PMID- 30849198
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20191120
IS  - 1520-636X (Electronic)
IS  - 0899-0042 (Linking)
VI  - 31
IP  - 5
DP  - 2019 May
TI  - Ultra-performance convergence chromatography with tandem mass 
      spectrometry-assisted method for rapid enantioseparation and determination of 
      fluazifop-butyl in tobacco and soil.
PG  - 353-361
LID - 10.1002/chir.23062 [doi]
AB  - A quick, green, and sensitive method for chiral separation and determination of 
      fluazifop-butyl enantiomers in tobacco and soil was established by 
      ultra-performance convergence chromatography with tandem mass spectrometry 
      (UPC(2) -MS/MS). The baseline separation was obtained on an ACQUITY UPC(2) 
      Trefoil CEL2 column in 4 minutes with CO(2) and methanol as mobile phase. Column 
      temperature, auto back pressure regulator pressure (ABPR), and modifier solvent 
      were optimized to obtain the best separation efficiency. Under the optimal 
      conditions, the recoveries of both enantiomers were 82.8% to 99.5% with relative 
      standard deviations (RSDs) less than 5.5% at three different concentration levels 
      in two matrices. Good coefficients of determination (R(2)  >/= 0.9976) were 
      achieved over the concentration range of 10 to 500 ng/mL. The limits of detection 
      (LODs) for all enantiomers in the two matrices varied from 1.6 to 2.1 mug/kg, and 
      the limits of quantification (LOQs) did not exceed 7.0 mug/kg. The proposed method 
      was then successfully applied to analyze authentic samples, confirming that it 
      was a green, convenient, and reliable strategy for the analysis of 
      fluazifop-butyl enantiomers in tobacco and soil.
CI  - (c) 2019 Wiley Periodicals, Inc.
FAU - Yang, Fei
AU  - Yang F
AUID- ORCID: 0000-0002-9179-375X
AD  - China National Tobacco Quality Supervision and Test Center, Zhengzhou, China.
FAU - Tang, Gangling
AU  - Tang G
AD  - China National Tobacco Quality Supervision and Test Center, Zhengzhou, China.
FAU - Liu, Shanshan
AU  - Liu S
AD  - China National Tobacco Quality Supervision and Test Center, Zhengzhou, China.
FAU - Fan, Ziyan
AU  - Fan Z
AD  - China National Tobacco Quality Supervision and Test Center, Zhengzhou, China.
FAU - Wang, Ying
AU  - Wang Y
AD  - China National Tobacco Quality Supervision and Test Center, Zhengzhou, China.
FAU - Deng, Huimin
AU  - Deng H
AD  - China National Tobacco Quality Supervision and Test Center, Zhengzhou, China.
FAU - Bian, Zhaoyang
AU  - Bian Z
AD  - China National Tobacco Quality Supervision and Test Center, Zhengzhou, China.
FAU - Li, Zhonghao
AU  - Li Z
AD  - China National Tobacco Quality Supervision and Test Center, Zhengzhou, China.
LA  - eng
PT  - Journal Article
DEP - 20190308
PL  - United States
TA  - Chirality
JT  - Chirality
JID - 8914261
OTO - NOTNLM
OT  - enantioselective separation
OT  - fluazifop-butyl
OT  - herbicide
OT  - tandem mass spectrometry
OT  - ultra-performance convergence chromatography
EDAT- 2019/03/09 06:00
MHDA- 2019/03/09 06:01
CRDT- 2019/03/09 06:00
PHST- 2018/11/19 00:00 [received]
PHST- 2019/01/07 00:00 [revised]
PHST- 2019/01/24 00:00 [accepted]
PHST- 2019/03/09 06:00 [pubmed]
PHST- 2019/03/09 06:01 [medline]
PHST- 2019/03/09 06:00 [entrez]
AID - 10.1002/chir.23062 [doi]
PST - ppublish
SO  - Chirality. 2019 May;31(5):353-361. doi: 10.1002/chir.23062. Epub 2019 Mar 8.