PMID- 31268216
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20200108
IS  - 1521-3773 (Electronic)
IS  - 1433-7851 (Linking)
VI  - 58
IP  - 35
DP  - 2019 Aug 26
TI  - Integrating Hydrogen Production with Aqueous Selective Semi-Dehydrogenation of 
      Tetrahydroisoquinolines over a Ni(2) P Bifunctional Electrode.
PG  - 12014-12017
LID - 10.1002/anie.201903327 [doi]
AB  - Exploring an alternative anodic reaction to produce value-added chemicals with 
      high selectivity, especially integrated with promoted hydrogen generation, is 
      desirable. Herein, a selective semi-dehydrogenation of tetrahydroisoquinolines 
      (THIQs) is demonstrated to replace the oxygen evolution reaction (OER) for 
      boosting H(2) evolution reaction (HER) in water over a Ni(2) P nanosheet 
      electrode. The value-added semi-dehydrogenation products, dihydroisoquinolines 
      (DHIQs), can be selectively obtained with high yields at the anode. The 
      controllable semi-dehydrogenation is attributed to the in situ formed Ni(II) 
      /Ni(III) redox active species. Such a strategy can deliver a variety of DHIQs 
      bearing electron-withdrawing/donating groups in good yields and excellent 
      selectivities, and can be applied to gram-scale synthesis. A two-electrode Ni(2) 
      P bifunctional electrolyzer can produce both H(2) and DHIQs with robust stability 
      and high Faradaic efficiencies at a much lower cell voltage than that of overall 
      water splitting.
CI  - (c) 2019 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.
FAU - Huang, Chenqi
AU  - Huang C
AD  - Department of Chemistry, Institute of Molecular Plus, School of Science, Tianjin 
      University, Tianjin, 300072, China.
FAU - Huang, Yi
AU  - Huang Y
AD  - Department of Chemistry, Institute of Molecular Plus, School of Science, Tianjin 
      University, Tianjin, 300072, China.
FAU - Liu, Cuibo
AU  - Liu C
AD  - Department of Chemistry, Institute of Molecular Plus, School of Science, Tianjin 
      University, Tianjin, 300072, China.
FAU - Yu, Yifu
AU  - Yu Y
AD  - Department of Chemistry, Institute of Molecular Plus, School of Science, Tianjin 
      University, Tianjin, 300072, China.
FAU - Zhang, Bin
AU  - Zhang B
AUID- ORCID: 0000-0003-0542-1819
AD  - Department of Chemistry, Institute of Molecular Plus, School of Science, Tianjin 
      University, Tianjin, 300072, China.
AD  - Tianjin Key Laboratory of Molecular Optoelectronic Sciences, Collaborative 
      Innovation Center of Chemical Science and Engineering, Tianjin, 300072, China.
LA  - eng
GR  - 21871206/National Natural Science Foundation of China/
GR  - 21422104/National Natural Science Foundation of China/
PT  - Journal Article
DEP - 20190801
PL  - Germany
TA  - Angew Chem Int Ed Engl
JT  - Angewandte Chemie (International ed. in English)
JID - 0370543
SB  - IM
OTO - NOTNLM
OT  - Raman spectroscopy
OT  - electrocatalysis
OT  - hydrogen evolution reaction (HER)
OT  - nickel
OT  - semi-dehydrogenation
EDAT- 2019/07/04 06:00
MHDA- 2019/07/04 06:01
CRDT- 2019/07/04 06:00
PHST- 2019/03/18 00:00 [received]
PHST- 2019/07/04 06:00 [pubmed]
PHST- 2019/07/04 06:01 [medline]
PHST- 2019/07/04 06:00 [entrez]
AID - 10.1002/anie.201903327 [doi]
PST - ppublish
SO  - Angew Chem Int Ed Engl. 2019 Aug 26;58(35):12014-12017. doi: 
      10.1002/anie.201903327. Epub 2019 Aug 1.