PMID- 31312945
OWN - NLM
STAT- MEDLINE
DCOM- 20200325
LR  - 20210211
IS  - 1436-5073 (Electronic)
IS  - 0026-3672 (Linking)
VI  - 186
IP  - 8
DP  - 2019 Jul 16
TI  - A nanohybrid composed of polyoxotungstate and graphene oxide for dispersive micro 
      solid-phase extraction of non-steroidal anti-inflammatory drugs prior to their 
      quantitation by HPLC.
PG  - 534
LID - 10.1007/s00604-019-3694-0 [doi]
AB  - A nanohybrid was prepared from polyoxotungstate anion and graphene oxide (POT/GO) 
      and characterized in terms of porosity by applying Fourier transform infrared and 
      transmission electron microscopy. The nanohybrid was applied as a sorbent for the 
      dispersive micro solid-phase extraction of the non-steroidal anti-inflammatory 
      drugs (NSAIDs) ibuprofen, diclofenac, and naproxen. Different types of sorbents 
      were compared, and the POT/GO nanohybrid was found to have the best adsorption 
      affinity. The NSAIDs were quantified via HPLC with UV detection. Under the 
      optimum conditions, the limits of detection (at an S/N ratio of 3) range between 
      0.02-0.03 ng.mL(-1), and the linear response ranges extend from 
      0.08-200 ng.mL(-1), respectively. The relative standard deviations (RSDs) for 
      five replicates at three concentration levels (0.1, 5 and 100 ng.mL(-1)) of 
      NSAIDs ranged from 4.1 to 6.1%. The applicability of the method was confirmed by 
      analyzing spiked real water samples, and satisfactory results were obtained, with 
      recoveries between 95.6 and 99.6%. Graphical abstract Schematic representation of 
      the polyoxotungstate/graphene oxide nanohybrid preparation.
FAU - Amiri, Amirhassan
AU  - Amiri A
AUID- ORCID: 0000-0002-5149-9038
AD  - Department of Chemistry, Faculty of Sciences, Hakim Sabzevari University, 
      Sabzevar, 96179-76487, Iran. Amiri_amirhassan@yahoo.com.
FAU - Mirzaei, Masoud
AU  - Mirzaei M
AD  - Department of Chemistry, Faculty of Science, Ferdowsi University of Mashhad, 
      Mashhad, 91775-1436, Iran. mirzaeesh@um.ac.ir.
FAU - Derakhshanrad, Shadi
AU  - Derakhshanrad S
AD  - Department of Chemistry, Faculty of Science, Ferdowsi University of Mashhad, 
      Mashhad, 91775-1436, Iran.
LA  - eng
PT  - Journal Article
DEP - 20190716
PL  - Austria
TA  - Mikrochim Acta
JT  - Mikrochimica acta
JID - 7808782
RN  - 0 (Anti-Inflammatory Agents, Non-Steroidal)
RN  - 0 (Polymers)
RN  - 0 (Tungsten Compounds)
RN  - 0 (Water Pollutants, Chemical)
RN  - 0 (graphene oxide)
RN  - 144O8QL0L1 (Diclofenac)
RN  - 57Y76R9ATQ (Naproxen)
RN  - 7782-42-5 (Graphite)
RN  - 84303-06-0 (polyoxotungstate PM 19)
RN  - WK2XYI10QM (Ibuprofen)
SB  - IM
MH  - Adsorption
MH  - Anti-Inflammatory Agents, Non-Steroidal/*analysis/isolation & purification
MH  - Chromatography, High Pressure Liquid/*methods
MH  - Diclofenac/analysis/isolation & purification
MH  - Graphite/*chemistry
MH  - Ibuprofen/analysis/isolation & purification
MH  - Limit of Detection
MH  - Nanostructures/*chemistry
MH  - Naproxen/analysis/isolation & purification
MH  - Polymers/chemistry
MH  - Porosity
MH  - Solid Phase Extraction
MH  - Spectrophotometry, Ultraviolet
MH  - Tungsten Compounds/chemistry
MH  - Water Pollutants, Chemical/analysis
OTO - NOTNLM
OT  - Anion exchange polymer
OT  - Carbon-based nanomaterial
OT  - Poly(diallyldimethylammonium chloride)
OT  - Polyoxometalate
OT  - River water analysis
OT  - Sample preparation
OT  - Tap water analysis
OT  - Wastewater analysis
EDAT- 2019/07/18 06:00
MHDA- 2020/03/26 06:00
CRDT- 2019/07/18 06:00
PHST- 2019/06/13 00:00 [received]
PHST- 2019/07/08 00:00 [accepted]
PHST- 2019/07/18 06:00 [entrez]
PHST- 2019/07/18 06:00 [pubmed]
PHST- 2020/03/26 06:00 [medline]
AID - 10.1007/s00604-019-3694-0 [pii]
AID - 10.1007/s00604-019-3694-0 [doi]
PST - epublish
SO  - Mikrochim Acta. 2019 Jul 16;186(8):534. doi: 10.1007/s00604-019-3694-0.