PMID- 31179621 OWN - NLM STAT- PubMed-not-MEDLINE DCOM- 20191016 LR - 20200108 IS - 1861-471X (Electronic) IS - 1861-471X (Linking) VI - 14 IP - 20 DP - 2019 Oct 15 TI - A Bifunctional Luminescent Metal-Organic Framework for the Sensing of Paraquat and Fe(3+) Ions in Water. PG - 3611-3619 LID - 10.1002/asia.201900682 [doi] AB - The hydrothermal reaction of Zn(2+) ions with a mixture of two ligands, Hcptpy and H(3) btc (Hcptpy=4-(4-carboxyphenyl)-2,2':4',4''-terpyridine; H(3) btc=1,3,5-benzenetricarboxylic acid), led to the formation of a 3D metal-organic framework (MOF) with 1D channels, [Zn(2) (cptpy)(btc)(H(2) O)](n) (1), which was structurally characterized by using single-crystal X-ray diffraction (SXRD). In MOF 1, two independent Zn(2+) ions were interconnected by btc(3-) ligands to form a 1D chain, whilst adjacent Zn(2+) ions were alternately bridged by cptpy(-) ligands to generate a 2D sheet, which was further linked by 1D chains to form a 3D framework with a new (3,3,4,4)-connected topology. Furthermore, compound 1 also exhibited excellent stability towards air and water and, more importantly, luminescence experiments indicated that it could serve as a probe for the sensitive detection of paraquat (PAQ) and Fe(3+) ions in aqueous solution. CI - (c) 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. FAU - Chen, Hongjuan AU - Chen H AD - Key Laboratory of Theoretical Organic Chemistry and Functional Molecules (Ministry of Education), Hunan Provincial Key Laboratory for the Controllable Preparation and Functional Application of Fine Polymers, Hunan Provincial Key Laboratory of Advanced Materials for New Energy Storage and Conversion, School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, 411201, P. R. China. FAU - Fan, Peng AU - Fan P AD - Key Laboratory of Theoretical Organic Chemistry and Functional Molecules (Ministry of Education), Hunan Provincial Key Laboratory for the Controllable Preparation and Functional Application of Fine Polymers, Hunan Provincial Key Laboratory of Advanced Materials for New Energy Storage and Conversion, School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, 411201, P. R. China. FAU - Tu, Xingxin AU - Tu X AD - Key Laboratory of Theoretical Organic Chemistry and Functional Molecules (Ministry of Education), Hunan Provincial Key Laboratory for the Controllable Preparation and Functional Application of Fine Polymers, Hunan Provincial Key Laboratory of Advanced Materials for New Energy Storage and Conversion, School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, 411201, P. R. China. FAU - Min, Hui AU - Min H AD - College of Chemistry, Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin, 300071, P. R. China. FAU - Yu, Xianyong AU - Yu X AD - Key Laboratory of Theoretical Organic Chemistry and Functional Molecules (Ministry of Education), Hunan Provincial Key Laboratory for the Controllable Preparation and Functional Application of Fine Polymers, Hunan Provincial Key Laboratory of Advanced Materials for New Energy Storage and Conversion, School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, 411201, P. R. China. FAU - Li, Xiaofang AU - Li X AD - Key Laboratory of Theoretical Organic Chemistry and Functional Molecules (Ministry of Education), Hunan Provincial Key Laboratory for the Controllable Preparation and Functional Application of Fine Polymers, Hunan Provincial Key Laboratory of Advanced Materials for New Energy Storage and Conversion, School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, 411201, P. R. China. FAU - Zeng, Ju-Lan AU - Zeng JL AD - School of Chemistry and Food Engineering, Changsha University of Science and Technology, Changsha 410114, P. R. China. FAU - Zhang, Shaowei AU - Zhang S AD - Key Laboratory of Theoretical Organic Chemistry and Functional Molecules (Ministry of Education), Hunan Provincial Key Laboratory for the Controllable Preparation and Functional Application of Fine Polymers, Hunan Provincial Key Laboratory of Advanced Materials for New Energy Storage and Conversion, School of Chemistry and Chemical Engineering, Hunan University of Science and Technology, Xiangtan, 411201, P. R. China. AD - College of Chemistry, Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin, 300071, P. R. China. FAU - Cheng, Peng AU - Cheng P AUID- ORCID: 0000-0003-0396-1846 AD - College of Chemistry, Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Education), Nankai University, Tianjin, 300071, P. R. China. LA - eng GR - 21601058/National Natural Science Foundation of China/ GR - 21771112/National Natural Science Foundation of China/ GR - B12015/111 Project/ GR - 2018JJ3146/Natural Science Foundation of Hunan Province/ GR - 2017JJ1026/Natural Science Foundation of Hunan Province/ GR - 18A192/Scientific Research Fund of Hunan Provincial Education Department/ GR - CX2018B672/Hunan Provincial Innovation Foundation for Postgraduate/ GR - E51677/Hunan University of Science and Technology/ GR - STZ2018007/Hunan University of Science and Technology/ GR - 201810534039/Hunan University of Science and Technology/ PT - Journal Article DEP - 20190703 PL - Germany TA - Chem Asian J JT - Chemistry, an Asian journal JID - 101294643 SB - IM OTO - NOTNLM OT - X-ray diffraction OT - luminescence OT - metal-organic frameworks OT - sensors OT - structure elucidation EDAT- 2019/06/11 06:00 MHDA- 2019/06/11 06:01 CRDT- 2019/06/11 06:00 PHST- 2019/05/22 00:00 [received] PHST- 2019/06/06 00:00 [revised] PHST- 2019/06/11 06:00 [pubmed] PHST- 2019/06/11 06:01 [medline] PHST- 2019/06/11 06:00 [entrez] AID - 10.1002/asia.201900682 [doi] PST - ppublish SO - Chem Asian J. 2019 Oct 15;14(20):3611-3619. doi: 10.1002/asia.201900682. Epub 2019 Jul 3.