PMID- 30917659
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20191120
IS  - 1520-5827 (Electronic)
IS  - 0743-7463 (Linking)
VI  - 35
IP  - 17
DP  - 2019 Apr 30
TI  - Nanoscale Surface Properties of Organic Matter and Clay Minerals in Shale.
PG  - 5711-5718
LID - 10.1021/acs.langmuir.9b00157 [doi]
AB  - Surface properties of shale play an essential role in adsorption, transport, and 
      production of hydrocarbons from shale reservoirs. Nanoscale surface properties of 
      kerogen and minerals of shale were examined by a series of techniques including 
      X-ray diffraction (XRD), scanning electron microscopy (SEM), X-ray photoelectron 
      spectroscopy (XPS), Fourier transform infrared spectroscopy (FTIRS), and atomic 
      force microscopy (AFM). The results show that aluminosilicate is the main 
      component of inorganic matter, while kerogen chiefly consists of carbon. FTIRS 
      and XPS analysis indicate that the chemical bonds of the kerogen surface are O-H, 
      C-C, C-O, pyrrolic, and so on. In contrast to kerogen, illite's bonds are mainly 
      Si-O and Al-O. AFM results indicate that the adhesion force of kerogen is higher 
      than that of illite in shale. In addition, at a preloading force of 2500 nN, the 
      adhesion force of kerogen increases from 40.8 to 118.2 nN when retraction 
      velocity increases from 500 to 2500 nm/s. The adhesion forces of montmorillonite, 
      calcite, and muscovite are 33.7 +/- 6.28, 23.8 +/- 11.8, and 105.1 +/- 9.1 nN, 
      respectively. The chemical composition and bonds have a profound effect on the 
      adhesion force of shale, which further reveals the transport and adsorption 
      mechanism of methane in kerogen.
FAU - Tian, Shouceng
AU  - Tian S
AD  - State Key Laboratory of Petroleum Resources and Prospecting , China University of 
      Petroleum (Beijing) , Beijing 102249 , China.
AD  - Harvard SEAS-CUPB Joint Laboratory on Petroleum Science , 29 Oxford Street , 
      Cambridge , Massachusetts 02138 , United States.
FAU - Wang, Tianyu
AU  - Wang T
AUID- ORCID: 0000-0003-2742-2011
AD  - State Key Laboratory of Petroleum Resources and Prospecting , China University of 
      Petroleum (Beijing) , Beijing 102249 , China.
AD  - Harvard SEAS-CUPB Joint Laboratory on Petroleum Science , 29 Oxford Street , 
      Cambridge , Massachusetts 02138 , United States.
FAU - Li, Gensheng
AU  - Li G
AD  - State Key Laboratory of Petroleum Resources and Prospecting , China University of 
      Petroleum (Beijing) , Beijing 102249 , China.
AD  - Harvard SEAS-CUPB Joint Laboratory on Petroleum Science , 29 Oxford Street , 
      Cambridge , Massachusetts 02138 , United States.
FAU - Sheng, Mao
AU  - Sheng M
AD  - State Key Laboratory of Petroleum Resources and Prospecting , China University of 
      Petroleum (Beijing) , Beijing 102249 , China.
AD  - Harvard SEAS-CUPB Joint Laboratory on Petroleum Science , 29 Oxford Street , 
      Cambridge , Massachusetts 02138 , United States.
FAU - Zhang, Panpan
AU  - Zhang P
AD  - State Key Laboratory of Petroleum Resources and Prospecting , China University of 
      Petroleum (Beijing) , Beijing 102249 , China.
AD  - Harvard SEAS-CUPB Joint Laboratory on Petroleum Science , 29 Oxford Street , 
      Cambridge , Massachusetts 02138 , United States.
LA  - eng
PT  - Journal Article
DEP - 20190408
PL  - United States
TA  - Langmuir
JT  - Langmuir : the ACS journal of surfaces and colloids
JID - 9882736
EDAT- 2019/03/29 06:00
MHDA- 2019/03/29 06:01
CRDT- 2019/03/29 06:00
PHST- 2019/03/29 06:00 [pubmed]
PHST- 2019/03/29 06:01 [medline]
PHST- 2019/03/29 06:00 [entrez]
AID - 10.1021/acs.langmuir.9b00157 [doi]
PST - ppublish
SO  - Langmuir. 2019 Apr 30;35(17):5711-5718. doi: 10.1021/acs.langmuir.9b00157. Epub 
      2019 Apr 8.