19 06:00 [medline] PHST- 2018/12/13 06:00 [entrez] AID - 10.1007/s11356-018-3886-x [pii] AID - 10.1007/s11356-018-3886-x [doi] PST - ppublish SO - Environ Sci Pollut Res Int. 2019 Feb;26(4):3814-3822. doi: 10.1007/s11356-018-3886-x. Epub 2018 Dec 11.