PMID- 31340424 OWN - NLM STAT- MEDLINE DCOM- 20191007 LR - 20191007 IS - 1879-1298 (Electronic) IS - 0045-6535 (Linking) VI - 233 DP - 2019 Oct TI - Air-water exchange of pesticidal persistent organic pollutants in the lower stretch of the transboundary river Ganga, India. PG - 966-974 LID - S0045-6535(19)31144-0 [pii] LID - 10.1016/j.chemosphere.2019.05.223 [doi] AB - The lower stretch of the perennial transboundary river Ganga is known as the Hooghly River (HR) in India. Despite the strict ban, HR has been evidenced with residues of pesticidal persistent organic pollutants (POPs) from primary and secondary sources. Hence surface water sampling and passive air sampling (PAS) were conducted along the urban and suburban transects and discharge points to study the fate of pesticidal (POPs along the HR. Excluding the discharge points, the mean concentration of hexachlorocyclohexane (HCH), dichlorodiphenyltrichloroethane (DDT) and endosulfan (ENDO) were 6 ng/L, 4 ng/L and 36 ng/L in surface water and 888 pg/m(3), 1689 pg/m(3) and 429 pg/m(3) in atmosphere respectively. Percentage composition and diagnostic ratios strongly suggest ongoing use of technical HCH, DDT and endosulfan. Elevated endosulfan in surface water has been related to its usage during fishing. Except for p,p'-DDE, alpha-Endo and beta-Endo, fluxes at the air-water interface showed net deposition from air to water for all the OCPs in urban and suburban transects. The estimated eco-toxicological risk assessment showed risk on lower trophic organisms due to DDT and lindane mostly at the discharge points. Endosulfan can pose potential risk to the edible fishe species in the HR. CI - Copyright (c) 2019 Elsevier Ltd. All rights reserved. FAU - Khuman, Sanjenbam Nirmala AU - Khuman SN AD - Department of Civil Engineering, SRM Research Institute, SRM Institute of Science of Technology, Kattankulathur, Tamil Nadu, India. FAU - Chakraborty, Paromita AU - Chakraborty P AD - Department of Civil Engineering, SRM Research Institute, SRM Institute of Science of Technology, Kattankulathur, Tamil Nadu, India. Electronic address: paromita.c@res.srmuniv.ac.in. LA - eng PT - Journal Article DEP - 20190527 PL - England TA - Chemosphere JT - Chemosphere JID - 0320657 RN - 0 (Air Pollutants) RN - 0 (Pesticides) RN - 0 (Water Pollutants, Chemical) RN - 059QF0KO0R (Water) RN - 4M7FS82U08 (Dichlorodiphenyl Dichloroethylene) RN - 59NEE7PCAB (Hexachlorocyclohexane) RN - CIW5S16655 (DDT) RN - OKA6A6ZD4K (Endosulfan) SB - IM MH - Air Pollutants/*analysis MH - Atmosphere/chemistry MH - DDT/analysis MH - Dichlorodiphenyl Dichloroethylene/analysis MH - Endosulfan/analysis MH - *Environmental Monitoring MH - Hexachlorocyclohexane/analysis MH - India MH - Pesticides/*analysis MH - Rivers/*chemistry MH - Water/chemistry MH - Water Pollutants, Chemical/*analysis OTO - NOTNLM OT - Air OT - Fluxes OT - Ganga OT - Organochlorine pesticides OT - Water EDAT- 2019/07/26 06:00 MHDA- 2019/10/08 06:00 CRDT- 2019/07/26 06:00 PHST- 2019/03/28 00:00 [received] PHST- 2019/05/11 00:00 [revised] PHST- 2019/05/25 00:00 [accepted] PHST- 2019/07/26 06:00 [entrez] PHST- 2019/07/26 06:00 [pubmed] PHST- 2019/10/08 06:00 [medline] AID - S0045-6535(19)31144-0 [pii] AID - 10.1016/j.chemosphere.2019.05.223 [doi] PST - ppublish SO - Chemosphere. 2019 Oct;233:966-974. doi: 10.1016/j.chemosphere.2019.05.223. Epub 2019 May 27.