PMID- 30960856 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20200930 IS - 2073-4360 (Electronic) IS - 2073-4360 (Linking) VI - 10 IP - 8 DP - 2018 Aug 20 TI - Bagasse Cellulose Grafted with an Amino-Terminated Hyperbranched Polymer for the Removal of Cr(VI) from Aqueous Solution. LID - 10.3390/polym10080931 [doi] LID - 931 AB - A novel bio-adsorbent was fabricated via grafting an amino-terminated hyperbranched polymer (HBP-NH(2)) onto bagasse cellulose. The morphology and microstructure of the HBP-NH(2)-grafted bagasse cellulose (HBP-g-BC) were characterized and its adsorption capacity for Cr(VI) ions in aqueous solutions was investigated. The rough surface structure of HBP-g-BC that is beneficial for improving the adsorption capacity was observed by scanning electron microscopy (SEM). The grafting reaction was confirmed by Fourier-transform infrared (FT-IR) spectroscopy. The adsorbent performance was shown to be better with a lower pH value, a higher adsorbent dosage, or a higher initial Cr(VI) concentration. Moreover, the kinetics study revealed that the adsorption behavior followed a pseudo-second-order model. The isotherm results showed that the adsorption data could be well-fitted by the Langmuir, Freundlich, or Temkin models. Moreover, HBP-g-BC could maintain 74.4% of the initial removal rate even after five cycles of regeneration. Thus, the high potential of HBP-g-BC as a bio-adsorbent for heavy metal removal has been demonstrated. FAU - Xia, Lu AU - Xia L AD - School of Chemistry and Chemical Engineering, Guangxi University for Nationalities, Nanning 530006, China. leiwin@163.com. AD - Guangxi Key Laboratory of Chemistry and Engineering of Forest Products, Guangxi University for Nationalities, Nanning 530006, China. leiwin@163.com. FAU - Huang, Zhonghang AU - Huang Z AD - School of Chemistry and Chemical Engineering, Guangxi University for Nationalities, Nanning 530006, China. zhfp1666@163.com. AD - Guangxi Key Laboratory of Chemistry and Engineering of Forest Products, Guangxi University for Nationalities, Nanning 530006, China. zhfp1666@163.com. FAU - Zhong, Lei AU - Zhong L AD - School of Chemistry and Chemical Engineering, Guangxi University for Nationalities, Nanning 530006, China. leiwin@gmail.com. AD - Guangxi Key Laboratory Cultivation Base for Polysaccharide Materials and Modifications, Guangxi University for Nationalities, Nanning 530006, China. leiwin@gmail.com. FAU - Xie, Fengwei AU - Xie F AUID- ORCID: 0000-0002-2033-082X AD - Institute of Advanced Study, University of Warwick, Coventry CV4 7HS, UK. D.Xie.2@warwick.ac.uk. AD - International Institute for Nanocomposites Manufacturing (IINM), WMG, University of Warwick, Coventry CV4 7AL, UK. D.Xie.2@warwick.ac.uk. FAU - Tang, Chak Yin AU - Tang CY AD - Department of Industrial and Systems Engineering, The Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong, China. cy.tang@polyu.edu.hk. FAU - Tsui, Chi Pong AU - Tsui CP AD - Department of Industrial and Systems Engineering, The Hong Kong Polytechnic University, Hung Hom, Kowloon, Hong Kong, China. gary.c.p.tsui@polyu.edu.hk. LA - eng GR - 41461092/National Natural Science Foundation of China/ GR - GXUN-CHXZS2016117/R&D Funds for the Postgraduate Students of Guangxi University for Nationalities/ PT - Journal Article DEP - 20180820 PL - Switzerland TA - Polymers (Basel) JT - Polymers JID - 101545357 PMC - PMC6403998 OTO - NOTNLM OT - Cr(VI) removal OT - adsorption capacity OT - bagasse cellulose OT - hyperbranched polymer COIS- The authors declare no conflict of interest. EDAT- 2019/04/10 06:00 MHDA- 2019/04/10 06:01 PMCR- 2018/08/20 CRDT- 2019/04/10 06:00 PHST- 2018/08/01 00:00 [received] PHST- 2018/08/15 00:00 [revised] PHST- 2018/08/18 00:00 [accepted] PHST- 2019/04/10 06:00 [entrez] PHST- 2019/04/10 06:00 [pubmed] PHST- 2019/04/10 06:01 [medline] PHST- 2018/08/20 00:00 [pmc-release] AID - polym10080931 [pii] AID - polymers-10-00931 [pii] AID - 10.3390/polym10080931 [doi] PST - epublish SO - Polymers (Basel). 2018 Aug 20;10(8):931. doi: 10.3390/polym10080931.