PMID- 30609486
OWN - NLM
STAT- MEDLINE
DCOM- 20190213
LR  - 20190215
IS  - 1879-1298 (Electronic)
IS  - 0045-6535 (Linking)
VI  - 218
DP  - 2019 Mar
TI  - Activation of peroxymonosulfate by magnetic carbon supported Prussian blue 
      nanocomposite for the degradation of organic contaminants with singlet oxygen and 
      superoxide radicals.
PG  - 1071-1081
LID - S0045-6535(18)32304-X [pii]
LID - 10.1016/j.chemosphere.2018.11.197 [doi]
AB  - In order to develop efficient and green catalyst for organic pollutants removal, 
      magnetic carbon supported Prussian blue nanocomposite Fe(3)O(4)@C/PB was prepared 
      for the first time. The performance of Fe(3)O(4)@C/PB in activating 
      peroxymonosulfate (PMS) for the degradation of 2,4-dichlorophenol (2,4-DCP) was 
      investigated. 2,4-DCP could be effectively degraded under the 
      "Fe(3)O(4)@C/PB + PMS" system within a broad pH range of 2-9. Without pH 
      adjustment (pH 3), 2,4-DCP (20 mg/L) was completely degraded in 50 min along with 
      a 70% removal of TOC; while the required time for complete degradation of 2,4-DCP 
      was shortened to 40 min under initial solution pH at 7. Fe(3)O(4)@C/PB could also 
      activate PMS for the degradation of phenol, Acid Orange II, Reactive brilliant 
      red X-3B, Rhodamine B and Methylene blue. The degradation rates higher than 95% 
      could be achieved for all these contaminants within the time scale of 15-60 min. 
      The studies of radical-quenching and electron paramagnetic resonance demonstrated 
      that singlet oxygen ((1)O(2)) and superoxide radicals (O(2)(-)), rather than 
      sulfate (SO(4)(-)) and hydroxyl (OH) radicals, were the dominant species 
      responsible for the oxidation of organic pollutants. The plausible mechanism of 
      the catalytic degradation was proposed and the enhanced activity of 
      Fe(3)O(4)@C/PB was assumed to be related to the increased electron transfer owing 
      to the synergic effect between the magnetic carbon and the mixed-valence units in 
      PB. Fe(3)O(4)@C/PB is promising in wastewater treatment owing to its high 
      efficiency, excellent stability and reusability, environmental friendliness and 
      magnetic separability.
CI  - Copyright (c) 2018 Elsevier Ltd. All rights reserved.
FAU - Guo, Furong
AU  - Guo F
AD  - School of Chemistry and Chemical Engineering, Wuhan Textile University, Wuhan, 
      430200, China.
FAU - Wang, Kangjie
AU  - Wang K
AD  - School of Chemistry and Chemical Engineering, Wuhan Textile University, Wuhan, 
      430200, China.
FAU - Lu, Jiahua
AU  - Lu J
AD  - School of Chemistry and Chemical Engineering, Wuhan Textile University, Wuhan, 
      430200, China.
FAU - Chen, Jichong
AU  - Chen J
AD  - School of Chemistry and Chemical Engineering, Wuhan Textile University, Wuhan, 
      430200, China.
FAU - Dong, Xiongwei
AU  - Dong X
AD  - Engineering Research Centre for Cleaner Production of Textile Printing and 
      Dyeing, Ministry of Education, Wuhan, 430200, China.
FAU - Xia, Dongsheng
AU  - Xia D
AD  - Engineering Research Centre for Cleaner Production of Textile Printing and 
      Dyeing, Ministry of Education, Wuhan, 430200, China. Electronic address: 
      dongsheng_xia@wtu.edu.cn.
FAU - Zhang, Aiqing
AU  - Zhang A
AD  - Key Laboratory of Catalysis and Materials Sciences of the State Ethnic Affairs 
      Commission & Ministry of Education, South-Central University for Nationalities, 
      Wuhan, 430073, China.
FAU - Wang, Qiang
AU  - Wang Q
AD  - School of Chemistry and Chemical Engineering, Wuhan Textile University, Wuhan, 
      430200, China; Engineering Research Centre for Cleaner Production of Textile 
      Printing and Dyeing, Ministry of Education, Wuhan, 430200, China; Hubei Key 
      Laboratory of Biomass Fibers and Eco-dyeing & Finishing, Wuhan Textile 
      University, Wuhan, 430200, China. Electronic address: wangqche@hotmail.com.
LA  - eng
PT  - Journal Article
DEP - 20181129
PL  - England
TA  - Chemosphere
JT  - Chemosphere
JID - 0320657
RN  - 0 (Peroxides)
RN  - 11062-77-4 (Superoxides)
RN  - 17778-80-2 (Singlet Oxygen)
RN  - 22047-43-4 (peroxymonosulfate)
RN  - 7440-44-0 (Carbon)
SB  - IM
MH  - Carbon/*chemistry
MH  - Nanocomposites/*chemistry
MH  - Oxidation-Reduction
MH  - Peroxides/*chemistry
MH  - Singlet Oxygen/*chemistry
MH  - Superoxides/*chemistry
OTO - NOTNLM
OT  - Advanced oxidation processes
OT  - Magnetic carbon
OT  - Organic pollutants degradation
OT  - Peroxymonosulfate
OT  - Prussian blue
OT  - Reactive oxygen species
EDAT- 2019/01/06 06:00
MHDA- 2019/02/14 06:00
CRDT- 2019/01/06 06:00
PHST- 2018/09/09 00:00 [received]
PHST- 2018/11/16 00:00 [revised]
PHST- 2018/11/28 00:00 [accepted]
PHST- 2019/01/06 06:00 [entrez]
PHST- 2019/01/06 06:00 [pubmed]
PHST- 2019/02/14 06:00 [medline]
AID - S0045-6535(18)32304-X [pii]
AID - 10.1016/j.chemosphere.2018.11.197 [doi]
PST - ppublish
SO  - Chemosphere. 2019 Mar;218:1071-1081. doi: 10.1016/j.chemosphere.2018.11.197. Epub 
      2018 Nov 29.