PMID- 31190425
OWN - NLM
STAT- MEDLINE
DCOM- 20200217
LR  - 20200217
IS  - 1522-7243 (Electronic)
IS  - 1522-7235 (Linking)
VI  - 34
IP  - 7
DP  - 2019 Nov
TI  - Novel fluorescent sensor using molecularly imprinted silica microsphere-coated 
      CdSe@CdS quantum dots and its application in the detection of 
      2,4,6-trichlorophenol from environmental water samples.
PG  - 680-688
LID - 10.1002/bio.3653 [doi]
AB  - In this study, a high fluorescence sensitivity and selectivity, molecularly 
      imprinted nanofluorescent polymer sensor (MIP@SiO(2) @QDs) was prepared using a 
      reverse microemulsion method. 2,4,6-Trichlorophenol (2,4,6-TCP) was detected 
      using fluorescence quenching. Tetraethyl orthosilicate (TEOS), quantum dots (QDs) 
      and 3-aminopropyltriethoxysilane (APTS) were used as cross-linker, signal sources 
      and functional monomer respectively. The sensor (MIP@SiO(2) @QDs) and the 
      non-imprinted polymer sensor (NIP@SiO(2) @QDs) were characterized using infra-red 
      (IR) analysis, X-ray diffraction (XRD), transmission electron microscopy (TEM) 
      and scanning electron microscopy (SEM). The selectivity of MIP@SiO(2) @QDs was 
      examined by comparing 2,4,6-TCP with other similar functional substances 
      including 2,4-dichlorophenol (2,4-DCP), 2,6-dichlorophenol (2,6-DCP) and 
      4-chlorophenol (4-CP). Results showed that MIP@SiO(2) @QDs had better selectivity 
      for 2,4,6-TCP than the other compounds. Fluorescence quenching efficiency 
      displayed a good linear response at the 2,4,6-TCP concentration range 
      5-1000 mumol/L. The limit of detection (LOD) was 0.9 mumol/L (3sigma, n = 9). This 
      method was equally applicable for testing actual samples with a recovery rate of 
      98.0-105.8%. The sensor had advantages of simple pretreatment, good sensitivity 
      and selectivity, and wide linear range and could be applied for the rapid 
      detection of 2,4,6-TCP in actual samples.
CI  - (c) 2019 John Wiley & Sons, Ltd.
FAU - Liu, Yang
AU  - Liu Y
AD  - College of Chemistry and Life Science, Zhejiang Normal University, Jinhua, China.
FAU - Chen, Piaopiao
AU  - Chen P
AD  - College of Chemistry and Life Science, Zhejiang Normal University, Jinhua, China.
FAU - Zheng, Shan
AU  - Zheng S
AD  - College of Chemistry and Life Science, Zhejiang Normal University, Jinhua, China.
FAU - Xing, Yichen
AU  - Xing Y
AD  - College of Chemistry and Life Science, Zhejiang Normal University, Jinhua, China.
FAU - Huang, Chaobiao
AU  - Huang C
AD  - College of Chemistry and Life Science, Zhejiang Normal University, Jinhua, China.
AD  - Zhejiang Normal University Xingzhi College, Jinhua, China.
LA  - eng
GR  - 21575129/National Natural Science Foundation of China/
PT  - Journal Article
DEP - 20190612
PL  - England
TA  - Luminescence
JT  - Luminescence : the journal of biological and chemical luminescence
JID - 100889025
RN  - 0 (Cadmium Compounds)
RN  - 0 (Chlorophenols)
RN  - 0 (Fluorescent Dyes)
RN  - 0 (Selenium Compounds)
RN  - 0 (Sulfides)
RN  - 0 (Water Pollutants, Chemical)
RN  - 057EZR4Z7Q (cadmium sulfide)
RN  - 7631-86-9 (Silicon Dioxide)
RN  - A7F646JC5C (cadmium selenide)
RN  - MHS8C5BAUZ (2,4,6-trichlorophenol)
SB  - IM
MH  - Cadmium Compounds/chemistry
MH  - Chlorophenols/*analysis
MH  - Fluorescent Dyes/*chemistry
MH  - Microspheres
MH  - *Molecular Imprinting
MH  - Particle Size
MH  - Quantum Dots/*chemistry
MH  - Selenium Compounds/chemistry
MH  - Silicon Dioxide/*chemistry
MH  - Sulfides/chemistry
MH  - Surface Properties
MH  - Water Pollutants, Chemical/*chemistry
OTO - NOTNLM
OT  - 2,4,6-trichlorophenol
OT  - fluorescence
OT  - molecularly imprinted polymers
OT  - quantum dots
EDAT- 2019/06/14 06:00
MHDA- 2020/02/18 06:00
CRDT- 2019/06/14 06:00
PHST- 2019/02/12 00:00 [received]
PHST- 2019/04/19 00:00 [revised]
PHST- 2019/05/05 00:00 [accepted]
PHST- 2019/06/14 06:00 [pubmed]
PHST- 2020/02/18 06:00 [medline]
PHST- 2019/06/14 06:00 [entrez]
AID - 10.1002/bio.3653 [doi]
PST - ppublish
SO  - Luminescence. 2019 Nov;34(7):680-688. doi: 10.1002/bio.3653. Epub 2019 Jun 12.