PMID- 31404739 OWN - NLM STAT- MEDLINE DCOM- 20191211 LR - 20221207 IS - 1879-1298 (Electronic) IS - 0045-6535 (Linking) VI - 237 DP - 2019 Dec TI - Enhanced removal of nitrate and refractory organic pollutants from bio-treated coking wastewater using corncobs as carbon sources and biofilm carriers. PG - 124520 LID - S0045-6535(19)31744-8 [pii] LID - 10.1016/j.chemosphere.2019.124520 [doi] AB - The quality of the bio-treated coking wastewater (BTCW) is difficult to meet increasingly stringent coking wastewater discharge standards and future wastewater recycling needs. In this study, the pre-treatment process of BTCW was installed including the two up-flow fixed-bed bioreactors (UFBRs) which were separately filled with alkali-pretreated or no alkali-pretreated corncobs used as solid carbon sources as well as biofilm carriers. Results showed that this pre-treatment process could significantly improve the biodegradability of BTCW and increase the C/N ratio. Thus, over 90% of residual nitrate in BTCW were removed stably. Furthermore, GC-MS analysis confirmed that the typical refractory organic matters decreased significantly after UFBRs pre-treatment. High-throughput sequencing analysis using 16S rRNA demonstrated that dominant denitrifiers, fermentative bacteria and refractory-organic-pollutants-degrading bacteria co-existed inside the UFBRs system. Compared with no alkali-pretreated corncobs, alkali-pretreated corncobs provided more porous structure and much stable release of carbon to guarantee the growth and the quantity of the functional bacteria such as denitrifiers. This study indicated that the UFBRs filled with alkali-pretreated corncobs could be utilized as an effective alternative for the enhanced treatment of the BTCW. CI - Copyright (c) 2019 Elsevier Ltd. All rights reserved. FAU - Sun, Guoping AU - Sun G AD - School of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou, China; School of Materials and Chemical Engineering, Zhongyuan University of Technology, Zhengzhou, China. FAU - Wan, Junfeng AU - Wan J AD - School of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou, China; Henan Center for Outstanding Overseas Scientists, Zhengzhou, China. Electronic address: wanjunfeng@zzu.edu.cn. FAU - Sun, Yichen AU - Sun Y AD - School of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou, China. FAU - Li, Haisong AU - Li H AD - School of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou, China. FAU - Chang, Chun AU - Chang C AD - School of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou, China; Henan Center for Outstanding Overseas Scientists, Zhengzhou, China. FAU - Wang, Yan AU - Wang Y AD - School of Chemical Engineering and Energy, Zhengzhou University, Zhengzhou, China. LA - eng PT - Journal Article DEP - 20190805 PL - England TA - Chemosphere JT - Chemosphere JID - 0320657 RN - 0 (Coke) RN - 0 (Environmental Pollutants) RN - 0 (Nitrates) RN - 0 (RNA, Ribosomal, 16S) RN - 0 (Waste Water) RN - 0 (Water Pollutants, Chemical) RN - 7440-44-0 (Carbon) SB - IM MH - *Biodegradation, Environmental MH - Biofilms MH - Bioreactors MH - Carbon MH - Coke/*analysis MH - Environmental Pollutants MH - Nitrates/*analysis/metabolism MH - RNA, Ribosomal, 16S MH - Recycling MH - Waste Disposal, Fluid/*methods MH - Wastewater/*chemistry MH - Water Pollutants, Chemical/*analysis/metabolism MH - Zea mays OTO - NOTNLM OT - Bio-treated coking wastewater (BTCW) OT - Corncobs OT - Refractory organic pollutants OT - Up-flow fixed-bed bioreactor (UFBR) EDAT- 2019/08/14 06:00 MHDA- 2019/12/18 06:00 CRDT- 2019/08/13 06:00 PHST- 2019/05/24 00:00 [received] PHST- 2019/07/31 00:00 [revised] PHST- 2019/08/04 00:00 [accepted] PHST- 2019/08/14 06:00 [pubmed] PHST- 2019/12/18 06:00 [medline] PHST- 2019/08/13 06:00 [entrez] AID - S0045-6535(19)31744-8 [pii] AID - 10.1016/j.chemosphere.2019.124520 [doi] PST - ppublish SO - Chemosphere. 2019 Dec;237:124520. doi: 10.1016/j.chemosphere.2019.124520. Epub 2019 Aug 5.