PMID- 31085495 OWN - NLM STAT- MEDLINE DCOM- 20190813 LR - 20190813 IS - 1879-1026 (Electronic) IS - 0048-9697 (Linking) VI - 678 DP - 2019 Aug 15 TI - Recently listed Stockholm convention POPs: Analytical methodology, occurrence in food and dietary exposure. PG - 793-800 LID - S0048-9697(19)31984-9 [pii] LID - 10.1016/j.scitotenv.2019.04.433 [doi] AB - In recent years, the Stockholm Convention has listed an additional set of persistent organic pollutants (POPs) for elimination or restricted use/release. Data on the occurrence of these contaminants in food is scarce. Validated analytical methodology was developed to investigate the occurrence of hexachlorobutadiene (HCBD), pentachlorobenzene (PCBz), hexachlorobenzene (HCB) pentachlorophenol (PCP) and polychlorinated naphthalenes (PCNs) in 120 retail foods and 19 total diet study samples. The foods covered the range of commonly consumed dietary items including dairy products, eggs (hen and other species), poultry, meat, fish, vegetables, etc. HCBD showed a low frequency of detection, whereas PCBz, HCB and PCNs occurred in most samples (ranges: <0.01 to 0.19 mug/kg; <0.01 to 3.16 mug/kg and 0.1 to 166 ng SigmaPCNs/kg respectively). PCP (<0.01 to 1.9 mug/kg) was detected more frequently in meat products, offal and eggs. Fish, shellfish, eggs from all species, animal fats, meat, offal and meat products showed higher contamination levels, which is normal when investigating lipophilic POPs. These levels of occurrence are similar to more recently reported literature levels but perhaps lower, relative to historic data. This is not unexpected, given the restrictions/limitations on these chemicals within the UK and Western Europe. The estimated human exposure to population groups through dietary intake is correspondingly low and based on current toxicological knowledge, the levels in the examined samples do not suggest a cause for health concern. The data also provide a current baseline for HCBD, PCBz and PCP, and update existing data for PCN and HCB occurrence in foods. CI - Crown Copyright (c) 2019. Published by Elsevier B.V. All rights reserved. FAU - Fernandes, A R AU - Fernandes AR AD - School of Environmental Sciences, University of East Anglia, Norwich NR4 7TJ, UK; Fera Science Ltd, Sand Hutton, York YO41 1LZ, UK. Electronic address: Alwyn.Fernandes@uea.ac.uk. FAU - Mortimer, D AU - Mortimer D AD - Food Standards Agency, Clive House, 70 Petty, London SW1H 9EX, France. FAU - Rose, M AU - Rose M AD - Fera Science Ltd, Sand Hutton, York YO41 1LZ, UK; Manchester Institute of Biotechnology, University of Manchester, Manchester M1 7DN, UK. FAU - Smith, F AU - Smith F AD - Fera Science Ltd, Sand Hutton, York YO41 1LZ, UK. FAU - Steel, Z AU - Steel Z AD - Fera Science Ltd, Sand Hutton, York YO41 1LZ, UK. FAU - Panton, S AU - Panton S AD - Fera Science Ltd, Sand Hutton, York YO41 1LZ, UK. LA - eng PT - Journal Article DEP - 20190503 PL - Netherlands TA - Sci Total Environ JT - The Science of the total environment JID - 0330500 RN - 0 (Environmental Pollutants) MH - Animals MH - Dietary Exposure/*analysis MH - Environmental Monitoring/*methods MH - Environmental Pollutants/*analysis MH - Food Contamination/*analysis MH - United Kingdom OTO - NOTNLM OT - Hexachlorobutadiene OT - Human exposure OT - Pentachlorobenzene OT - Pentachlorophenol OT - Polychlorinated naphthalenes OT - Risk assessment EDAT- 2019/05/16 06:00 MHDA- 2019/08/14 06:00 CRDT- 2019/05/16 06:00 PHST- 2019/03/12 00:00 [received] PHST- 2019/04/27 00:00 [revised] PHST- 2019/04/29 00:00 [accepted] PHST- 2019/05/16 06:00 [pubmed] PHST- 2019/08/14 06:00 [medline] PHST- 2019/05/16 06:00 [entrez] AID - S0048-9697(19)31984-9 [pii] AID - 10.1016/j.scitotenv.2019.04.433 [doi] PST - ppublish SO - Sci Total Environ. 2019 Aug 15;678:793-800. doi: 10.1016/j.scitotenv.2019.04.433. Epub 2019 May 3.