PMID- 30613891
OWN - NLM
STAT- MEDLINE
DCOM- 20190527
LR  - 20221207
IS  - 1614-7499 (Electronic)
IS  - 0944-1344 (Linking)
VI  - 26
IP  - 6
DP  - 2019 Feb
TI  - Uptake and distribution of fluopyram and tebuconazole residues in tomato and bell 
      pepper plant tissues.
PG  - 6077-6086
LID - 10.1007/s11356-018-04071-4 [doi]
AB  - The present study describes the uptake and distribution of fungicides, fluopyram, 
      and tebuconazole in tomato and bell pepper plant tissues from the soil drench 
      application of their combination product fluopyram17.7% + tebuconazole 17.7%. For 
      extraction and cleanup of fluopyram, its metabolite fluopyram benzamide, and 
      tebuconazole samples, the QuEChERS method was used in conjunction with LC-MS/MS. 
      The limit of detection (LOD) and limit of quantification (LOQ) of the method 
      determined were 1.5 mug kg(-1) and 0.005 mg kg(-1), respectively, and recoveries 
      of all analytes from sample matrices remained within the acceptable range of 
      70-120%. Rapid uptake of the fungicides by tomato and bell pepper plants was 
      observed from the first day onwards. In the tomato plant, the major part of the 
      fungicides accumulated in the roots, whereas in bell pepper plant, it accumulated 
      both in the roots and in the leaves. Accumulation of fluopyram and tebuconazole 
      residues was lowest in tomato and bell pepper fruits which were much below their 
      respective maximum residue limits (MRLs). The highest residue concentration of 
      fluopyram and tebuconazole in tomato fruits was 0.060 and 0.009 mg kg(-1); the 
      corresponding values in bell pepper fruits were 0.080 and 0.013 mg kg(-1). In 
      field soil, fluopyram residues were 3.18-3.570 mg kg(-1) initially which 
      dissipated at the half-life of 36 days. Tebuconazole concentration was 
      1.57-1.892 mg kg(-1) initially, and it dissipated at the half-life of 
      44.5-49.5 days. The major metabolite of fluopyram, fluopyram benzamide, was 
      detected in plant tissues as well as in soil, and remained within 12% of the 
      parent compound. The results of the study indicated that fluopyram and 
      tebuconazole are less likely of entry into food chain through intake of tomato 
      and bell pepper fruits if these crops are grown on soil contaminated with these 
      fungicides.
FAU - Matadha, Nagapooja Yogendraiah
AU  - Matadha NY
AD  - Pesticide Residue Laboratory, ICAR-Indian Institute of Horticultural Research, 
      Hesaraghatta Lake, Bangalore, 560089, India.
AD  - Department of chemistry, Center for Nano and Material Science, Jain University, 
      Jakkasandra, Kanakpura, Bangalore, 562112, India.
FAU - Mohapatra, Soudamini
AU  - Mohapatra S
AUID- ORCID: 0000-0002-1849-709X
AD  - Pesticide Residue Laboratory, ICAR-Indian Institute of Horticultural Research, 
      Hesaraghatta Lake, Bangalore, 560089, India. soudamini_mohapatra@rediffmail.com.
FAU - Siddamallaiah, Lekha
AU  - Siddamallaiah L
AD  - Pesticide Residue Laboratory, ICAR-Indian Institute of Horticultural Research, 
      Hesaraghatta Lake, Bangalore, 560089, India.
FAU - Udupi, Veena Rao
AU  - Udupi VR
AD  - Pesticide Residue Laboratory, ICAR-Indian Institute of Horticultural Research, 
      Hesaraghatta Lake, Bangalore, 560089, India.
FAU - Gadigeppa, Shambulinga
AU  - Gadigeppa S
AD  - Pesticide Residue Laboratory, ICAR-Indian Institute of Horticultural Research, 
      Hesaraghatta Lake, Bangalore, 560089, India.
FAU - Raja, Danish Poothotathil
AU  - Raja DP
AD  - Pesticide Residue Laboratory, ICAR-Indian Institute of Horticultural Research, 
      Hesaraghatta Lake, Bangalore, 560089, India.
LA  - eng
PT  - Journal Article
DEP - 20190106
PL  - Germany
TA  - Environ Sci Pollut Res Int
JT  - Environmental science and pollution research international
JID - 9441769
RN  - 0 (Benzamides)
RN  - 0 (Fungicides, Industrial)
RN  - 0 (Pesticide Residues)
RN  - 0 (Pyridines)
RN  - 0 (Soil Pollutants)
RN  - 0 (Triazoles)
RN  - 401ATW8TRW (tebuconazole)
RN  - F0VT7K5302 
      (N-(2-(3-chloro-5-(trifluoromethyl)-2-pyridyl)ethyl)-alpha,alpha,alpha-trifluoro-o-toluamide)
SB  - IM
MH  - Benzamides/*analysis/pharmacokinetics
MH  - Capsicum/*chemistry
MH  - Chromatography, Liquid
MH  - Fruit/chemistry
MH  - Fungicides, Industrial/analysis/pharmacokinetics
MH  - Half-Life
MH  - Solanum lycopersicum/*chemistry
MH  - Pesticide Residues/*analysis/pharmacokinetics
MH  - Pyridines/*analysis/pharmacokinetics
MH  - Reproducibility of Results
MH  - Soil Pollutants/*analysis
MH  - Tandem Mass Spectrometry
MH  - Triazoles/*analysis/pharmacokinetics
OTO - NOTNLM
OT  - Bell pepper
OT  - Fluopyram
OT  - LC-MS/MS
OT  - Tebuconazole
OT  - Tomato
OT  - Uptake
EDAT- 2019/01/08 06:00
MHDA- 2019/05/28 06:00
CRDT- 2019/01/08 06:00
PHST- 2018/08/13 00:00 [received]
PHST- 2018/12/27 00:00 [accepted]
PHST- 2019/01/08 06:00 [pubmed]
PHST- 2019/05/28 06:00 [medline]
PHST- 2019/01/08 06:00 [entrez]
AID - 10.1007/s11356-018-04071-4 [pii]
AID - 10.1007/s11356-018-04071-4 [doi]
PST - ppublish
SO  - Environ Sci Pollut Res Int. 2019 Feb;26(6):6077-6086. doi: 
      10.1007/s11356-018-04071-4. Epub 2019 Jan 6.