PMID- 30711322
OWN - NLM
STAT- MEDLINE
DCOM- 20190503
LR  - 20190503
IS  - 1873-3778 (Electronic)
IS  - 0021-9673 (Linking)
VI  - 1592
DP  - 2019 May 10
TI  - A solid phase microextraction Arrow with zirconium metal-organic 
      framework/molybdenum disulfide coating coupled with gas chromatography-mass 
      spectrometer for the determination of polycyclic aromatic hydrocarbons in fish 
      samples.
PG  - 9-18
LID - S0021-9673(19)30114-1 [pii]
LID - 10.1016/j.chroma.2019.01.066 [doi]
AB  - Solid phase microextraction (SPME) Arrows with enlarged sorption phases and 
      Arrow-shaped tips are good alternatives to classic SPME fibers. Developing SPME 
      Arrows with functionalized coatings has become a growing area of SPME research. 
      In this study, a zirconium metal organic framework/molybdenum disulfide 
      (UiO-66/MoS(2)) composite coating modified SPME Arrow was developed and coupled 
      with gas chromatography-mass spectrometry for the headspace extraction and 
      detection of 16 polycyclic aromatic hydrocarbons (PAHs). The coating preparation 
      can be easily manipulated by the assembly strategy using silicone gels to adhere 
      UiO-66/MoS(2) powder onto the surface of the Arrows. The prepared UiO-66/MoS(2) 
      coated SPME Arrows exhibited clearly enhanced adsorption capacity (2.1-4.5 folds) 
      and an improved degree of affinity to PAHs species when compared to commercial 
      PDMS/CARS/DVB SPME Arrows or fibers. The improved mechanism may be due to the 
      high specific area, hierarchical micropores and mesopores, and the largely 
      increased and immobilized amount of UiO-66/MoS(2) coating on the stainless-steel 
      Arrow. Under optimized conditions, the SPME Arrow-based assay was successfully 
      applied to determine PAH levels in fish samples with satisfactory recoveries of 
      80.2-101% and relative standard deviations (RSDs) of less than 6%. The detection 
      limits of PAHs were between 0.11-1.40 ng kg(-1). The coating showed satisfied 
      reproducibility and repeatability (RSD <8.6%) with only 10 mL of 10% (v/v) 
      acetone in water used as the extraction phase in an effort to be environmentally 
      friendly. All of the results showed that the method is simple, sensitive, and 
      robust. SPME Arrows with UiO-66/MoS(2) coatings can provide new opportunities for 
      the efficient extraction of persistent organic pollutants in food safety 
      applications.
CI  - Copyright (c) 2019 Elsevier B.V. All rights reserved.
FAU - Yuan, Yongli
AU  - Yuan Y
AD  - Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo, 
      315211, China.
FAU - Lin, Xiaoting
AU  - Lin X
AD  - Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo, 
      315211, China.
FAU - Li, Tianhua
AU  - Li T
AD  - Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo, 
      315211, China.
FAU - Pang, Tianyu
AU  - Pang T
AD  - Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo, 
      315211, China.
FAU - Dong, Youren
AU  - Dong Y
AD  - Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo, 
      315211, China.
FAU - Zhuo, Rongjie
AU  - Zhuo R
AD  - Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo, 
      315211, China.
FAU - Wang, Qiqin
AU  - Wang Q
AD  - Institute of Pharmaceutical Analysis, College of Pharmacy, Jinan University, 
      Guangzhou, 510632, China. Electronic address: qiqinxtu@163.com.
FAU - Cao, Yuting
AU  - Cao Y
AD  - Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo, 
      315211, China.
FAU - Gan, Ning
AU  - Gan N
AD  - Faculty of Materials Science and Chemical Engineering, Ningbo University, Ningbo, 
      315211, China. Electronic address: ganning@nbu.edu.cn.
LA  - eng
PT  - Journal Article
DEP - 20190124
PL  - Netherlands
TA  - J Chromatogr A
JT  - Journal of chromatography. A
JID - 9318488
RN  - 0 (Dimethylpolysiloxanes)
RN  - 0 (Disulfides)
RN  - 0 (Metal-Organic Frameworks)
RN  - 0 (Polycyclic Aromatic Hydrocarbons)
RN  - 0 (Polyvinyls)
RN  - 0 (Water Pollutants, Chemical)
RN  - 0 (poly(dimethylsiloxane-divinylbenzene))
RN  - 059QF0KO0R (Water)
RN  - 12597-68-1 (Stainless Steel)
RN  - 1364PS73AF (Acetone)
RN  - 81AH48963U (Molybdenum)
RN  - C6V6S92N3C (Zirconium)
RN  - ZC8B4P503V (molybdenum disulfide)
SB  - IM
MH  - Acetone/chemistry
MH  - Adsorption
MH  - Animals
MH  - Dimethylpolysiloxanes
MH  - Disulfides/*chemistry
MH  - *Fishes
MH  - Food Analysis/*instrumentation
MH  - Gas Chromatography-Mass Spectrometry
MH  - Limit of Detection
MH  - Metal-Organic Frameworks/*chemistry
MH  - Molybdenum/*chemistry
MH  - Polycyclic Aromatic Hydrocarbons/*analysis
MH  - Polyvinyls
MH  - Reproducibility of Results
MH  - Solid Phase Microextraction/*instrumentation
MH  - Stainless Steel/chemistry
MH  - Water/chemistry
MH  - Water Pollutants, Chemical/analysis
MH  - Zirconium/*chemistry
OTO - NOTNLM
OT  - GC-MS
OT  - MoS(2)
OT  - Polycyclic aromatic hydrocarbons
OT  - Solid-phase microextraction Arrow
OT  - UiO-66
EDAT- 2019/02/04 06:00
MHDA- 2019/05/06 06:00
CRDT- 2019/02/04 06:00
PHST- 2018/11/18 00:00 [received]
PHST- 2019/01/17 00:00 [revised]
PHST- 2019/01/23 00:00 [accepted]
PHST- 2019/02/04 06:00 [pubmed]
PHST- 2019/05/06 06:00 [medline]
PHST- 2019/02/04 06:00 [entrez]
AID - S0021-9673(19)30114-1 [pii]
AID - 10.1016/j.chroma.2019.01.066 [doi]
PST - ppublish
SO  - J Chromatogr A. 2019 May 10;1592:9-18. doi: 10.1016/j.chroma.2019.01.066. Epub 
      2019 Jan 24.