PMID- 30625596 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20190212 LR - 20190215 IS - 1873-3573 (Electronic) IS - 0039-9140 (Linking) VI - 195 DP - 2019 Apr 1 TI - Large-pore ordered mesoporous carbon as solid-phase microextraction coating for analysis of polycyclic aromatic hydrocarbons from aqueous media. PG - 647-654 LID - S0039-9140(18)31243-8 [pii] LID - 10.1016/j.talanta.2018.11.090 [doi] AB - In this study, large pore ordered mesoporous carbon (LP-OMC) material was first applied as solid-phase microextraction (SPME) coating for the extraction of polycyclic aromatic hydrocarbons (PAHs) from aqueous media. The LP-OMC SPME fiber was prepared via the dip-coating method in-combination with evaporation-induced self-assembly (EISA) approach. The LP-OMC coating material possessed large specific surface area with the BET surface area of 629 m(2) g(-1) and uniform large pore size at the mean value of 13.5 nm with a narrow pore-size distribution. The extraction performance of LP-OMC fiber for PAHs was compared with another kind of OMC fiber with pore diameter of 4.1 nm. The results implied that the LP-OMC fiber showed better extraction capability towards PAHs. The developed LP-OMC-SPME method for PAHs exhibited wide linear ranges (0.01-50 mug L(-1)), low detection limits (1.6-10.0 ng L(-1)) and good repeatabilities (3.9-7.4% for one fiber, 6.7-11.7% for fiber-to-fiber). The method was successfully applied for the analysis of PAHs in real environmental water samples with satisfactory recovery ranging from 82.6% to 112.1%. CI - Copyright (c) 2018 Elsevier B.V. All rights reserved. FAU - Jiang, Hui AU - Jiang H AD - Jiangsu Key Laboratory of Chemical Pollution Control and Resources Reuse, School of Environmental Science and Engineering, Nanjing University of Science and Technology, Nanjing 210094, PR China; School of Geography Science, Nantong University, Nantong 226001, PR China. FAU - Hu, Xingru AU - Hu X AD - Jiangsu Key Laboratory of Chemical Pollution Control and Resources Reuse, School of Environmental Science and Engineering, Nanjing University of Science and Technology, Nanjing 210094, PR China. FAU - Li, Yang AU - Li Y AD - Jiangsu Key Laboratory of Chemical Pollution Control and Resources Reuse, School of Environmental Science and Engineering, Nanjing University of Science and Technology, Nanjing 210094, PR China. FAU - Qi, Junwen AU - Qi J AD - Jiangsu Key Laboratory of Chemical Pollution Control and Resources Reuse, School of Environmental Science and Engineering, Nanjing University of Science and Technology, Nanjing 210094, PR China. FAU - Sun, Xiuyun AU - Sun X AD - Jiangsu Key Laboratory of Chemical Pollution Control and Resources Reuse, School of Environmental Science and Engineering, Nanjing University of Science and Technology, Nanjing 210094, PR China. FAU - Wang, Lianjun AU - Wang L AD - Jiangsu Key Laboratory of Chemical Pollution Control and Resources Reuse, School of Environmental Science and Engineering, Nanjing University of Science and Technology, Nanjing 210094, PR China. FAU - Li, Jiansheng AU - Li J AD - Jiangsu Key Laboratory of Chemical Pollution Control and Resources Reuse, School of Environmental Science and Engineering, Nanjing University of Science and Technology, Nanjing 210094, PR China. Electronic address: lijsh@njust.edu.cn. LA - eng PT - Journal Article DEP - 20181126 PL - Netherlands TA - Talanta JT - Talanta JID - 2984816R OTO - NOTNLM OT - Ordered mesoporous carbon OT - Polycyclic aromatic hydrocarbons OT - Solid phase microextraction EDAT- 2019/01/11 06:00 MHDA- 2019/01/11 06:01 CRDT- 2019/01/11 06:00 PHST- 2018/08/05 00:00 [received] PHST- 2018/10/27 00:00 [revised] PHST- 2018/11/24 00:00 [accepted] PHST- 2019/01/11 06:00 [entrez] PHST- 2019/01/11 06:00 [pubmed] PHST- 2019/01/11 06:01 [medline] AID - S0039-9140(18)31243-8 [pii] AID - 10.1016/j.talanta.2018.11.090 [doi] PST - ppublish SO - Talanta. 2019 Apr 1;195:647-654. doi: 10.1016/j.talanta.2018.11.090. Epub 2018 Nov 26.