PMID- 30740393 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20200930 IS - 2296-2646 (Print) IS - 2296-2646 (Electronic) IS - 2296-2646 (Linking) VI - 6 DP - 2018 TI - Thermo-Responsive Molecularly Imprinted Hydrogels for Selective Adsorption and Controlled Release of Phenol From Aqueous Solution. PG - 674 LID - 10.3389/fchem.2018.00674 [doi] LID - 674 AB - In this study, thermo-responsive molecularly imprinted hydrogels (T-MIHs) were developed as an effective potential adsorbent for selectively adsorption phenol from wastewater. During the process, N-isopropyl acrylamide (NIPAm) was used as thermal responsive monomer. The obtained materials were characterized in detail by fourier transform infrared (FT-IR) spectrometer, scanning electron microscope (SEM), and thermo gravimetric analysis (TGA). A series of static adsorption studies were performed to investigate the kinetics, specific adsorption equilibrium, and selective recognition ability of phenol. Reversible adsorption and release of phenol were realized by changing temperatures. Three type of phenols, namely 3-chlorophenols (3-CP), 2,4-dichlorophenol (2,4-DCP), and 2,4,6-trichlorophenol (2,4,6-TCP) were selected as model analytes to evaluate the selective recognition performance of T-MIHs. The T-MIHs have good selectivity, temperature response, and reusability, making them ideal in applying in the controlled separation and release of phenol pollutants. FAU - Si, Zhenhui AU - Si Z AD - School of Computer Science, Jilin Normal University, Siping, China. AD - Key Laboratory of Numerical Simulation of Jilin Province, Jilin Normal University, Siping, China. FAU - Yu, Ping AU - Yu P AD - School of Computer Science, Jilin Normal University, Siping, China. AD - Key Laboratory of Numerical Simulation of Jilin Province, Jilin Normal University, Siping, China. FAU - Dong, Yanying AU - Dong Y AD - School of Computer Science, Jilin Normal University, Siping, China. AD - Key Laboratory of Numerical Simulation of Jilin Province, Jilin Normal University, Siping, China. FAU - Lu, Yang AU - Lu Y AD - School of Computer Science, Jilin Normal University, Siping, China. AD - Key Laboratory of Numerical Simulation of Jilin Province, Jilin Normal University, Siping, China. FAU - Tan, Zhenjiang AU - Tan Z AD - School of Computer Science, Jilin Normal University, Siping, China. AD - Key Laboratory of Numerical Simulation of Jilin Province, Jilin Normal University, Siping, China. FAU - Yu, Xiaopeng AU - Yu X AD - School of Computer Science, Jilin Normal University, Siping, China. AD - Key Laboratory of Numerical Simulation of Jilin Province, Jilin Normal University, Siping, China. FAU - Zhao, Rui AU - Zhao R AD - School of Computer Science, Jilin Normal University, Siping, China. AD - Key Laboratory of Numerical Simulation of Jilin Province, Jilin Normal University, Siping, China. FAU - Yan, Yongsheng AU - Yan Y AD - School of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang, China. LA - eng PT - Journal Article DEP - 20190124 PL - Switzerland TA - Front Chem JT - Frontiers in chemistry JID - 101627988 PMC - PMC6357936 OTO - NOTNLM OT - N-isopropyl acrylamide OT - molecularly imprinted hydrogels OT - phenol OT - recognition OT - thermo-responsive EDAT- 2019/02/12 06:00 MHDA- 2019/02/12 06:01 PMCR- 2018/01/01 CRDT- 2019/02/12 06:00 PHST- 2018/05/18 00:00 [received] PHST- 2018/12/24 00:00 [accepted] PHST- 2019/02/12 06:00 [entrez] PHST- 2019/02/12 06:00 [pubmed] PHST- 2019/02/12 06:01 [medline] PHST- 2018/01/01 00:00 [pmc-release] AID - 10.3389/fchem.2018.00674 [doi] PST - epublish SO - Front Chem. 2019 Jan 24;6:674. doi: 10.3389/fchem.2018.00674. eCollection 2018.