PMID- 30628149
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20191120
IS  - 1521-3773 (Electronic)
IS  - 1433-7851 (Linking)
VI  - 58
IP  - 16
DP  - 2019 Apr 8
TI  - Robust Superhydrophobic/Superoleophilic Wrinkled Microspherical MOF@rGO 
      Composites for Efficient Oil-Water Separation.
PG  - 5297-5301
LID - 10.1002/anie.201814487 [doi]
AB  - Graphene/MOF-based composite materials in three-dimensional (3D) architectures 
      are promising for the treatment of oil-containing wastewater by absorption owing 
      to their intrinsic properties of graphene and metal-organic frameworks (MOFs), 
      such as high porosity, ultralow density, and facilely tailored superwettability. 
      In this study, novel wrinkled 3D microspherical MOF@rGO composites with both 
      superhydrophobic and superoleophilic properties were developed by embedding MOF 
      nanoparticles between graphene oxide (GO) nanosheets, followed by 
      high-temperature reduction self-assembly. The microspherical composites feature a 
      unique micro/nano hierarchy consisting of crumpled reduced GO (rGO) nanosheets 
      intercalated with well-dispersed MOF nanoparticles. Combined with the 
      superwettability and abundant meso/microporosity, the peculiar architectures of 
      wrinkled ZIF-8@rGO microspheres show very fast absorption rates and high sorption 
      selectivity for organic solvents and oils from water.
CI  - (c) 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
FAU - Gu, Jiahui
AU  - Gu J
AD  - Beijing Key Laboratory of Membrane Science and Technology, Beijing University of 
      Chemical Technology, Beijing, 100029, P. R. China.
FAU - Fan, Hongwei
AU  - Fan H
AD  - Beijing Key Laboratory of Membrane Science and Technology, Beijing University of 
      Chemical Technology, Beijing, 100029, P. R. China.
AD  - Institute of Physical Chemistry and Electrochemistry, Leibniz Universitat 
      Hannover, Callinstrasse 3A, 30167, Hannover, Germany.
FAU - Li, Chunxi
AU  - Li C
AD  - Beijing Key Laboratory of Membrane Science and Technology, Beijing University of 
      Chemical Technology, Beijing, 100029, P. R. China.
FAU - Caro, Jurgen
AU  - Caro J
AD  - Institute of Physical Chemistry and Electrochemistry, Leibniz Universitat 
      Hannover, Callinstrasse 3A, 30167, Hannover, Germany.
FAU - Meng, Hong
AU  - Meng H
AUID- ORCID: 0000-0001-5513-7846
AD  - Beijing Key Laboratory of Membrane Science and Technology, Beijing University of 
      Chemical Technology, Beijing, 100029, P. R. China.
LA  - eng
GR  - 51773012/National Natural Science Foundation of China/
GR  - 2017(57343410)/Sino-German (CSC-DAAD) Postdoc Scholarship Program/
PT  - Journal Article
DEP - 20190206
PL  - Germany
TA  - Angew Chem Int Ed Engl
JT  - Angewandte Chemie (International ed. in English)
JID - 0370543
OTO - NOTNLM
OT  - graphene-based microspheres
OT  - metal-organic frameworks
OT  - oil-water separation
OT  - superhydrophobicity
OT  - superoleophilicity
EDAT- 2019/01/11 06:00
MHDA- 2019/01/11 06:01
CRDT- 2019/01/11 06:00
PHST- 2018/12/21 00:00 [received]
PHST- 2019/01/11 06:00 [pubmed]
PHST- 2019/01/11 06:01 [medline]
PHST- 2019/01/11 06:00 [entrez]
AID - 10.1002/anie.201814487 [doi]
PST - ppublish
SO  - Angew Chem Int Ed Engl. 2019 Apr 8;58(16):5297-5301. doi: 10.1002/anie.201814487. 
      Epub 2019 Feb 6.