PMID- 30614680
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20190205
LR  - 20190215
IS  - 1944-8252 (Electronic)
IS  - 1944-8244 (Linking)
VI  - 11
IP  - 4
DP  - 2019 Jan 30
TI  - Controlled Manipulation of Metal-Organic Framework Layers to Nanometer Precision 
      Inside Large Mesochannels of Ordered Mesoporous Silica for Enhanced Removal of 
      Bisphenol A from Water.
PG  - 4328-4337
LID - 10.1021/acsami.8b17508 [doi]
AB  - Considerable attention has been paid on the design of hierarchical porous 
      metal-organic framework (MOF) composites, which not only enhances the performance 
      but also broadens the applications of MOFs. So far, controlled manipulation of 
      nanometer-thick MOF layers in ordered mesochannels, while retaining their 
      respective intrinsic properties, is still a main challenge because of the 
      difficulty of growing MOFs in confined space. Herein, using a step-by-step 
      coordination method, the formation of a hierarchical micro-mesoporous hybrid with 
      a wall (channel wall and coating layer) thickness of up to 8.0 nm and open pore 
      size down to 7.7 nm has been achieved based on large mesoporous SBA-15, and the 
      wall thickness with nanometer precision can be controlled by adjusting the growth 
      cycles of zeolite imidazolate framework-8 (ZIF-8) coating layers. Compared to 
      pure ZIF-8, the obtained ZIF-8@SBA-15 composites showed more than 2-fold 
      enhancement in adsorption capacity and approximately 20-fold improvement in the 
      adsorption rate constant for bisphenol A in water, which could be ascribed to the 
      synergistic effects of the high adsorption ability from ZIF-8 and the fast 
      diffusion property from SBA-15. More importantly, the degraded ZIF-8@SBA-15 
      composite can be completely restored by a simple immersion into 2-methylimidazole 
      solution. The easy restorability and good reusability further enable ZIF-8@SBA-15 
      as a promising adsorbent for effectively removing organic contaminants from 
      water.
FAU - Peng, Junyu
AU  - Peng J
AD  - Key Laboratory of Separation Science for Analytical Chemistry, Dalian Institute 
      of Chemical Physics , Chinese Academy of Sciences , Dalian 116011 , China.
AD  - University of Chinese Academy of Science , Beijing 100049 , China.
FAU - Li, Yun
AU  - Li Y
AD  - Key Laboratory of Separation Science for Analytical Chemistry, Dalian Institute 
      of Chemical Physics , Chinese Academy of Sciences , Dalian 116011 , China.
FAU - Sun, Xiaoli
AU  - Sun X
AD  - Lishui University , Lishui 323000 , China.
FAU - Huang, Chaonan
AU  - Huang C
AD  - Key Laboratory of Separation Science for Analytical Chemistry, Dalian Institute 
      of Chemical Physics , Chinese Academy of Sciences , Dalian 116011 , China.
AD  - University of Chinese Academy of Science , Beijing 100049 , China.
FAU - Jin, Jing
AU  - Jin J
AD  - Key Laboratory of Separation Science for Analytical Chemistry, Dalian Institute 
      of Chemical Physics , Chinese Academy of Sciences , Dalian 116011 , China.
FAU - Wang, Jincheng
AU  - Wang J
AD  - Key Laboratory of Separation Science for Analytical Chemistry, Dalian Institute 
      of Chemical Physics , Chinese Academy of Sciences , Dalian 116011 , China.
FAU - Chen, Jiping
AU  - Chen J
AUID- ORCID: 0000-0001-9404-1687
AD  - Key Laboratory of Separation Science for Analytical Chemistry, Dalian Institute 
      of Chemical Physics , Chinese Academy of Sciences , Dalian 116011 , China.
LA  - eng
PT  - Journal Article
DEP - 20190118
PL  - United States
TA  - ACS Appl Mater Interfaces
JT  - ACS applied materials & interfaces
JID - 101504991
OTO - NOTNLM
OT  - BPA adsorption
OT  - ZIF-8@SBA-15 composite
OT  - fast mass transfer
OT  - nanometer precision
OT  - stepwise coordination
EDAT- 2019/01/08 06:00
MHDA- 2019/01/08 06:01
CRDT- 2019/01/08 06:00
PHST- 2019/01/08 06:00 [pubmed]
PHST- 2019/01/08 06:01 [medline]
PHST- 2019/01/08 06:00 [entrez]
AID - 10.1021/acsami.8b17508 [doi]
PST - ppublish
SO  - ACS Appl Mater Interfaces. 2019 Jan 30;11(4):4328-4337. doi: 
      10.1021/acsami.8b17508. Epub 2019 Jan 18.