PMID- 30926491 OWN - NLM STAT- MEDLINE DCOM- 20191105 LR - 20191105 IS - 1879-0003 (Electronic) IS - 0141-8130 (Linking) VI - 132 DP - 2019 Jul 1 TI - Synthesis of superabsorbent polymers based on chitosan derivative graft acrylic acid-co-acrylamide and its property testing. PG - 575-584 LID - S0141-8130(19)30759-7 [pii] LID - 10.1016/j.ijbiomac.2019.03.176 [doi] AB - A new kind of eco-friendly superabsorbent polymer was successfully synthesized using (2-pyridyl) acetyl chitosan chloride (PACS), acrylic acid (AA) and acrylamide (AM) in aqueous solution by a free radical polymerization. The effect of different reaction conditions, such as the initiator content, crosslinker content and PACS content were investigated. And the water retention, salt tolerance and reuse ability were investigated too. The chemical structure and morphological characterizations of the superabsorbent polymer were investigated by Fourier-transform infrared spectroscopy (FT-IR), X-ray diffraction (XRD), Thermogravimetric analysis (TGA) and Scanning electron microscope (SEM). The results showed that the novel superabsorbent polymer exhibits excellent water absorbency, which can absorb distilled water 615 g/g and 0.9% NaCl solution 44 g/g. At the same time, this product showed excellent water retention and reusability. The antibacterial properties of the superabsorbent polymers were tested too. The introduction of antibacterial groups also enhances antibacterial properties against Escherichia coli and Staphylococcus aureus. This kind of superabsorbent polymer has a broad application prospect. CI - Copyright (c) 2019. Published by Elsevier B.V. FAU - Fang, Shixin AU - Fang S AD - Key Laboratory of Experimental Marine Biology, Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, China; Qingdao University of Science and Technology, Qingdao 266071, China. FAU - Wang, Guangjian AU - Wang G AD - Qingdao University of Science and Technology, Qingdao 266071, China. Electronic address: wgjnet@126.com. FAU - Xing, Ronge AU - Xing R AD - Key Laboratory of Experimental Marine Biology, Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, China. FAU - Chen, Xiaolin AU - Chen X AD - Key Laboratory of Experimental Marine Biology, Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, China. FAU - Liu, Song AU - Liu S AD - Key Laboratory of Experimental Marine Biology, Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, China. FAU - Qin, Yukun AU - Qin Y AD - Key Laboratory of Experimental Marine Biology, Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, China. FAU - Li, Kecheng AU - Li K AD - Key Laboratory of Experimental Marine Biology, Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, China. FAU - Wang, Xueqin AU - Wang X AD - Key Laboratory of Experimental Marine Biology, Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, China. FAU - Li, Rongfeng AU - Li R AD - Key Laboratory of Experimental Marine Biology, Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, China. FAU - Li, Pengcheng AU - Li P AD - Key Laboratory of Experimental Marine Biology, Institute of Oceanology, Chinese Academy of Sciences, Qingdao 266071, China. Electronic address: pcli@qdio.ac.cn. LA - eng PT - Journal Article DEP - 20190326 PL - Netherlands TA - Int J Biol Macromol JT - International journal of biological macromolecules JID - 7909578 RN - 0 (Acrylamides) RN - 0 (Anti-Bacterial Agents) RN - 0 (Salts) RN - 0 (poly(acrylamide-co-acrylic acid)) RN - 059QF0KO0R (Water) RN - 9012-76-4 (Chitosan) SB - IM MH - *Absorption, Physicochemical MH - Acrylamides/*chemical synthesis/chemistry/*pharmacology MH - Anti-Bacterial Agents/*chemical synthesis/chemistry/*pharmacology MH - Chemistry Techniques, Synthetic MH - Chitosan/*chemistry MH - Escherichia coli/drug effects MH - Salts/chemistry MH - Staphylococcus aureus/drug effects MH - Water/chemistry OTO - NOTNLM OT - (2-Pyridyl) acetyl chitosan chloride OT - Antibacterial activity OT - Superabsorbent polymer EDAT- 2019/03/31 06:00 MHDA- 2019/11/07 06:00 CRDT- 2019/03/31 06:00 PHST- 2019/01/30 00:00 [received] PHST- 2019/02/27 00:00 [revised] PHST- 2019/03/25 00:00 [accepted] PHST- 2019/03/31 06:00 [pubmed] PHST- 2019/11/07 06:00 [medline] PHST- 2019/03/31 06:00 [entrez] AID - S0141-8130(19)30759-7 [pii] AID - 10.1016/j.ijbiomac.2019.03.176 [doi] PST - ppublish SO - Int J Biol Macromol. 2019 Jul 1;132:575-584. doi: 10.1016/j.ijbiomac.2019.03.176. Epub 2019 Mar 26.