PMID- 30809347
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20231006
IS  - 2041-6520 (Print)
IS  - 2041-6539 (Electronic)
IS  - 2041-6520 (Linking)
VI  - 10
IP  - 5
DP  - 2019 Feb 7
TI  - Sodium-coupled electron transfer reactivity of metal-organic frameworks 
      containing titanium clusters: the importance of cations in redox chemistry.
PG  - 1322-1331
LID - 10.1039/c8sc04138e [doi]
AB  - Stoichiometric reduction reactions of two metal-organic frameworks (MOFs) by the 
      solution reagents (M = Cr, Co) are described. The two MOFs contain clusters with 
      Ti(8)O(8) rings: Ti(8)O(8)(OH)(4)(bdc)(6); bdc = terephthalate (MIL-125) and 
      Ti(8)O(8)(OH)(4)(bdc-NH(2))(6); bdc-NH(2) = 2-aminoterephthalate (NH(2)-MIL-125). 
      The stoichiometry of the redox reactions was probed using solution NMR methods. 
      The extent of reduction is greatly enhanced by the presence of Na(+), which is 
      incorporated into the bulk of the material. The roughly 1 : 1 stoichiometry of 
      electrons and cations indicates that the storage of e(-) in the MOF is tightly 
      coupled to a cation within the architecture, for charge balance.
FAU - Saouma, Caroline T
AU  - Saouma CT
AUID- ORCID: 0000-0003-1170-6175
AD  - Department of Chemistry , University of Washington , Box 351700 , Seattle , 
      Washington 98195-1700 , USA.
AD  - Department of Chemistry , University of Utah , 315 S 1400 E , Salt Lake City , 
      Utah 84112-0850 , USA . Email: caroline.saouma@utah.edu.
FAU - Tsou, Chih-Chin
AU  - Tsou CC
AD  - Department of Chemistry , University of Washington , Box 351700 , Seattle , 
      Washington 98195-1700 , USA.
AD  - Department of Chemistry , Yale University , P.O. Box 208107 , New Haven , CT 
      06520-8107 , USA . Email: james.mayer@yale.edu.
FAU - Richard, Sarah
AU  - Richard S
AD  - Department of Chemistry , University of Washington , Box 351700 , Seattle , 
      Washington 98195-1700 , USA.
FAU - Ameloot, Rob
AU  - Ameloot R
AD  - Centre for Surface Chemistry and Catalysis , KU Leuven , University of Leuven , 
      Celestijnenlaan 200F p.o. box 2461 , 3001 Leuven , Belgium . Email: 
      dirk.devos@kuleuven.be.
FAU - Vermoortele, Frederik
AU  - Vermoortele F
AD  - Centre for Surface Chemistry and Catalysis , KU Leuven , University of Leuven , 
      Celestijnenlaan 200F p.o. box 2461 , 3001 Leuven , Belgium . Email: 
      dirk.devos@kuleuven.be.
FAU - Smolders, Simon
AU  - Smolders S
AUID- ORCID: 0000-0002-3622-2022
AD  - Centre for Surface Chemistry and Catalysis , KU Leuven , University of Leuven , 
      Celestijnenlaan 200F p.o. box 2461 , 3001 Leuven , Belgium . Email: 
      dirk.devos@kuleuven.be.
FAU - Bueken, Bart
AU  - Bueken B
AUID- ORCID: 0000-0002-4610-7204
AD  - Centre for Surface Chemistry and Catalysis , KU Leuven , University of Leuven , 
      Celestijnenlaan 200F p.o. box 2461 , 3001 Leuven , Belgium . Email: 
      dirk.devos@kuleuven.be.
FAU - DiPasquale, Antonio G
AU  - DiPasquale AG
AUID- ORCID: 0000-0002-9265-8381
AD  - Department of Chemistry , University of California , Latimer Hall , Berkeley , CA 
      94720 , USA.
FAU - Kaminsky, Werner
AU  - Kaminsky W
AUID- ORCID: 0000-0002-9100-4909
AD  - Department of Chemistry , University of Washington , Box 351700 , Seattle , 
      Washington 98195-1700 , USA.
FAU - Valdez, Carolyn N
AU  - Valdez CN
AD  - Department of Chemistry , University of Washington , Box 351700 , Seattle , 
      Washington 98195-1700 , USA.
AD  - Department of Chemistry , Yale University , P.O. Box 208107 , New Haven , CT 
      06520-8107 , USA . Email: james.mayer@yale.edu.
FAU - De Vos, Dirk E
AU  - De Vos DE
AD  - Centre for Surface Chemistry and Catalysis , KU Leuven , University of Leuven , 
      Celestijnenlaan 200F p.o. box 2461 , 3001 Leuven , Belgium . Email: 
      dirk.devos@kuleuven.be.
FAU - Mayer, James M
AU  - Mayer JM
AUID- ORCID: 0000-0002-3943-5250
AD  - Department of Chemistry , University of Washington , Box 351700 , Seattle , 
      Washington 98195-1700 , USA.
AD  - Department of Chemistry , Yale University , P.O. Box 208107 , New Haven , CT 
      06520-8107 , USA . Email: james.mayer@yale.edu.
LA  - eng
GR  - F32 GM099316/GM/NIGMS NIH HHS/United States
PT  - Journal Article
DEP - 20181119
PL  - England
TA  - Chem Sci
JT  - Chemical science
JID - 101545951
PMC - PMC6354900
EDAT- 2019/02/28 06:00
MHDA- 2019/02/28 06:01
PMCR- 2018/11/19
CRDT- 2019/02/28 06:00
PHST- 2018/09/18 00:00 [received]
PHST- 2018/11/17 00:00 [accepted]
PHST- 2019/02/28 06:00 [entrez]
PHST- 2019/02/28 06:00 [pubmed]
PHST- 2019/02/28 06:01 [medline]
PHST- 2018/11/19 00:00 [pmc-release]
AID - c8sc04138e [pii]
AID - 10.1039/c8sc04138e [doi]
PST - epublish
SO  - Chem Sci. 2018 Nov 19;10(5):1322-1331. doi: 10.1039/c8sc04138e. eCollection 2019 
      Feb 7.