PMID- 31071523
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20191120
IS  - 1095-7103 (Electronic)
IS  - 0021-9797 (Linking)
VI  - 550
DP  - 2019 Aug 15
TI  - Immobilization of rubber additive on graphene for high-performance rubber 
      composites.
PG  - 190-198
LID - S0021-9797(19)30544-2 [pii]
LID - 10.1016/j.jcis.2019.05.006 [doi]
AB  - It is still a challenge to achieve simultaneous improvements in aging resistance, 
      mechanical strength, thermal conductivity and dielectric constant of rubber 
      composites via incorporation of graphene obtained by conventional methods. 
      Herein, an effective and green method was proposed to simultaneously reduce and 
      functionalize graphene oxide (GO) with 2-mercaptobenzimidazole (antioxidant MB) 
      via a one-pot method. GO was successfully reduced by MB which was also chemically 
      grafted on the reduced GO (G-MB). G-MB sheets were uniformly dispersed in rubber 
      with strong interfacial interaction, and graphene-graphene conductive paths were 
      formed through intermolecular H-bonding between the grafted antioxidant 
      molecules. Consequently, rubber composites with G-MB showed higher thermal 
      conductivity, mechanical strength and dielectric constant than rubber composites 
      with hydrazine hydrate reduced GO (rGO). Moreover, the thermo-oxidative aging 
      resistance of rubber composites with G-MB was also superior to that of rubber 
      composites with rGO because of the elimination of blooming effect of the grafted 
      MB molecules. Thus, this work may open a new way for the eco-friendly 
      functionalization and reduction of GO and may boost the development of 
      high-performance, functional graphene-elastomer composites.
CI  - Copyright (c) 2019 Elsevier Inc. All rights reserved.
FAU - Zhong, Bangchao
AU  - Zhong B
AD  - College of Chemistry, Chongqing Normal University, Chongqing 401331, China; 
      Department of Polymer Materials and Engineering, South China University of 
      Technology, Guangzhou 510640, China. Electronic address: pcbczhong@163.com.
FAU - Luo, Yongyue
AU  - Luo Y
AD  - Agricultural Products Processing Research Institute, Chinese Academy of Tropical 
      Agricultural Sciences (CATAS), Zhanjiang 524001, China.
FAU - Chen, Wanjuan
AU  - Chen W
AD  - College of Materials Science and Energy Engineering, Foshan University, Foshan 
      528000, China.
FAU - Luo, Yuanfang
AU  - Luo Y
AD  - Department of Polymer Materials and Engineering, South China University of 
      Technology, Guangzhou 510640, China.
FAU - Hu, Dechao
AU  - Hu D
AD  - Department of Polymer Materials and Engineering, South China University of 
      Technology, Guangzhou 510640, China.
FAU - Dong, Huanhuan
AU  - Dong H
AD  - Department of Polymer Materials and Engineering, South China University of 
      Technology, Guangzhou 510640, China.
FAU - Jia, Zhixin
AU  - Jia Z
AD  - Department of Polymer Materials and Engineering, South China University of 
      Technology, Guangzhou 510640, China. Electronic address: 18620901980m@sina.cn.
FAU - Jia, Demin
AU  - Jia D
AD  - Department of Polymer Materials and Engineering, South China University of 
      Technology, Guangzhou 510640, China.
LA  - eng
PT  - Journal Article
DEP - 20190502
PL  - United States
TA  - J Colloid Interface Sci
JT  - Journal of colloid and interface science
JID - 0043125
OTO - NOTNLM
OT  - Aging resistance
OT  - Graphene
OT  - Interfacial enhancement
OT  - Rubber nanocomposites
OT  - Thermal conductivity
EDAT- 2019/05/10 06:00
MHDA- 2019/05/10 06:01
CRDT- 2019/05/10 06:00
PHST- 2019/03/14 00:00 [received]
PHST- 2019/04/28 00:00 [revised]
PHST- 2019/05/01 00:00 [accepted]
PHST- 2019/05/10 06:00 [pubmed]
PHST- 2019/05/10 06:01 [medline]
PHST- 2019/05/10 06:00 [entrez]
AID - S0021-9797(19)30544-2 [pii]
AID - 10.1016/j.jcis.2019.05.006 [doi]
PST - ppublish
SO  - J Colloid Interface Sci. 2019 Aug 15;550:190-198. doi: 
      10.1016/j.jcis.2019.05.006. Epub 2019 May 2.