PMID- 31083926
OWN - NLM
STAT- MEDLINE
DCOM- 20190917
LR  - 20190917
IS  - 1520-5851 (Electronic)
IS  - 0013-936X (Linking)
VI  - 53
IP  - 11
DP  - 2019 Jun 4
TI  - Molecular Characterization and Source Identification of Atmospheric Particulate 
      Organosulfates Using Ultrahigh Resolution Mass Spectrometry.
PG  - 6192-6202
LID - 10.1021/acs.est.9b02628 [doi]
AB  - Organosulfates (OSs) have been observed as substantial constituents of 
      atmospheric organic aerosol (OA) in a wide range of environments; however, the 
      chemical composition, sources, and formation mechanism of OSs are still not well 
      understood. In this study, we first created an "OS precursor map" based on the 
      elemental composition of previous OS chamber experiments. Then, according to this 
      "OS precursor map", we estimated the possible sources and molecular structures of 
      OSs in atmospheric PM(2.5) (particles with aerodynamic diameter </= 2.5 mum) 
      samples, which were collected in urban areas of Beijing (China) and Mainz 
      (Germany) and analyzed by ultrahigh-performance liquid chromatography (UHPLC) 
      coupled with an Orbitrap mass spectrometer. On the basis of the "OS precursor 
      map", together with the polarity information provided by UHPLC, OSs in Mainz 
      samples are suggested to be mainly derived from isoprene/glyoxal or other unknown 
      small polar organic compounds, while OSs in Beijing samples were generated from 
      both isoprene/glyoxal and anthropogenic sources (e.g., long-chain alkanes and 
      aromatics). The nitrooxy-OSs in the clean aerosol samples were mainly derived 
      from monoterpenes, while much fewer monoterpene-derived nitrooxy-OSs were 
      obtained in the polluted aerosol samples, showing that nitrooxy-OS formation is 
      affected by different precursors in clean and polluted air conditions.
FAU - Wang, Kai
AU  - Wang K
AD  - Key Laboratory of Aerosol Chemistry and Physics, State Key Laboratory of Loess 
      and Quaternary Geology, and Center for Excellence in Quaternary Science and 
      Global Change , Institute of Earth Environment, Chinese Academy of Sciences , 
      Xi'an 710061 , China.
AD  - Institute of Inorganic and Analytical Chemistry , Johannes Gutenberg University 
      Mainz , Duesbergweg 10-14 , 55128 Mainz , Germany.
AD  - Department of Chemistry , Aarhus University , Langelandsgade 140 , DK-8000 Aarhus 
      C , Denmark.
FAU - Zhang, Yun
AU  - Zhang Y
AD  - Institute of Inorganic and Analytical Chemistry , Johannes Gutenberg University 
      Mainz , Duesbergweg 10-14 , 55128 Mainz , Germany.
FAU - Huang, Ru-Jin
AU  - Huang RJ
AUID- ORCID: 0000-0002-4907-9616
AD  - Key Laboratory of Aerosol Chemistry and Physics, State Key Laboratory of Loess 
      and Quaternary Geology, and Center for Excellence in Quaternary Science and 
      Global Change , Institute of Earth Environment, Chinese Academy of Sciences , 
      Xi'an 710061 , China.
AD  - Open Studio for Oceanic-Continental Climate and Environment Changes , Pilot 
      National Laboratory for Marine Science and Technology (Qingdao) , Qingdao 266061 
      , China.
FAU - Wang, Meng
AU  - Wang M
AD  - Key Laboratory of Aerosol Chemistry and Physics, State Key Laboratory of Loess 
      and Quaternary Geology, and Center for Excellence in Quaternary Science and 
      Global Change , Institute of Earth Environment, Chinese Academy of Sciences , 
      Xi'an 710061 , China.
FAU - Ni, Haiyan
AU  - Ni H
AD  - Key Laboratory of Aerosol Chemistry and Physics, State Key Laboratory of Loess 
      and Quaternary Geology, and Center for Excellence in Quaternary Science and 
      Global Change , Institute of Earth Environment, Chinese Academy of Sciences , 
      Xi'an 710061 , China.
FAU - Kampf, Christopher J
AU  - Kampf CJ
AD  - Multiphase Chemistry Department , Max Planck Institute for Chemistry , 
      Hahn-Meitner-Weg 1 , 55128 Mainz , Germany.
AD  - Institute of Organic Chemistry , Johannes Gutenberg University Mainz , 
      Duesbergweg 10-14 , 55128 Mainz , Germany.
FAU - Cheng, Yafang
AU  - Cheng Y
AD  - Multiphase Chemistry Department , Max Planck Institute for Chemistry , 
      Hahn-Meitner-Weg 1 , 55128 Mainz , Germany.
FAU - Bilde, Merete
AU  - Bilde M
AD  - Department of Chemistry , Aarhus University , Langelandsgade 140 , DK-8000 Aarhus 
      C , Denmark.
FAU - Glasius, Marianne
AU  - Glasius M
AUID- ORCID: 0000-0002-4404-6989
AD  - Department of Chemistry , Aarhus University , Langelandsgade 140 , DK-8000 Aarhus 
      C , Denmark.
FAU - Hoffmann, Thorsten
AU  - Hoffmann T
AD  - Institute of Inorganic and Analytical Chemistry , Johannes Gutenberg University 
      Mainz , Duesbergweg 10-14 , 55128 Mainz , Germany.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20190523
PL  - United States
TA  - Environ Sci Technol
JT  - Environmental science & technology
JID - 0213155
RN  - 0 (Aerosols)
RN  - 0 (Air Pollutants)
RN  - 0 (Sulfates)
SB  - IM
MH  - Aerosols
MH  - *Air Pollutants
MH  - Beijing
MH  - China
MH  - Environmental Monitoring
MH  - Germany
MH  - Mass Spectrometry
MH  - *Sulfates
EDAT- 2019/05/16 06:00
MHDA- 2019/09/19 06:00
CRDT- 2019/05/16 06:00
PHST- 2019/05/16 06:00 [pubmed]
PHST- 2019/09/19 06:00 [medline]
PHST- 2019/05/16 06:00 [entrez]
AID - 10.1021/acs.est.9b02628 [doi]
PST - ppublish
SO  - Environ Sci Technol. 2019 Jun 4;53(11):6192-6202. doi: 10.1021/acs.est.9b02628. 
      Epub 2019 May 23.