PMID- 31070923
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20190723
IS  - 1520-5827 (Electronic)
IS  - 0743-7463 (Linking)
VI  - 35
IP  - 22
DP  - 2019 Jun 4
TI  - Interdiffusive Surfactant Procedure for the Preparation of Nanoarchitectured 
      Porous Films: Application to the Growth of Titania Thin Films on Silicon 
      Substrates.
PG  - 7169-7174
LID - 10.1021/acs.langmuir.9b00960 [doi]
AB  - Herein is reported the preparation of nanostructured mesoporous supported films, 
      in this case, titanium dioxide nanoparticles on silicon wafer, according to a new 
      approach taking place in two consecutive deposition steps: (i) coating of a 
      homogeneous and continuous layer of a surfactant on the selected support and (ii) 
      building up of a second layer of the fresh metal-oxide gel precursor, followed by 
      thermal treatment to generate porosity. This approach represents an alternative 
      way to soft-template procedures, as for instance, the largely applied 
      evaporation-induced self-assembly (EISA) method, which typically consists of a 
      single-step deposition of the mixture of gel precursor and surfactant used as a 
      soft template to create porosity. The main advantage of the procedure reported 
      here compared to the EISA method is the possibility of reaching tunable textural 
      characteristics along the growing film (pore size, shape, and distribution of 
      pores) by using gels with nanoparticles preformed at different stages via a 
      simple regulation of the residence time of the precursors deposited on the 
      support containing the surfactant.
FAU - Perez-Carvajal, Javier
AU  - Perez-Carvajal J
AD  - Materials Science Institute of Madrid, CSIC , c/ Sor Juana Ines de la Cruz, 3, 
      Cantoblanco , 28049 Madrid , Spain.
FAU - Aranda, Pilar
AU  - Aranda P
AUID- ORCID: 0000-0003-2196-0476
AD  - Materials Science Institute of Madrid, CSIC , c/ Sor Juana Ines de la Cruz, 3, 
      Cantoblanco , 28049 Madrid , Spain.
FAU - Boissiere, Cedric
AU  - Boissiere C
AUID- ORCID: 0000-0003-1212-6850
AD  - College de France and Pierre and Marie Curie University , 11 Place Marcelin 
      Berthelot , 75231 Paris , France.
FAU - Sanchez, Clement
AU  - Sanchez C
AUID- ORCID: 0000-0002-6426-4844
AD  - College de France and Pierre and Marie Curie University , 11 Place Marcelin 
      Berthelot , 75231 Paris , France.
FAU - Ruiz-Hitzky, Eduardo
AU  - Ruiz-Hitzky E
AUID- ORCID: 0000-0003-4383-7698
AD  - Materials Science Institute of Madrid, CSIC , c/ Sor Juana Ines de la Cruz, 3, 
      Cantoblanco , 28049 Madrid , Spain.
LA  - eng
PT  - Journal Article
DEP - 20190522
PL  - United States
TA  - Langmuir
JT  - Langmuir : the ACS journal of surfaces and colloids
JID - 9882736
EDAT- 2019/05/10 06:00
MHDA- 2019/05/10 06:01
CRDT- 2019/05/10 06:00
PHST- 2019/05/10 06:00 [pubmed]
PHST- 2019/05/10 06:01 [medline]
PHST- 2019/05/10 06:00 [entrez]
AID - 10.1021/acs.langmuir.9b00960 [doi]
PST - ppublish
SO  - Langmuir. 2019 Jun 4;35(22):7169-7174. doi: 10.1021/acs.langmuir.9b00960. Epub 
      2019 May 22.