PMID- 31165936
OWN - NLM
STAT- MEDLINE
DCOM- 20190808
LR  - 20221207
IS  - 1573-2959 (Electronic)
IS  - 0167-6369 (Linking)
VI  - 191
IP  - 7
DP  - 2019 Jun 5
TI  - Optimization and validation of headspace solid-phase microextraction method 
      coupled with gas chromatography-triple quadrupole tandem mass spectrometry for 
      simultaneous determination of volatile and semi-volatile organic compounds in 
      coking wastewater treatment plant.
PG  - 411
LID - 10.1007/s10661-019-7554-5 [doi]
AB  - Industrial wastewater could be an important source for the emission of volatile 
      (VOCs) and semi-volatile organic compounds (SVOCs), but little is known about it. 
      In this study, a method for the identification and quantitation of 43 VOCs and 
      SVOCs in coking wastewater was developed using a solvent-free equilibrium 
      extraction method on the basis of headspace solid-phase microextraction 
      accompanied by gas chromatography-triple quadrupole tandem mass spectrometry 
      (HS-SPME-GC-MS/MS). To ensure good extraction efficiency, the parameters that 
      have an effect on the HS-SPME-GC-MS/MS process were carefully optimized, in terms 
      of fiber exposure time and temperature, pH, salt additives, sample volume, and 
      desorption time. The HS-SPME method showed good linearity range with coefficients 
      of determination (R(2)) >/= 0.991 and achieving a satisfactory recoveries value 
      (70-120%) with good relative standard deviations (RSDs) < 20% (precision). 
      Furthermore, the purposed approach proved to be sensitive with low detection 
      limits, where the values ranged from 0.03 to 3.01 mug/L. The real sample analysis 
      result showed that 43 of VOCs and SVOCs were detected in raw coking wastewater, 
      with 3-cresol as the dominant ones. Further, the method revealed that seven 
      phenols, 11 polycyclic aromatic hydrocarbons, and five BTEX were detected even in 
      the treated effluent. In conclusion, the HS-SPME method developed in this study 
      is simple in sample preparation, convenient, sensitive, and could satisfy the 
      requirement of the analysis of VOCs and SVOCs in coking wastewater.
FAU - Saber, Ayman N
AU  - Saber AN
AD  - State Key Laboratory of Environmental Aquatic Chemistry, Research Center for 
      Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing, 100085, China.
AD  - University of Chinese Academy of Sciences, Beijing, 100049, China.
AD  - Pesticide Residues and Environmental Pollution Department, Central Agricultural 
      Pesticide Laboratory, Agricultural Research Center, Dokki, Giza, 12618, Egypt.
FAU - Zhang, Haifeng
AU  - Zhang H
AD  - State Key Laboratory of Environmental Aquatic Chemistry, Research Center for 
      Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing, 100085, China.
AD  - University of Chinese Academy of Sciences, Beijing, 100049, China.
FAU - Yang, Min
AU  - Yang M
AD  - State Key Laboratory of Environmental Aquatic Chemistry, Research Center for 
      Eco-Environmental Sciences, Chinese Academy of Sciences, Beijing, 100085, China. 
      yangmin@rcees.ac.cn.
AD  - University of Chinese Academy of Sciences, Beijing, 100049, China. 
      yangmin@rcees.ac.cn.
LA  - eng
PT  - Journal Article
PT  - Validation Study
DEP - 20190605
PL  - Netherlands
TA  - Environ Monit Assess
JT  - Environmental monitoring and assessment
JID - 8508350
RN  - 0 (Coke)
RN  - 0 (Polycyclic Aromatic Hydrocarbons)
RN  - 0 (Solvents)
RN  - 0 (Volatile Organic Compounds)
RN  - 0 (Waste Water)
MH  - Coke
MH  - Environmental Monitoring/*methods
MH  - Gas Chromatography-Mass Spectrometry/*methods
MH  - Limit of Detection
MH  - Polycyclic Aromatic Hydrocarbons/*analysis
MH  - Solid Phase Microextraction/*methods
MH  - Solvents/analysis
MH  - Tandem Mass Spectrometry/*methods
MH  - Volatile Organic Compounds/*analysis
MH  - Wastewater/*chemistry
OTO - NOTNLM
OT  - Coking wastewater
OT  - GC-MS/MS
OT  - HP-SPME
OT  - Optimization
OT  - Validation
OT  - Volatile organic compounds
EDAT- 2019/06/06 06:00
MHDA- 2019/08/09 06:00
CRDT- 2019/06/06 06:00
PHST- 2019/02/01 00:00 [received]
PHST- 2019/05/21 00:00 [accepted]
PHST- 2019/06/06 06:00 [entrez]
PHST- 2019/06/06 06:00 [pubmed]
PHST- 2019/08/09 06:00 [medline]
AID - 10.1007/s10661-019-7554-5 [pii]
AID - 10.1007/s10661-019-7554-5 [doi]
PST - epublish
SO  - Environ Monit Assess. 2019 Jun 5;191(7):411. doi: 10.1007/s10661-019-7554-5.