PMID- 31178605
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20231011
IS  - 0026-9247 (Print)
IS  - 1434-4475 (Electronic)
IS  - 0026-9247 (Linking)
VI  - 150
IP  - 5
DP  - 2019
TI  - Synthesis, characterization, and POM-protein interactions of a Fe-substituted 
      Krebs-type Sandwich-tungstoantimonate.
PG  - 871-875
LID - 10.1007/s00706-019-2381-5 [doi]
AB  - ABSTRACT: The novel iron-substituted Krebs-type polyoxotungstate 
      (C(12)N(4)H(11))(4)Na(2)H(5)[(Fe(H(2)O)(3))(2)((FeO(2))(0.5)(WO(2))(0.5))(2)(beta-SbW(9)O(33))(2)] 
      (Fe-1) has been synthesized using ortho-phenylenediamine (opda) as a precursor 
      for the in situ formation of the counter cation 2,3-diaminophenazinium 
      (C(12)N(4)H(11))(+) (2,3-DAP). Fe-1 has been thoroughly characterized in the 
      solid state by single-crystal X-ray diffraction (SXRD), powder X-ray diffraction 
      (PXRD), IR spectroscopy, and elemental analysis as well as in solution by UV-Vis 
      spectroscopy. The crystal structure of Fe-1 reveals pi-pi-interactions between the 
      aromatic systems of the unconventional 2,3-DAP counter cation. POM-protein 
      interaction studies using SDS-PAGE revealed a non-proteolytic behavior of Fe-1 
      towards Human Serum Albumin (HSA) as a model protein.
FAU - Tanuhadi, Elias
AU  - Tanuhadi E
AUID- ORCID: 0000-0001-5474-6260
AD  - 1Universitat Wien, Fakultat fur Chemie, Institut fur Biophysikalische Chemie, 
      Althanstrasse 14, 1090 Wien, Austria. ISNI: 0000 0001 2286 1424. GRID: 
      grid.10420.37
FAU - Kampatsikas, Ioannis
AU  - Kampatsikas I
AUID- ORCID: 0000-0001-7660-3121
AD  - 1Universitat Wien, Fakultat fur Chemie, Institut fur Biophysikalische Chemie, 
      Althanstrasse 14, 1090 Wien, Austria. ISNI: 0000 0001 2286 1424. GRID: 
      grid.10420.37
FAU - Giester, Gerald
AU  - Giester G
AUID- ORCID: 0000-0002-3883-4188
AD  - 2Universitat Wien, Fakultat fur Geowissenschaften, Geographie und Astronomie, 
      Institut fur Mineralogie und Kristallographie, Althanstrasse 14, 1090 Wien, 
      Austria. ISNI: 0000 0001 2286 1424. GRID: grid.10420.37
FAU - Rompel, Annette
AU  - Rompel A
AUID- ORCID: 0000-0002-5919-0553
AD  - 1Universitat Wien, Fakultat fur Chemie, Institut fur Biophysikalische Chemie, 
      Althanstrasse 14, 1090 Wien, Austria. ISNI: 0000 0001 2286 1424. GRID: 
      grid.10420.37
LA  - eng
GR  - P 27534/FWF_/Austrian Science Fund FWF/Austria
PT  - Journal Article
DEP - 20190429
PL  - Austria
TA  - Monatsh Chem
JT  - Monatshefte fur chemie
JID - 0254164
PMC - PMC6533222
OTO - NOTNLM
OT  - Bioinorganic chemistry
OT  - Crystal structure
OT  - Proteins
OT  - Sandwich polyoxometalates
OT  - Tungstoantimonates
EDAT- 2019/06/11 06:00
MHDA- 2019/06/11 06:01
PMCR- 2019/04/29
CRDT- 2019/06/11 06:00
PHST- 2018/12/23 00:00 [received]
PHST- 2019/01/25 00:00 [accepted]
PHST- 2019/06/11 06:00 [entrez]
PHST- 2019/06/11 06:00 [pubmed]
PHST- 2019/06/11 06:01 [medline]
PHST- 2019/04/29 00:00 [pmc-release]
AID - 2381 [pii]
AID - 10.1007/s00706-019-2381-5 [doi]
PST - ppublish
SO  - Monatsh Chem. 2019;150(5):871-875. doi: 10.1007/s00706-019-2381-5. Epub 2019 Apr 
      29.