PMID- 30712207
OWN - NLM
STAT- MEDLINE
DCOM- 20190530
LR  - 20200225
IS  - 1614-7499 (Electronic)
IS  - 0944-1344 (Linking)
VI  - 26
IP  - 9
DP  - 2019 Mar
TI  - Synergistic effect and degradation mechanism on Fe-Ni/CNTs for removal of 
      2,4-dichlorophenol in aqueous solution.
PG  - 8768-8778
LID - 10.1007/s11356-019-04394-w [doi]
AB  - Fe-Ni bimetallic nanoparticles supported on CNTs (Fe-Ni/CNTs) were synthesized, 
      characterized, and applied for removal of 2,4-dichlorophenol (2,4-DCP) in aqueous 
      solution. The removal performance was enhanced drastically on Fe-Ni/CNTs with 
      respect to monometallic Fe/CNTs. The synergistic effect between Fe-Ni 
      nanoparticles and CNTs has been studied in detail. The research results indicated 
      that the doping of Ni played an important role in promoting the catalytic 
      degradation of 2,4-DCP. And the presence of CNTs not only could effectively 
      reduce the aggregation of nanoparticles but also facilitate the mass transfer of 
      2,4-DCP and the formation of active atomic hydrogen during the catalytic process. 
      In addition, the removal kinetics of 2,4-DCP by Fe-Ni/CNTs were in agreement with 
      a pseudo-first-order model, and the rate constants were dependent on a number of 
      factors including the initial concentration of 2,4-DCP, the dosage of Fe-Ni/CNTs, 
      pH value of the solution, and doping amount of Ni. The degradation mechanism 
      involved the adsorption by CNTs and catalytic reduction by Fe under the 
      stimulating of Ni, and the preferred dechlorination followed the order of para-Cl 
      > ortho-Cl. The study confirmed that Fe-Ni/CNTs had a potential to be a promising 
      catalytic material for removal of chlorophenol and had a great prospect for 
      practical application.
FAU - Sun, Yufeng
AU  - Sun Y
AD  - Key Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical 
      Engineering, Nanjing University, Nanjing, 210023, People's Republic of China.
AD  - School of Chemistry and Environmental Engineering, Yancheng Teachers University, 
      Yancheng, 224002, People's Republic of China.
FAU - Liu, Zongtang
AU  - Liu Z
AD  - School of Chemistry and Environmental Engineering, Yancheng Teachers University, 
      Yancheng, 224002, People's Republic of China.
FAU - Fei, Zhenghao
AU  - Fei Z
AD  - School of Chemistry and Environmental Engineering, Yancheng Teachers University, 
      Yancheng, 224002, People's Republic of China.
FAU - Li, Changshun
AU  - Li C
AD  - Key Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical 
      Engineering, Nanjing University, Nanjing, 210023, People's Republic of China.
FAU - Chun, Yuan
AU  - Chun Y
AD  - Key Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical 
      Engineering, Nanjing University, Nanjing, 210023, People's Republic of China.
FAU - Zhang, Aimin
AU  - Zhang A
AD  - Key Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical 
      Engineering, Nanjing University, Nanjing, 210023, People's Republic of China. 
      zhangamchem@163.com.
LA  - eng
GR  - 41877118/the National Natural Science Foundation of China/
GR  - 21573104/the National Natural Science Foundation of China/
GR  - BK20181479/the Natural Science Foundation of Jiangsu Province of China/
GR  - 17KJB610013/the Natural Science Foundation of the Jiangsu Higher Education 
      Institutions of China/
GR  - 17KJA610006/the Natural Science Foundation of the Jiangsu Higher Education 
      Institutions of China/
PT  - Journal Article
DEP - 20190202
PL  - Germany
TA  - Environ Sci Pollut Res Int
JT  - Environmental science and pollution research international
JID - 9441769
RN  - 0 (Chlorophenols)
RN  - 0 (Nanotubes, Carbon)
RN  - 0 (Water Pollutants, Chemical)
RN  - 7OV03QG267 (Nickel)
RN  - E1UOL152H7 (Iron)
RN  - R669TG1950 (2,4-dichlorophenol)
SB  - IM
MH  - Catalysis
MH  - Chlorophenols/*chemistry
MH  - Iron/*chemistry
MH  - Kinetics
MH  - *Nanotubes, Carbon
MH  - Nickel/*chemistry
MH  - Water Pollutants, Chemical/*chemistry
MH  - Water Purification/*methods
OTO - NOTNLM
OT  - 2,4-dichlorophenol
OT  - CNTs
OT  - Degradation
OT  - Supported Fe-Ni nanoparticles
OT  - Synergistic effect
EDAT- 2019/02/04 06:00
MHDA- 2019/05/31 06:00
CRDT- 2019/02/04 06:00
PHST- 2018/10/19 00:00 [received]
PHST- 2019/01/25 00:00 [accepted]
PHST- 2019/02/04 06:00 [pubmed]
PHST- 2019/05/31 06:00 [medline]
PHST- 2019/02/04 06:00 [entrez]
AID - 10.1007/s11356-019-04394-w [pii]
AID - 10.1007/s11356-019-04394-w [doi]
PST - ppublish
SO  - Environ Sci Pollut Res Int. 2019 Mar;26(9):8768-8778. doi: 
      10.1007/s11356-019-04394-w. Epub 2019 Feb 2.