PMID- 31194510
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20200409
LR  - 20200409
IS  - 1520-6882 (Electronic)
IS  - 0003-2700 (Linking)
VI  - 91
IP  - 13
DP  - 2019 Jul 2
TI  - Substituent-Induced Aggregated State Electrochemiluminescence of 
      Tetraphenylethene Derivatives.
PG  - 8676-8682
LID - 10.1021/acs.analchem.9b02357 [doi]
AB  - The development of highly active, eco-friendly, and structurely fine-tunable 
      organic luminophores is currently desirable for electrochemiluminescence (ECL). 
      Tetraphenylethene (TPE) derivatives are the most representative 
      aggregation-induced emission characteristic (AIEgens). In contrast, their 
      aggregation-induced ECLs have not been detail studied. Herein, we report the 
      bright cathodic aggregated state ECL of TPE derivatives by a coreactant approach. 
      In this system, the substituents profoundly affect ECL emissions by changing the 
      relative intensities of R and B band intensity ratios in their UV-vis spectra as 
      well as the HOMO and LUMO energies. It was discovered that electron-withdrawing 
      nitro-substituted TPE-(NO(2))(4) with a smaller LUMO/HOMO band gap and stronger R 
      band featured the strongest ECL emissions and became the best luminophore for the 
      highly efficient detection of iodide (I(-)) in the aqueous phase. This work not 
      only reveals the influence of R and B bands in TPE derivative UV-vis spectra on 
      their optical properties but also constructs a novel aggregation-induced ECL 
      sensing.
FAU - Han, Zhengang
AU  - Han Z
AD  - Key Laboratory of Bioelectrochemistry and Environmental Analysis of Gansu 
      Province, College of Chemistry and Chemical Engineering , Northwest Normal 
      University , Lanzhou 730070 , People's Republic of China.
FAU - Zhang, Yinpan
AU  - Zhang Y
AD  - Key Laboratory of Bioelectrochemistry and Environmental Analysis of Gansu 
      Province, College of Chemistry and Chemical Engineering , Northwest Normal 
      University , Lanzhou 730070 , People's Republic of China.
FAU - Wu, Yanxia
AU  - Wu Y
AD  - Key Laboratory of Bioelectrochemistry and Environmental Analysis of Gansu 
      Province, College of Chemistry and Chemical Engineering , Northwest Normal 
      University , Lanzhou 730070 , People's Republic of China.
FAU - Li, Zhimin
AU  - Li Z
AD  - Key Laboratory of Bioelectrochemistry and Environmental Analysis of Gansu 
      Province, College of Chemistry and Chemical Engineering , Northwest Normal 
      University , Lanzhou 730070 , People's Republic of China.
FAU - Bai, Lei
AU  - Bai L
AD  - Key Laboratory of Bioelectrochemistry and Environmental Analysis of Gansu 
      Province, College of Chemistry and Chemical Engineering , Northwest Normal 
      University , Lanzhou 730070 , People's Republic of China.
FAU - Huo, Shuhui
AU  - Huo S
AD  - Key Laboratory of Bioelectrochemistry and Environmental Analysis of Gansu 
      Province, College of Chemistry and Chemical Engineering , Northwest Normal 
      University , Lanzhou 730070 , People's Republic of China.
FAU - Lu, Xiaoquan
AU  - Lu X
AUID- ORCID: 0000-0003-2375-668X
AD  - Key Laboratory of Bioelectrochemistry and Environmental Analysis of Gansu 
      Province, College of Chemistry and Chemical Engineering , Northwest Normal 
      University , Lanzhou 730070 , People's Republic of China.
AD  - Tianjin Key Laboratory of Molecular Optoelectronic, Department of Chemistry , 
      Tianjin University , Tianjin 300072 , People's Republic of China.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20190613
PL  - United States
TA  - Anal Chem
JT  - Analytical chemistry
JID - 0370536
SB  - IM
EDAT- 2019/06/14 06:00
MHDA- 2019/06/14 06:01
CRDT- 2019/06/14 06:00
PHST- 2019/06/14 06:00 [pubmed]
PHST- 2019/06/14 06:01 [medline]
PHST- 2019/06/14 06:00 [entrez]
AID - 10.1021/acs.analchem.9b02357 [doi]
PST - ppublish
SO  - Anal Chem. 2019 Jul 2;91(13):8676-8682. doi: 10.1021/acs.analchem.9b02357. Epub 
      2019 Jun 13.