PMID- 31201908
OWN - NLM
STAT- MEDLINE
DCOM- 20200108
LR  - 20200108
IS  - 1879-0003 (Electronic)
IS  - 0141-8130 (Linking)
VI  - 136
DP  - 2019 Sep 1
TI  - Gamma radiation induced preparation of polyampholyte nanocomposite polymers for 
      removal of Co(II).
PG  - 1273-1281
LID - S0141-8130(19)31114-6 [pii]
LID - 10.1016/j.ijbiomac.2019.06.081 [doi]
AB  - A series of polyampholyte nanocomposite biopolymers, 
      poly(N,N-diallyldimethylammonium chloride-co-acrylamide) grafted on 
      carboxymethylcellulose/iron(III) oxide [P(DADMAC-AAm)CMC/Fe(2)O(3)] and 
      poly(N,N-diallyldimethylammonium chloride-co-sodium acrylate) grafted on 
      carboxymethylcellulose/iron(III) oxide [P(DADMAC-SA)CMC/Fe(2)O(3)], was prepared 
      with different molar ratios of anionic groups to cationic groups using gamma 
      irradiation. The grafting properties and swelling behavior were investigated as a 
      function of grafting conditions such as DADMAC, AAm, SA, and CMC concentrations 
      and absorbed dose. Fourier transform infrared spectroscopic analysis (FTIR) 
      confirmed the graft copolymerization. Scanning electron microscope (SEM) was 
      employed to check the morphological structure of CMC, P(DADMAC-AAm)CMC/Fe(2)O(3), 
      and P(DADMAC-SA)CMC/Fe(2)O(3). Thermogravimetric analysis (TGA) and differential 
      thermal analysis (DTA) further characterized the grafted copolymers and showed 
      their high thermal stability. Using batch sorption experiments and (60)Co as a 
      radiotracer, P(DADMAC-AAm)CMC/Fe(2)O(3) and P(DADMAC-SA)CMC/Fe(2)O(3) were 
      evaluated for Co(II) removal from aqueous solutions. Experimentally, 
      P(DADMAC-AAm)CMC/Fe(2)O(3) and P(DADMAC-SA)CMC/Fe(2)O(3) show high sorption 
      capacity of Co(II), i.e. 69.67 mg g(-1) and 75.17 mg g(-1), respectively, which 
      makes them potential sorbents for Co(II) removal from water/wastewater. Finally, 
      the Co(II) sorption was examined using sorption isotherm and kinetic models. 
      Cobalt sorption was best fitted to Langmuir model which suggests the sorption is 
      of chemisorption type. On the other hand, the sorption kinetics was best 
      represented by the pseudo-first-order kinetic model.
CI  - Copyright (c) 2019 Elsevier B.V. All rights reserved.
FAU - Elsharma, Emad M
AU  - Elsharma EM
AD  - Nuclear Chemistry Department, Hot Laboratories Center, Egyptian Atomic Energy 
      Authority, Inshas, Cairo 13759, Egypt.
FAU - Saleh, Alaaeldine Sh
AU  - Saleh AS
AD  - Nuclear Chemistry Department, Hot Laboratories Center, Egyptian Atomic Energy 
      Authority, Inshas, Cairo 13759, Egypt. Electronic address: 
      alaaeldinesaleh@gmail.com.
FAU - Abou-Elmagd, Wael S I
AU  - Abou-Elmagd WSI
AD  - Department of Chemistry, Faculty of Science, Ain Shams University, Abassia, Cairo 
      11566, Egypt.
FAU - Metwally, Essam
AU  - Metwally E
AD  - Nuclear Chemistry Department, Hot Laboratories Center, Egyptian Atomic Energy 
      Authority, Inshas, Cairo 13759, Egypt.
FAU - Siyam, Tharwat
AU  - Siyam T
AD  - Nuclear Chemistry Department, Hot Laboratories Center, Egyptian Atomic Energy 
      Authority, Inshas, Cairo 13759, Egypt.
LA  - eng
PT  - Journal Article
DEP - 20190612
PL  - Netherlands
TA  - Int J Biol Macromol
JT  - International journal of biological macromolecules
JID - 7909578
RN  - 0 (Ferric Compounds)
RN  - 0 (Polymers)
RN  - 0 (Water Pollutants, Chemical)
RN  - 059QF0KO0R (Water)
RN  - 1K09F3G675 (ferric oxide)
RN  - 789U1901C5 (Copper)
RN  - K679OBS311 (Carboxymethylcellulose Sodium)
SB  - IM
MH  - Carboxymethylcellulose Sodium/chemistry
MH  - Copper/*chemistry/*isolation & purification
MH  - Ferric Compounds/chemistry
MH  - *Gamma Rays
MH  - Hydrogen-Ion Concentration
MH  - Kinetics
MH  - Nanocomposites/*chemistry
MH  - Particle Size
MH  - Polymers/*chemistry
MH  - Temperature
MH  - Water/chemistry
MH  - Water Pollutants, Chemical/chemistry/isolation & purification
MH  - Water Purification/*methods
EDAT- 2019/06/16 06:00
MHDA- 2020/01/09 06:00
CRDT- 2019/06/16 06:00
PHST- 2019/02/13 00:00 [received]
PHST- 2019/06/08 00:00 [revised]
PHST- 2019/06/11 00:00 [accepted]
PHST- 2019/06/16 06:00 [pubmed]
PHST- 2020/01/09 06:00 [medline]
PHST- 2019/06/16 06:00 [entrez]
AID - S0141-8130(19)31114-6 [pii]
AID - 10.1016/j.ijbiomac.2019.06.081 [doi]
PST - ppublish
SO  - Int J Biol Macromol. 2019 Sep 1;136:1273-1281. doi: 
      10.1016/j.ijbiomac.2019.06.081. Epub 2019 Jun 12.