PMID- 30961327 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20231006 IS - 2073-4360 (Electronic) IS - 2073-4360 (Linking) VI - 10 IP - 12 DP - 2018 Dec 18 TI - Inkjet Printable and Self-Curable Disperse Dyes/P(St-BA-MAA) Nanosphere Inks for Both Hydrophilic and Hydrophobic Fabrics. LID - 10.3390/polym10121402 [doi] LID - 1402 AB - Low-water-soluble disperse dyes possess a broad color gamut and good durability, but they need chemical or physical modification before being used in inks and can only be applied to several kinds of hydrophobic fabrics. In this work, disperse dyes/P(St-BA-MAA) nanospheres (known as DPN) absorbed by sodium nitrilotriacetate (known as NTA@DPN) were prepared and applied into ink formulations, which exhibited high dye fixation, long-term stability and self-curable ability without addition of any binder. Transmission electron microscopy (TEM) images showed the nanospheres have homogeneous core-shell spherical shape and the average diameter increased by 20.6 nm after coloration. X-ray diffraction (XRD), Fourier transform infrared spectrum (FTIR), and differential scanning calorimetry (DSC) measurements illustrated the interaction between dyes and nanospheres and indicated that the colored nanospheres contained both dye molecules and crystalline dyes. The Zeta potential and particle size measurements demonstrated that the dispersion stability was improved when sodium nitrilotriacetate (NTA) was absorbed onto DPN. The rheological behavior of the NTA@DPN inks was Newtonian and desired droplet formation was achieved at the viscosity of 4.23 mPa.s. Both hydrophilic cotton and hydrophobic polyester fabrics were cationic modified before used, which had an excellent image quality and desired rubbing fastness after inkjet printing. Scanning electron microscope (SEM) images showed NTA@DPN formed stable deposits on the surface of modified fibers and could self-cure to form continuous film coating on the fiber surface after being baked at 150 degrees C without addition of any binder. FAU - Song, Yawei AU - Song Y AD - Fiber Materials and Modern Textiles of the Growing Base for State Key Laboratory, Qingdao University, 308 Ningxia Road, Qingdao 266071, China. 15864737168@163.com. AD - School of Textiles & Clothing, Qingdao University, 308 Ningxia Road, Qingdao 266071, China. 15864737168@163.com. AD - Collaborative Innovation Center for Eco-Textiles of Shandong Province, 308 Ningxia Road, Qingdao 266071, China. 15864737168@163.com. FAU - Fang, Kuanjun AU - Fang K AD - Fiber Materials and Modern Textiles of the Growing Base for State Key Laboratory, Qingdao University, 308 Ningxia Road, Qingdao 266071, China. 13808980221@163.com. AD - School of Textiles & Clothing, Qingdao University, 308 Ningxia Road, Qingdao 266071, China. 13808980221@163.com. AD - Collaborative Innovation Center for Eco-Textiles of Shandong Province, 308 Ningxia Road, Qingdao 266071, China. 13808980221@163.com. FAU - Ren, Yanfei AU - Ren Y AD - Fiber Materials and Modern Textiles of the Growing Base for State Key Laboratory, Qingdao University, 308 Ningxia Road, Qingdao 266071, China. tjpuryf@126.com. AD - School of Textiles & Clothing, Qingdao University, 308 Ningxia Road, Qingdao 266071, China. tjpuryf@126.com. AD - Collaborative Innovation Center for Eco-Textiles of Shandong Province, 308 Ningxia Road, Qingdao 266071, China. tjpuryf@126.com. FAU - Tang, Zhiyuan AU - Tang Z AD - Fiber Materials and Modern Textiles of the Growing Base for State Key Laboratory, Qingdao University, 308 Ningxia Road, Qingdao 266071, China. 18363995943@163.com. AD - School of Textiles & Clothing, Qingdao University, 308 Ningxia Road, Qingdao 266071, China. 18363995943@163.com. AD - Collaborative Innovation Center for Eco-Textiles of Shandong Province, 308 Ningxia Road, Qingdao 266071, China. 18363995943@163.com. FAU - Wang, Rongqing AU - Wang R AD - Fiber Materials and Modern Textiles of the Growing Base for State Key Laboratory, Qingdao University, 308 Ningxia Road, Qingdao 266071, China. 17864283938@163.com. AD - School of Textiles & Clothing, Qingdao University, 308 Ningxia Road, Qingdao 266071, China. 17864283938@163.com. AD - Collaborative Innovation Center for Eco-Textiles of Shandong Province, 308 Ningxia Road, Qingdao 266071, China. 17864283938@163.com. FAU - Chen, Weichao AU - Chen W AD - Fiber Materials and Modern Textiles of the Growing Base for State Key Laboratory, Qingdao University, 308 Ningxia Road, Qingdao 266071, China. chenwc@qdu.edu.cn. AD - School of Textiles & Clothing, Qingdao University, 308 Ningxia Road, Qingdao 266071, China. chenwc@qdu.edu.cn. AD - Collaborative Innovation Center for Eco-Textiles of Shandong Province, 308 Ningxia Road, Qingdao 266071, China. chenwc@qdu.edu.cn. FAU - Xie, Ruyi AU - Xie R AD - Fiber Materials and Modern Textiles of the Growing Base for State Key Laboratory, Qingdao University, 308 Ningxia Road, Qingdao 266071, China. xry1228@126.com. AD - School of Textiles & Clothing, Qingdao University, 308 Ningxia Road, Qingdao 266071, China. xry1228@126.com. AD - Collaborative Innovation Center for Eco-Textiles of Shandong Province, 308 Ningxia Road, Qingdao 266071, China. xry1228@126.com. FAU - Shi, Zhen AU - Shi Z AD - Fiber Materials and Modern Textiles of the Growing Base for State Key Laboratory, Qingdao University, 308 Ningxia Road, Qingdao 266071, China. shizhen988@126.com. AD - School of Textiles & Clothing, Qingdao University, 308 Ningxia Road, Qingdao 266071, China. shizhen988@126.com. AD - Collaborative Innovation Center for Eco-Textiles of Shandong Province, 308 Ningxia Road, Qingdao 266071, China. shizhen988@126.com. FAU - Hao, Longyun AU - Hao L AD - Fiber Materials and Modern Textiles of the Growing Base for State Key Laboratory, Qingdao University, 308 Ningxia Road, Qingdao 266071, China. hly1978@163.com. AD - School of Textiles & Clothing, Qingdao University, 308 Ningxia Road, Qingdao 266071, China. hly1978@163.com. AD - Collaborative Innovation Center for Eco-Textiles of Shandong Province, 308 Ningxia Road, Qingdao 266071, China. hly1978@163.com. LA - eng GR - No. 2017YFB03098/National Key Technology R&D Program,China/ GR - No. 2017CXGC1006/Shandong Province Key Technology R&D Program/ PT - Journal Article DEP - 20181218 PL - Switzerland TA - Polymers (Basel) JT - Polymers JID - 101545357 PMC - PMC6401999 OTO - NOTNLM OT - P(St-BA-MAA) OT - color polymer nanospheres OT - disperse dyes OT - inkjet printing OT - self-curable OT - stability COIS- The authors declare no conflicts of interest. EDAT- 2019/04/10 06:00 MHDA- 2019/04/10 06:01 PMCR- 2018/12/18 CRDT- 2019/04/10 06:00 PHST- 2018/11/21 00:00 [received] PHST- 2018/12/13 00:00 [revised] PHST- 2018/12/14 00:00 [accepted] PHST- 2019/04/10 06:00 [entrez] PHST- 2019/04/10 06:00 [pubmed] PHST- 2019/04/10 06:01 [medline] PHST- 2018/12/18 00:00 [pmc-release] AID - polym10121402 [pii] AID - polymers-10-01402 [pii] AID - 10.3390/polym10121402 [doi] PST - epublish SO - Polymers (Basel). 2018 Dec 18;10(12):1402. doi: 10.3390/polym10121402.