PMID- 30840448
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20190319
LR  - 20190319
IS  - 1520-510X (Electronic)
IS  - 0020-1669 (Linking)
VI  - 58
IP  - 6
DP  - 2019 Mar 18
TI  - Alkenone-enol-alkenone [2+2+2] Cyclotrimerization Producing Functional 
      Coordination Polymers with Excellent Adsorption Performance.
PG  - 3959-3967
LID - 10.1021/acs.inorgchem.9b00037 [doi]
AB  - [2+2+2] cycloaddition reactions are one of the most elegant routes for the 
      construction of six-membered rings. Here, we report initially the 
      alkenone-enol-alkenone [2+2+2] cycloaddition reaction and introduce the 
      cycloaddition into the system of in situ building complexes, where three novel 
      coordination polymers (CPs) with functional groups, namely [CdCl(2)(L1)] (n) 
      (1), [CdCl(2)(L2)] (n) (2), and [CdCl(2)(L3)] (n) (3), have been obtained. 
      Particularly, the new 1,2,3,4,5-pentasubtituted cyclohexanols ligands L1, L2, and 
      L3 are created from the starting chalcone derivatives via the [2+2+2] 
      cyclotrimerization. Cadmium chloride not only plays the role of constructing CPs 
      but also acts as a catalyst to promote the cycloaddition reaction. In addition, 
      benefiting from numerous exposed carbonyl and hydroxyl function groups, CPs 1-3 
      are applied to the adsorptive removal of dyes (congo red (CR) and methyl orange 
      (MO)) from aqueous solutions. As a result, 1-3 show excellent dye adsorption 
      capacity. 1 exhibits maximum CR adsorption capacity of 485.4 mg g(-1), and 3 has 
      ultrahigh MO uptake capacity of 492.6 mg g(-1). Experimental results suggest that 
      the dye removal effect derives from the interactions between dye molecules and 
      the exposed carbonyl and hydroxyl groups.
FAU - Xu, Wenjuan
AU  - Xu W
AD  - The College of Chemistry and Molecular Engineering , Zhengzhou University , 
      Zhengzhou , Henan 450001 , P. R. China.
FAU - Shao, Zhichao
AU  - Shao Z
AD  - The College of Chemistry and Molecular Engineering , Zhengzhou University , 
      Zhengzhou , Henan 450001 , P. R. China.
FAU - Huang, Chao
AU  - Huang C
AUID- ORCID: 0000-0001-8576-8024
AD  - Center for Advanced Materials Research , Zhongyuan University of Technology , 
      Zhengzhou 450007 , P. R. China.
FAU - Xu, Ruixue
AU  - Xu R
AD  - The College of Chemistry and Molecular Engineering , Zhengzhou University , 
      Zhengzhou , Henan 450001 , P. R. China.
FAU - Dong, Bingzhe
AU  - Dong B
AD  - The College of Chemistry and Molecular Engineering , Zhengzhou University , 
      Zhengzhou , Henan 450001 , P. R. China.
FAU - Hou, Hongwei
AU  - Hou H
AUID- ORCID: 0000-0003-4762-0920
AD  - The College of Chemistry and Molecular Engineering , Zhengzhou University , 
      Zhengzhou , Henan 450001 , P. R. China.
LA  - eng
PT  - Journal Article
DEP - 20190306
PL  - United States
TA  - Inorg Chem
JT  - Inorganic chemistry
JID - 0366543
EDAT- 2019/03/07 06:00
MHDA- 2019/03/07 06:01
CRDT- 2019/03/07 06:00
PHST- 2019/03/07 06:00 [pubmed]
PHST- 2019/03/07 06:01 [medline]
PHST- 2019/03/07 06:00 [entrez]
AID - 10.1021/acs.inorgchem.9b00037 [doi]
PST - ppublish
SO  - Inorg Chem. 2019 Mar 18;58(6):3959-3967. doi: 10.1021/acs.inorgchem.9b00037. Epub 
      2019 Mar 6.