PMID- 31022940
OWN - NLM
STAT- MEDLINE
DCOM- 20190816
LR  - 20200225
IS  - 1420-3049 (Electronic)
IS  - 1420-3049 (Linking)
VI  - 24
IP  - 8
DP  - 2019 Apr 24
TI  - Excellent Temperature-Control Based on Reversible Thermochromic Materials for 
      Light-Driven Phase Change Materials System.
LID - 10.3390/molecules24081623 [doi]
LID - 1623
AB  - Light-driven phase change materials (PCMs) have received significant attention 
      due to their capacity to convert visible light into thermal energy, storing it as 
      latent heat. However, continuous photo-thermal conversion can cause the PCMs to 
      reach high thermal equilibrium temperatures after phase transition. In our study, 
      a novel light-driven phase change material system with temperature-control 
      properties was constructed using a thermochromic compound. Thermochromic phase 
      change materials (TC-PCMs) were prepared by introducing 
      2-anilino-6-dibutylamino-3-methylfluoran (ODB-2) and bisphenol A (BPA) into 
      1-hexadecanol (1-HD) in various proportions. Photo-thermal conversion performance 
      was investigated with solar radiation (low power of 0.09 W/cm(2)) and a xenon 
      lamp (at a high power of 0.14 W/cm(2)). The TC-PCMs showed a low equilibrium 
      temperature due to variations in absorbance. Specifically, the temperature of 
      TC-PCM(180) (ODB-2, bisphenol A and 1-HD ratio 1:2:180) could stabilize at 54  degrees C 
      approximately. TC-PCMs exhibited reversibility and repeatability after 20 
      irradiation and cooling cycles.
FAU - Ren, Caixia
AU  - Ren C
AD  - State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 
      116024, China. 13127037258@163.com.
FAU - Liu, Fangfang
AU  - Liu F
AD  - State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 
      116024, China. liufangfang@mail.dlut.edu.cn.
FAU - Umair, Malik Muhammad
AU  - Umair MM
AUID- ORCID: 0000-0003-3307-3049
AD  - State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 
      116024, China. umairdut@mail.dlut.edu.cn.
FAU - Jin, Xin
AU  - Jin X
AD  - Eco-chemical Engineering Cooperative Innovation Center of Shandong, Qingdao 
      University of Science and Technology, Qingdao 266042, China. jinx1971@163.com.
FAU - Zhang, Shufen
AU  - Zhang S
AD  - State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 
      116024, China. zhangshf@dlut.edu.cn.
FAU - Tang, Bingtao
AU  - Tang B
AUID- ORCID: 0000-0001-5201-9924
AD  - State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian 
      116024, China. tangbt@dlut.edu.cn.
AD  - Eco-chemical Engineering Cooperative Innovation Center of Shandong, Qingdao 
      University of Science and Technology, Qingdao 266042, China. tangbt@dlut.edu.cn.
LA  - eng
GR  - 21576039, 21878043, 21536002, 21421005 and U1608223/National Natural Science 
      Foundation of China/
GR  - IRT_13R06/Program for Innovative Research Team in University/
GR  - DUT18ZD218/the Fundamental Research Funds for the Central Universities/
PT  - Journal Article
DEP - 20190424
PL  - Switzerland
TA  - Molecules
JT  - Molecules (Basel, Switzerland)
JID - 100964009
RN  - 0 (2-phenylamino-3-methyl-6-di-n-butylaminofluoran)
RN  - 0 (Aniline Compounds)
RN  - 0 (Benzhydryl Compounds)
RN  - 0 (Fatty Alcohols)
RN  - 0 (Fluoresceins)
RN  - 0 (Phenols)
RN  - 936JST6JCN (cetyl alcohol)
RN  - MLT3645I99 (bisphenol A)
MH  - Aniline Compounds/*chemical synthesis/chemistry/radiation effects
MH  - Benzhydryl Compounds/*chemical synthesis/chemistry/radiation effects
MH  - Fatty Alcohols/*chemical synthesis/chemistry/radiation effects
MH  - Fluoresceins/*chemical synthesis/chemistry/radiation effects
MH  - Hot Temperature
MH  - Light
MH  - Phase Transition/radiation effects
MH  - Phenols/*chemical synthesis/chemistry/radiation effects
MH  - Temperature
PMC - PMC6526475
OTO - NOTNLM
OT  - phase change materials
OT  - photo-thermal conversion
OT  - temperature control
OT  - thermochromic compound
COIS- The authors declare no conflict of interest.
EDAT- 2019/04/27 06:00
MHDA- 2019/08/17 06:00
PMCR- 2019/04/24
CRDT- 2019/04/27 06:00
PHST- 2019/02/28 00:00 [received]
PHST- 2019/04/22 00:00 [revised]
PHST- 2019/04/23 00:00 [accepted]
PHST- 2019/04/27 06:00 [entrez]
PHST- 2019/04/27 06:00 [pubmed]
PHST- 2019/08/17 06:00 [medline]
PHST- 2019/04/24 00:00 [pmc-release]
AID - molecules24081623 [pii]
AID - molecules-24-01623 [pii]
AID - 10.3390/molecules24081623 [doi]
PST - epublish
SO  - Molecules. 2019 Apr 24;24(8):1623. doi: 10.3390/molecules24081623.