PMID- 30933859
OWN - NLM
STAT- MEDLINE
DCOM- 20200824
LR  - 20200824
IS  - 1873-3336 (Electronic)
IS  - 0304-3894 (Linking)
VI  - 373
DP  - 2019 Jul 5
TI  - Metal-organic frameworks-derived MnO(2)/Mn(3)O(4) microcuboids with 
      hierarchically ordered nanosheets and Ti(3)C(2) MXene/Au NPs composites for 
      electrochemical pesticide detection.
PG  - 367-376
LID - S0304-3894(19)30365-6 [pii]
LID - 10.1016/j.jhazmat.2019.03.083 [doi]
AB  - Transition metal oxides (TMOs) derived from metal - organic frameworks (MOF) 
      combined with two-dimensional (2D) transition metal carbides possibly pave an 
      innovative pathway for designing promising biosensors. Herein, a novel 
      electrochemical sensing platform has been fabricated for ultra-sensitive 
      determination of organophosphorus pesticides (OPs), based on MOF-derived 
      MnO(2)/Mn(3)O(4) and Ti(3)C(2) MXene/Au NPs composites. Remarkably, the 
      three-dimensional (3D) MnO(2)/Mn(3)O(4) hierarchical microcuboids derived from 
      Mn-MOF are composed of vertically aligned, highly ordered nanosheets, and further 
      combined with MXene/Au NPs yields synergistic signal amplification effect, with 
      outstanding electrochemical performance, large specific surface area, and good 
      environmental biocompatibility. Under the optimum conditions, the reported 
      sensing platform AChE-Chit/MXene/Au NPs/MnO(2)/Mn(3)O(4)/GCE can be utilized to 
      detect methamidophos in a broad concentration range (10(-12)-10(-6) M), together 
      with a good linearity (R = 0.995). Besides that, the biosensor possesses a low 
      limit of detection (1.34 x 10(-13) M), which far exceeds the maximum residue 
      limits (MRLs) for methamidophos (0.01 mg/kg) established by European Union. 
      Additionally, the feasibility of the proposed biosensor for detecting 
      methamidophos in real samples has been demonstrated with excellent recoveries 
      (95.2%-101.3%). Interestingly, the unique structures and remarkable properties of 
      these composites make them attractive materials for various electrochemical 
      sensors for monitoring either pesticide residuals or other environmentally 
      deleterious chemicals.
CI  - Copyright (c) 2019 Elsevier B.V. All rights reserved.
FAU - Song, Dandan
AU  - Song D
AD  - Key Laboratory of Applied Chemistry, Department of Applied Chemistry, Yanshan 
      University, Qinhuangdao 066004, PR China.
FAU - Jiang, Xinyu
AU  - Jiang X
AD  - Key Laboratory of Applied Chemistry, Department of Applied Chemistry, Yanshan 
      University, Qinhuangdao 066004, PR China.
FAU - Li, Yanshan
AU  - Li Y
AD  - Key Laboratory of Applied Chemistry, Department of Applied Chemistry, Yanshan 
      University, Qinhuangdao 066004, PR China.
FAU - Lu, Xiong
AU  - Lu X
AD  - Key Laboratory of Applied Chemistry, Department of Applied Chemistry, Yanshan 
      University, Qinhuangdao 066004, PR China.
FAU - Luan, Sunrui
AU  - Luan S
AD  - Key Laboratory of Applied Chemistry, Department of Applied Chemistry, Yanshan 
      University, Qinhuangdao 066004, PR China.
FAU - Wang, Yuanzhe
AU  - Wang Y
AD  - Key Laboratory of Applied Chemistry, Department of Applied Chemistry, Yanshan 
      University, Qinhuangdao 066004, PR China.
FAU - Li, Yan
AU  - Li Y
AD  - Key Laboratory of Applied Chemistry, Department of Applied Chemistry, Yanshan 
      University, Qinhuangdao 066004, PR China.
FAU - Gao, Faming
AU  - Gao F
AD  - Key Laboratory of Applied Chemistry, Department of Applied Chemistry, Yanshan 
      University, Qinhuangdao 066004, PR China. Electronic address: 
      gaofaming@ysu.edu.cn.
LA  - eng
PT  - Evaluation Study
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20190323
PL  - Netherlands
TA  - J Hazard Mater
JT  - Journal of hazardous materials
JID - 9422688
RN  - 0 (Manganese Compounds)
RN  - 0 (Organothiophosphorus Compounds)
RN  - 0 (Oxides)
RN  - 0 (Pesticides)
RN  - 12070-08-5 (titanium carbide)
RN  - 64J2OA7MH3 (manganese oxide)
RN  - 7440-57-5 (Gold)
RN  - 8Z083FM94W (methamidophos)
RN  - D1JT611TNE (Titanium)
SB  - IM
MH  - *Electrochemical Techniques
MH  - Gold/chemistry
MH  - Manganese Compounds/*chemistry
MH  - Nanostructures/*chemistry/ultrastructure
MH  - Organothiophosphorus Compounds/analysis
MH  - Oxides/*chemistry
MH  - Pesticides/*analysis
MH  - Titanium/*chemistry
OTO - NOTNLM
OT  - AChE biosensor
OT  - MOF-derived MnO(2)/Mn(3)O(4)
OT  - Methamidophos
OT  - Ti(3)C(2)MXene/Au NPs
EDAT- 2019/04/02 06:00
MHDA- 2020/08/25 06:00
CRDT- 2019/04/02 06:00
PHST- 2018/11/19 00:00 [received]
PHST- 2019/03/09 00:00 [revised]
PHST- 2019/03/18 00:00 [accepted]
PHST- 2019/04/02 06:00 [pubmed]
PHST- 2020/08/25 06:00 [medline]
PHST- 2019/04/02 06:00 [entrez]
AID - S0304-3894(19)30365-6 [pii]
AID - 10.1016/j.jhazmat.2019.03.083 [doi]
PST - ppublish
SO  - J Hazard Mater. 2019 Jul 5;373:367-376. doi: 10.1016/j.jhazmat.2019.03.083. Epub 
      2019 Mar 23.