PMID- 30797005
OWN - NLM
STAT- MEDLINE
DCOM- 20190903
LR  - 20190903
IS  - 1879-0003 (Electronic)
IS  - 0141-8130 (Linking)
VI  - 130
DP  - 2019 Jun 1
TI  - A facile synthesis of CuAg nanoparticles on highly porous ZnO/carbon 
      black-cellulose acetate sheets for nitroarene and azo dyes reduction/degradation.
PG  - 288-299
LID - S0141-8130(19)30620-8 [pii]
LID - 10.1016/j.ijbiomac.2019.02.114 [doi]
AB  - A facile and highly porous heterostructure nanocomposite was designed for the 
      support of zero-valent metal nanoparticles. This nanocomposite comprising of 
      ZnO/carbon black (ZnO/CB) embedded in cellulose acetate polymer (CA), named as 
      ZCA sheet, supported the metallic Cu, Ag and bimetallic CuAg nanoparticles (NPs). 
      The ZnO/CB was incorporated to CA polymer host molecule in 3, 4 and 5 wt% and are 
      designated as ZCA-3, ZCA-4 and ZCA-5. The catalytic tunability was evaluated for 
      CuAg/ZCA-5 by adjusting the concentration of Cu and Ag ions in different molar 
      ratio. Therefore, the CuAg/ZCA-5 was further selected for the removal of eight 
      model pollutants comprising of o-nitrophenol (ONP), m-nitrophenol (MNP), 
      p-nitrophenol (PNP), 2,6-dinitrophenol (DNP), methyl orange (MO), congo red (CR), 
      methylene blue (MB) and rhodamine B (RB). The K(app) value for PNP was 
      1.9 x 10(-1) min(-1) and 9.0 x 10(-2) min(-1) for MO(.) Among the various 
      nitrophenols, the rate of reaction with CuAg/ZCA-5 followed the ordered as PNP > 
      ONP > MNP > DNP, while methyl orange (MO) is degraded faster as compared to other 
      dyes. The morphology, shape, elemental analysis, functional groups and peak 
      crystallinity were scrutinized through FESEM, EDS, ATR-FTIR and XRD respectively.
CI  - Copyright (c) 2019. Published by Elsevier B.V.
FAU - Khan, Shahid Ali
AU  - Khan SA
AD  - Center of Excellence for Advanced Materials Research (CEAMR), King Abdulaziz 
      University, P.O. Box 80203, Jeddah 21589, Saudi Arabia; Department of Chemistry, 
      King Abdulaziz University, P.O. Box 80203, Jeddah 21589, Saudi Arabia; Department 
      of Chemistry, University of Swabi, Anbar 23561, Khyber Pakhtunkhwa, Pakistan. 
      Electronic address: skhan@uoswabi.edu.pk.
FAU - Khan, Sher Bahadar
AU  - Khan SB
AD  - Center of Excellence for Advanced Materials Research (CEAMR), King Abdulaziz 
      University, P.O. Box 80203, Jeddah 21589, Saudi Arabia; Department of Chemistry, 
      King Abdulaziz University, P.O. Box 80203, Jeddah 21589, Saudi Arabia. Electronic 
      address: sbkhan@kau.edu.sa.
FAU - Farooq, Aliya
AU  - Farooq A
AD  - Department of Chemistry, Shaheed Benazir Bhutto Women University, Pakistan.
FAU - Asiri, Abdullah M
AU  - Asiri AM
AD  - Center of Excellence for Advanced Materials Research (CEAMR), King Abdulaziz 
      University, P.O. Box 80203, Jeddah 21589, Saudi Arabia; Department of Chemistry, 
      King Abdulaziz University, P.O. Box 80203, Jeddah 21589, Saudi Arabia.
LA  - eng
PT  - Journal Article
DEP - 20190220
PL  - Netherlands
TA  - Int J Biol Macromol
JT  - International journal of biological macromolecules
JID - 7909578
RN  - 0 (Azo Compounds)
RN  - 0 (Environmental Pollutants)
RN  - 0 (Nitrophenols)
RN  - 0 (Soot)
RN  - 3J2P07GVB6 (acetylcellulose)
RN  - 3M4G523W1G (Silver)
RN  - 789U1901C5 (Copper)
RN  - 9004-34-6 (Cellulose)
RN  - SOI2LOH54Z (Zinc Oxide)
SB  - IM
MH  - Adsorption
MH  - Azo Compounds/*chemistry/isolation & purification
MH  - Catalysis
MH  - Cellulose/*analogs & derivatives/chemistry
MH  - Chemistry Techniques, Synthetic
MH  - Copper/chemistry
MH  - Environmental Pollutants/chemistry/isolation & purification
MH  - Metal Nanoparticles/*chemistry
MH  - Nanoparticles/*chemistry
MH  - Nanotechnology
MH  - Nitrophenols/*chemistry/isolation & purification
MH  - Oxidation-Reduction
MH  - Porosity
MH  - Silver/chemistry
MH  - Soot/*chemistry
MH  - Zinc Oxide/*chemistry
OTO - NOTNLM
OT  - Cellulose acetate
OT  - CuAg nanoparticles
OT  - Degradation
EDAT- 2019/02/24 06:00
MHDA- 2019/09/04 06:00
CRDT- 2019/02/24 06:00
PHST- 2019/01/24 00:00 [received]
PHST- 2019/02/19 00:00 [accepted]
PHST- 2019/02/24 06:00 [pubmed]
PHST- 2019/09/04 06:00 [medline]
PHST- 2019/02/24 06:00 [entrez]
AID - S0141-8130(19)30620-8 [pii]
AID - 10.1016/j.ijbiomac.2019.02.114 [doi]
PST - ppublish
SO  - Int J Biol Macromol. 2019 Jun 1;130:288-299. doi: 10.1016/j.ijbiomac.2019.02.114. 
      Epub 2019 Feb 20.