PMID- 31409001 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20200930 IS - 2079-4991 (Print) IS - 2079-4991 (Electronic) IS - 2079-4991 (Linking) VI - 9 IP - 8 DP - 2019 Aug 12 TI - Improvement of the Bias Stress Stability in 2D MoS(2) and WS(2) Transistors with a TiO(2) Interfacial Layer. LID - 10.3390/nano9081155 [doi] LID - 1155 AB - The fermi-level pinning phenomenon, which occurs at the metal-semiconductor interface, not only obstructs the achievement of high-performance field effect transistors (FETs) but also results in poor long-term stability. This paper reports on the improvement in gate-bias stress stability in two-dimensional (2D) transition metal dichalcogenide (TMD) FETs with a titanium dioxide (TiO(2)) interfacial layer inserted between the 2D TMDs (MoS(2) or WS(2)) and metal electrodes. Compared to the control MoS(2), the device without the TiO(2) layer, the TiO(2) interfacial layer deposited on 2D TMDs could lead to more effective carrier modulation by simply changing the contact metal, thereby improving the performance of the Schottky-barrier-modulated FET device. The TiO(2) layer could also suppress the Fermi-level pinning phenomenon usually fixed to the metal-semiconductor interface, resulting in an improvement in transistor performance. Especially, the introduction of the TiO(2) layer contributed to achieving stable device performance. Threshold voltage variation of MoS(2) and WS(2) FETs with the TiO(2) interfacial layer was ~2 V and ~3.6 V, respectively. The theoretical result of the density function theory validated that mid-gap energy states created within the bandgap of 2D MoS(2) can cause a doping effect. The simple approach of introducing a thin interfacial oxide layer offers a promising way toward the implementation of high-performance 2D TMD-based logic circuits. FAU - Park, Woojin AU - Park W AD - Department of Advanced Material Engineering, Chungbuk National University, Chungdae-ro 1, Seowon-Gu, Cheongju, Chungbuk 28644, Korea. FAU - Pak, Yusin AU - Pak Y AUID- ORCID: 0000-0002-5444-6513 AD - Department of Nanobio Materials and Electronics, GIST, 123 Cheomdan-gwagiro, Buk-gu, Gwangju 61005, Korea. FAU - Jang, Hye Yeon AU - Jang HY AD - Department of Advanced Material Engineering, Chungbuk National University, Chungdae-ro 1, Seowon-Gu, Cheongju, Chungbuk 28644, Korea. FAU - Nam, Jae Hyeon AU - Nam JH AD - Department of Advanced Material Engineering, Chungbuk National University, Chungdae-ro 1, Seowon-Gu, Cheongju, Chungbuk 28644, Korea. FAU - Kim, Tae Hyeon AU - Kim TH AD - Department of Advanced Material Engineering, Chungbuk National University, Chungdae-ro 1, Seowon-Gu, Cheongju, Chungbuk 28644, Korea. FAU - Oh, Seyoung AU - Oh S AD - Department of Advanced Material Engineering, Chungbuk National University, Chungdae-ro 1, Seowon-Gu, Cheongju, Chungbuk 28644, Korea. FAU - Choi, Sung Mook AU - Choi SM AD - Materials Center for Energy Department, Surface Technology Division, Korea Institute of Materials Science (KIMS), 797 Changwondaero, Sungsan-gu, Changwon, Gyeongnam 51508, Korea. FAU - Kim, Yonghun AU - Kim Y AD - Materials Center for Energy Department, Surface Technology Division, Korea Institute of Materials Science (KIMS), 797 Changwondaero, Sungsan-gu, Changwon, Gyeongnam 51508, Korea. FAU - Cho, Byungjin AU - Cho B AUID- ORCID: 0000-0002-3885-8139 AD - Department of Advanced Material Engineering, Chungbuk National University, Chungdae-ro 1, Seowon-Gu, Cheongju, Chungbuk 28644, Korea. bjcho@chungbuk.ac.kr. LA - eng PT - Journal Article DEP - 20190812 PL - Switzerland TA - Nanomaterials (Basel) JT - Nanomaterials (Basel, Switzerland) JID - 101610216 PMC - PMC6724147 OTO - NOTNLM OT - MoS2 OT - WS2 OT - bias stress stability OT - contact resistance OT - interfacial layer COIS- The authors declare no conflict of interest. EDAT- 2019/08/15 06:00 MHDA- 2019/08/15 06:01 PMCR- 2019/08/12 CRDT- 2019/08/15 06:00 PHST- 2019/07/11 00:00 [received] PHST- 2019/08/01 00:00 [revised] PHST- 2019/08/08 00:00 [accepted] PHST- 2019/08/15 06:00 [entrez] PHST- 2019/08/15 06:00 [pubmed] PHST- 2019/08/15 06:01 [medline] PHST- 2019/08/12 00:00 [pmc-release] AID - nano9081155 [pii] AID - nanomaterials-09-01155 [pii] AID - 10.3390/nano9081155 [doi] PST - epublish SO - Nanomaterials (Basel). 2019 Aug 12;9(8):1155. doi: 10.3390/nano9081155.