PMID- 31152899
OWN - NLM
STAT- MEDLINE
DCOM- 20190815
LR  - 20221207
IS  - 1879-1298 (Electronic)
IS  - 0045-6535 (Linking)
VI  - 232
DP  - 2019 Oct
TI  - In-situ sampling of chlorophenols in industrial wastewater using diffusive 
      gradients in thin films technique based on mesoporous carbon.
PG  - 18-25
LID - S0045-6535(19)31076-8 [pii]
LID - 10.1016/j.chemosphere.2019.05.163 [doi]
AB  - In-situ sampling of 2-chlorophenol (CP), 2,4-dichlorophenol (DCP), and 
      2,4,6-trichlorophenol (TCP) in industrial wastewater was carried out by the 
      diffusive gradients in thin films (DGT) device based on mesoporous carbon (MC). 
      The diffusion coefficients of CP ((1.33 +/- 0.05) x 10(-6) cm(2) s(-1)), 
      DCP((1.35 +/- 0.04) x 10(-6) cm(2) s(-1)) and 
      TCP((1.09 +/- 0.07) x 10(-6) cm(2) s(-1))) in nylon membrane at 25  degrees C were 
      independent of pH 3-9 and ionic strength as pNaCl from 0.155 to 3, and were less 
      than their values in water, demonstrating that the nylon membrane with good 
      tolerance and constant diffusion coefficients was suitable as the DGT diffusion 
      layer for controlling the diffusion of CPs. MC-DGT accurately measured the 
      concentrations of CP, DCP and TCP in synthetic solution 
      (C(DGT)/C(SOLN) = 0.956-1.04) over the deployment of 120 h. The experimental data 
      also agreed well with the theoretical data calculated on the DGT equation. The 
      performance of MC-DGT for sampling CPs was independent of pH (3-8) and ionic 
      strength as pNaCl (1.3-3) due to the change of the interaction between MC and CPs 
      under relatively high pH and ionic strength. Deployments in laboratory and field 
      trials demonstrated that the MC-DGT was a reliable simple, robust and accurate 
      tool for the in-situ sampling of CP, DCP and TCP in the industrial wastewater.
CI  - Copyright (c) 2019 Elsevier Ltd. All rights reserved.
FAU - Meng, Zhuo
AU  - Meng Z
AD  - College of Chemistry Chemical Engineering, and Environmental Engineering, 
      Liaoning Shihua University, China.
FAU - You, Nan
AU  - You N
AD  - College of Chemistry Chemical Engineering, and Environmental Engineering, 
      Liaoning Shihua University, China.
FAU - Fan, Hong-Tao
AU  - Fan HT
AD  - College of Chemistry Chemical Engineering, and Environmental Engineering, 
      Liaoning Shihua University, China. Electronic address: httyf_77@163.com.
LA  - eng
PT  - Journal Article
DEP - 20190522
PL  - England
TA  - Chemosphere
JT  - Chemosphere
JID - 0320657
RN  - 0 (Chlorophenols)
RN  - 0 (Nylons)
RN  - 0 (Waste Water)
RN  - 0 (Water Pollutants, Chemical)
RN  - 7440-44-0 (Carbon)
RN  - K9KAV4K6BN (2-chlorophenol)
MH  - Carbon/chemistry
MH  - Chlorophenols/*analysis
MH  - Diffusion
MH  - *Environmental Monitoring
MH  - Nylons
MH  - Osmolar Concentration
MH  - Waste Disposal, Fluid
MH  - Wastewater/analysis/chemistry
MH  - Water Pollutants, Chemical/*analysis
OTO - NOTNLM
OT  - Chlorophenols
OT  - Diffusive gradients in thin films
OT  - In-situ
OT  - Mesoporous carbon
OT  - Sampling
EDAT- 2019/06/04 06:00
MHDA- 2019/08/16 06:00
CRDT- 2019/06/02 06:00
PHST- 2019/03/24 00:00 [received]
PHST- 2019/05/12 00:00 [revised]
PHST- 2019/05/18 00:00 [accepted]
PHST- 2019/06/04 06:00 [pubmed]
PHST- 2019/08/16 06:00 [medline]
PHST- 2019/06/02 06:00 [entrez]
AID - S0045-6535(19)31076-8 [pii]
AID - 10.1016/j.chemosphere.2019.05.163 [doi]
PST - ppublish
SO  - Chemosphere. 2019 Oct;232:18-25. doi: 10.1016/j.chemosphere.2019.05.163. Epub 
      2019 May 22.