PMID- 30835453 OWN - NLM STAT- MEDLINE DCOM- 20190322 LR - 20190322 IS - 1520-5118 (Electronic) IS - 0021-8561 (Linking) VI - 67 IP - 10 DP - 2019 Mar 13 TI - Unexpected Potential of Iso-oligosaccharides in the Generation of Important Food Odorants. PG - 2954-2962 LID - 10.1021/acs.jafc.8b07100 [doi] AB - The generation of selected Maillard-derived odorants from iso-oligosaccharides (IOSs), namely, from isomaltose, isomaltotriose, isomaltulose, and melibiose, was studied and compared with that from other oligosaccharides (maltose, lactose, and panose) and monosaccharides (glucose, galactose, and fructose). The study was carried out in binary mixtures of sugar and amino acids (glycine, proline, and cysteine) and upon wafer baking. The results indicate that IOSs induce browning and generation of the majority of the monitored odorants, in particular 4-hydroxy-2,5-dimethyl-3(2 H)-furanone, 2,3-butanedione, 2-acetyl-1-pyrroline, 2-propionyl-1-pyrroline, 2-acetylthiazole, and 2-acetyl-2-thiazoline, far more than the other oligosaccharides and to a higher or similar degree to that of the monosaccharides. Plausible mechanisms, consistent with the yields obtained from individual sugars, were proposed for the formation of the studied compounds. This newly obtained data brought for the first time evidence about the extraordinary potential of IOSs in the formation of several potent food odorants. FAU - Novotny, Ondrej AU - Novotny O AD - Nestle Research and Development Orbe , Nestec LTD. , Route de Chavornay 3 , CH-1350 Orbe , Switzerland. FAU - Dufosse, Thierry AU - Dufosse T AD - Nestle Research and Development Orbe , Nestec LTD. , Route de Chavornay 3 , CH-1350 Orbe , Switzerland. FAU - Davidek, Tomas AU - Davidek T AUID- ORCID: 0000-0002-4555-8492 AD - Nestle Research and Development Orbe , Nestec LTD. , Route de Chavornay 3 , CH-1350 Orbe , Switzerland. LA - eng PT - Journal Article DEP - 20190305 PL - United States TA - J Agric Food Chem JT - Journal of agricultural and food chemistry JID - 0374755 RN - 0 (Flavoring Agents) RN - 0 (Oligosaccharides) SB - IM MH - Cooking MH - Flavoring Agents/*chemistry MH - Food Analysis MH - Maillard Reaction MH - Odorants/*analysis MH - Oligosaccharides/*chemistry OTO - NOTNLM OT - Maillard reaction OT - browning OT - iso-oligosaccharide OT - odorant EDAT- 2019/03/06 06:00 MHDA- 2019/03/23 06:00 CRDT- 2019/03/06 06:00 PHST- 2019/03/06 06:00 [pubmed] PHST- 2019/03/23 06:00 [medline] PHST- 2019/03/06 06:00 [entrez] AID - 10.1021/acs.jafc.8b07100 [doi] PST - ppublish SO - J Agric Food Chem. 2019 Mar 13;67(10):2954-2962. doi: 10.1021/acs.jafc.8b07100. Epub 2019 Mar 5.