PMID- 31036228
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20191120
IS  - 1873-3573 (Electronic)
IS  - 0039-9140 (Linking)
VI  - 200
DP  - 2019 Aug 1
TI  - An ESIPT-based fluorescent probe for the detection of phosgene in the solution 
      and gas phases.
PG  - 78-83
LID - S0039-9140(19)30247-4 [pii]
LID - 10.1016/j.talanta.2019.03.003 [doi]
AB  - Phosgene is a highly toxic gas that poses a serious threat to public health and 
      safety. Herein, we describe the preparation of a ratiometric fluorescence probe 
      (Pi) bearing hydroxyl and imidazole moieties as recognition sites, and employ it 
      for the excited-state intramolecular proton transfer-based (ESIPT-based) 
      detection of phosgene. It is the first time that hydroxyl and imidazole have been 
      exploited as recognition sites for phosgene. In the presence of phosgene, Pi 
      undergoes sequential nucleophilic substitution and cyclization reactions that 
      facilitate a rapid response, high selectivity, and excellent sensitivity 
      (detection limit = 0.14 muM). The sensing mechanism was verified by (1)H NMR 
      spectroscopy and high-resolution mass spectrometry. Furthermore, we fabricated a 
      fluorescent test strip (FTS-Pi) for the detection of phosgene in the gas phase 
      that undergoes a fluorescence color change, from green to blue, under 365 nm UV 
      light in the presence of phosgene, which is easily observed with the naked eye.
CI  - Copyright (c) 2019 Elsevier B.V. All rights reserved.
FAU - Wu, Cuiyan
AU  - Wu C
AD  - Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research 
      (Ministry of Education), College of Chemistry and Chemical Engineering, Hunan 
      Normal University, Changsha 410081, PR China.
FAU - Xu, Hai
AU  - Xu H
AD  - Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research 
      (Ministry of Education), College of Chemistry and Chemical Engineering, Hunan 
      Normal University, Changsha 410081, PR China.
FAU - Li, Yaqian
AU  - Li Y
AD  - Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research 
      (Ministry of Education), College of Chemistry and Chemical Engineering, Hunan 
      Normal University, Changsha 410081, PR China.
FAU - Xie, Ruihua
AU  - Xie R
AD  - Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research 
      (Ministry of Education), College of Chemistry and Chemical Engineering, Hunan 
      Normal University, Changsha 410081, PR China.
FAU - Li, Peijuan
AU  - Li P
AD  - Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research 
      (Ministry of Education), College of Chemistry and Chemical Engineering, Hunan 
      Normal University, Changsha 410081, PR China; Key Laboratory of Functional 
      Organometallic Materials of College of Hunan Province, College of Chemistry and 
      Materials Science, Hengyang Normal University, Hengyang 421008, PR China.
FAU - Pang, Xiao
AU  - Pang X
AD  - Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research 
      (Ministry of Education), College of Chemistry and Chemical Engineering, Hunan 
      Normal University, Changsha 410081, PR China.
FAU - Zhou, Zile
AU  - Zhou Z
AD  - Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research 
      (Ministry of Education), College of Chemistry and Chemical Engineering, Hunan 
      Normal University, Changsha 410081, PR China.
FAU - Gu, Biao
AU  - Gu B
AD  - Key Laboratory of Functional Organometallic Materials of College of Hunan 
      Province, College of Chemistry and Materials Science, Hengyang Normal University, 
      Hengyang 421008, PR China.
FAU - Li, Haitao
AU  - Li H
AD  - Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research 
      (Ministry of Education), College of Chemistry and Chemical Engineering, Hunan 
      Normal University, Changsha 410081, PR China. Electronic address: 
      haitao-li@hunnu.edu.cn.
FAU - Zhang, Youyu
AU  - Zhang Y
AD  - Key Laboratory of Chemical Biology and Traditional Chinese Medicine Research 
      (Ministry of Education), College of Chemistry and Chemical Engineering, Hunan 
      Normal University, Changsha 410081, PR China.
LA  - eng
PT  - Journal Article
DEP - 20190302
PL  - Netherlands
TA  - Talanta
JT  - Talanta
JID - 2984816R
OTO - NOTNLM
OT  - Detection
OT  - Fluorescent probe
OT  - Fluorescent test strip
OT  - Phosgene
OT  - Ratiometric
EDAT- 2019/05/01 06:00
MHDA- 2019/05/01 06:01
CRDT- 2019/05/01 06:00
PHST- 2018/12/19 00:00 [received]
PHST- 2019/02/26 00:00 [revised]
PHST- 2019/03/01 00:00 [accepted]
PHST- 2019/05/01 06:00 [entrez]
PHST- 2019/05/01 06:00 [pubmed]
PHST- 2019/05/01 06:01 [medline]
AID - S0039-9140(19)30247-4 [pii]
AID - 10.1016/j.talanta.2019.03.003 [doi]
PST - ppublish
SO  - Talanta. 2019 Aug 1;200:78-83. doi: 10.1016/j.talanta.2019.03.003. Epub 2019 Mar 
      2.