PMID- 30665640
OWN - NLM
STAT- MEDLINE
DCOM- 20190130
LR  - 20190130
IS  - 1001-0742 (Print)
IS  - 1001-0742 (Linking)
VI  - 78
DP  - 2019 Apr
TI  - One-step preparation of polyimide-inlaid amine-rich porous organic block 
      copolymer for efficient removal of chlorophenols from aqueous solution.
PG  - 215-229
LID - S1001-0742(18)31949-1 [pii]
LID - 10.1016/j.jes.2018.09.023 [doi]
AB  - A novel polyimide-inlaid amine-rich porous organic block copolymer (PI-b-ARPOP) 
      was prepared via one-step polymerization by using different molar ratios of 
      melamine (MA)/terephthalaldehyde (TA)/pyromellitic dianhydride (PMDA), at molar 
      ratios of 4/3/1, 4/2/2 and 4/1/3. The copolymer contained both aminal groups 
      belonging to ARPOP and imide groups belonging to PI, and the bonding styles of 
      the monomers and growth orientations of the polymeric chains were diversiform, 
      forming an excellent porous structure. Notably, MA/TA/PMDA (4/2/2) had a surface 
      area and pore volume of 487.27 m(2)/g and 1.169 cm(3)/g, respectively. The 
      adsorption performance of the materials towards 2,4-dichlorophenol (2,4-DCP) in 
      ultra-pure water was systematically studied. The pH value of 7 was optimal in 
      aqueous solution. Na(+) and Cl(-) ions did not negatively affect the adsorption 
      process, while humic acid (HA) slightly decreased the capacity. The equilibrium 
      time was 40 sec, and the maximum adsorption capacity reached 282.49 mg/g at 
      298 K. The removal process was endothermic and spontaneous, and the copolymer 
      could maintain its porous structure and consistent performance after regeneration 
      by treatment with alkali. Moreover, to further assess the practical applicability 
      of the material, the adsorption performance towards 2,4-DCP in river water was 
      also investigated. This paper demonstrated that the PI-b-ARPOP can be an 
      efficient and practical adsorbent to remove chlorophenols from aqueous solution.
CI  - Copyright (c) 2018. Published by Elsevier B.V.
FAU - Liu, Yanyang
AU  - Liu Y
AD  - Engineering Research Center of Nano-Geomaterials of Ministry of Education, 
      Faculty of Material Science and Chemistry, China University of Geosciences, Wuhan 
      430074, China.
FAU - Ou, Haijian
AU  - Ou H
AD  - Engineering Research Center of Nano-Geomaterials of Ministry of Education, 
      Faculty of Material Science and Chemistry, China University of Geosciences, Wuhan 
      430074, China.
FAU - Li, Shangqing
AU  - Li S
AD  - Engineering Research Center of Nano-Geomaterials of Ministry of Education, 
      Faculty of Material Science and Chemistry, China University of Geosciences, Wuhan 
      430074, China.
FAU - You, Qingliang
AU  - You Q
AD  - Key Laboratory of Optoelectronic Chemical Materials and Devices, Ministry of 
      Education, School of Chemical and Environmental Engineering, Jianghan University, 
      Wuhan 430056, China.
FAU - Liu, Huixian
AU  - Liu H
AD  - Engineering Research Center of Nano-Geomaterials of Ministry of Education, 
      Faculty of Material Science and Chemistry, China University of Geosciences, Wuhan 
      430074, China.
FAU - Liao, Guiying
AU  - Liao G
AD  - Engineering Research Center of Nano-Geomaterials of Ministry of Education, 
      Faculty of Material Science and Chemistry, China University of Geosciences, Wuhan 
      430074, China. Electronic address: liaogy@cug.edu.cn.
FAU - Wang, Dongsheng
AU  - Wang D
AD  - Engineering Research Center of Nano-Geomaterials of Ministry of Education, 
      Faculty of Material Science and Chemistry, China University of Geosciences, Wuhan 
      430074, China; State Key Laboratory of Environmental Aquatic Chemistry, Research 
      Center for Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing 
      100085, China. Electronic address: wgds@rcees.ac.cn.
LA  - eng
PT  - Journal Article
DEP - 20181005
PL  - Netherlands
TA  - J Environ Sci (China)
JT  - Journal of environmental sciences (China)
JID - 100967627
RN  - 0 (Chlorophenols)
RN  - 0 (Polymers)
RN  - 0 (Water Pollutants, Chemical)
SB  - IM
MH  - Adsorption
MH  - Chlorophenols/analysis/*chemistry
MH  - Kinetics
MH  - Polymers/*chemistry
MH  - Porosity
MH  - Water Pollutants, Chemical/analysis/*chemistry
MH  - Water Purification/*methods
OTO - NOTNLM
OT  - 2,4-Dichlorophenol
OT  - Adsorption
OT  - Polyimide
OT  - Porous block copolymer
OT  - Schiff base
EDAT- 2019/01/23 06:00
MHDA- 2019/01/31 06:00
CRDT- 2019/01/23 06:00
PHST- 2018/07/17 00:00 [received]
PHST- 2018/09/21 00:00 [revised]
PHST- 2018/09/25 00:00 [accepted]
PHST- 2019/01/23 06:00 [entrez]
PHST- 2019/01/23 06:00 [pubmed]
PHST- 2019/01/31 06:00 [medline]
AID - S1001-0742(18)31949-1 [pii]
AID - 10.1016/j.jes.2018.09.023 [doi]
PST - ppublish
SO  - J Environ Sci (China). 2019 Apr;78:215-229. doi: 10.1016/j.jes.2018.09.023. Epub 
      2018 Oct 5.