PMID- 31421553
OWN - NLM
STAT- PubMed-not-MEDLINE
DCOM- 20200302
LR  - 20200302
IS  - 1873-3336 (Electronic)
IS  - 0304-3894 (Linking)
VI  - 381
DP  - 2020 Jan 5
TI  - A novel catalytic oxidation process for removing elemental mercury by using 
      diperiodatoargentate(III) in the catalysis of trace ruthenium(III).
PG  - 120964
LID - S0304-3894(19)30918-5 [pii]
LID - 10.1016/j.jhazmat.2019.120964 [doi]
AB  - A series of experiments were conducted at a bench scale reactor to investigate 
      the effects of key influencing factors on the Hg(0) removal from flue gas using 
      the prepared diperiodatoargentate (III) (DPA) as an oxidant, trace ruthenium(III) 
      as a catalyst, respectively. The experimental results showed that the average 
      Hg(0) removal efficiency reached to 87.5% under the optimal conditions in which 
      the DPA concentration was 1.03 mmol/L, catalyst concentration was 2.0 mumol/L, 
      reaction temperature was 40  degrees C and solution pH was 8.5. Meanwhile, it was found 
      from the experiments that the high concentrations of SO(2) and NO could inhibit 
      the Hg(0) removal due to the competition between Hg(0) and SO(2)/NO, while the 
      lower NO concentration exhibited a slight promotion for Hg(0) removal. The 
      evolutions of DPA(III) and Ru(III) before and after the reaction were 
      characterized by an ultraviolet visible spectrophotometer (UV-vis), from which, 
      the promotional mechanism of Ru(III) on Hg(0) removal was analyzed. The spent 
      solution was analyzed by a cold vapor atomic fluorescence spectrometer (CVAFS), 
      which verified that Hg(0) was oxidized into Hg(2+) by the catalytic system of 
      DPA(III)-Ru(III), and DPA was converted into Ag(+).
CI  - Copyright (c) 2019 Elsevier B.V. All rights reserved.
FAU - Zhao, Yi
AU  - Zhao Y
AD  - MOE Key Laboratory of Resources and Environmental System Optimization, College of 
      Environmental Science & Engineering, North China Electric Power University, 
      Beijing, 102206, PR China; Hebei Key Lab of Power Plant Flue Gas Multi-Pollutants 
      Control, Department of Environmental Science and Engineering, North China 
      Electric Power University, Baoding, 071003, PR China. Electronic address: 
      zhaoyi9515@163.com.
FAU - Qi, Meng
AU  - Qi M
AD  - MOE Key Laboratory of Resources and Environmental System Optimization, College of 
      Environmental Science & Engineering, North China Electric Power University, 
      Beijing, 102206, PR China; Hebei Key Lab of Power Plant Flue Gas Multi-Pollutants 
      Control, Department of Environmental Science and Engineering, North China 
      Electric Power University, Baoding, 071003, PR China.
FAU - Hao, Runlong
AU  - Hao R
AD  - MOE Key Laboratory of Resources and Environmental System Optimization, College of 
      Environmental Science & Engineering, North China Electric Power University, 
      Beijing, 102206, PR China; Hebei Key Lab of Power Plant Flue Gas Multi-Pollutants 
      Control, Department of Environmental Science and Engineering, North China 
      Electric Power University, Baoding, 071003, PR China.
FAU - Jiang, Jiajun
AU  - Jiang J
AD  - MOE Key Laboratory of Resources and Environmental System Optimization, College of 
      Environmental Science & Engineering, North China Electric Power University, 
      Beijing, 102206, PR China; Hebei Key Lab of Power Plant Flue Gas Multi-Pollutants 
      Control, Department of Environmental Science and Engineering, North China 
      Electric Power University, Baoding, 071003, PR China.
FAU - Yuan, Bo
AU  - Yuan B
AD  - MOE Key Laboratory of Resources and Environmental System Optimization, College of 
      Environmental Science & Engineering, North China Electric Power University, 
      Beijing, 102206, PR China; Hebei Key Lab of Power Plant Flue Gas Multi-Pollutants 
      Control, Department of Environmental Science and Engineering, North China 
      Electric Power University, Baoding, 071003, PR China.
LA  - eng
PT  - Journal Article
PT  - Research Support, Non-U.S. Gov't
DEP - 20190805
PL  - Netherlands
TA  - J Hazard Mater
JT  - Journal of hazardous materials
JID - 9422688
SB  - IM
OTO - NOTNLM
OT  - Catalytic oxidation
OT  - Diperiodatoargentate(III)
OT  - Hg(0) removal
OT  - Ruthenium(III)
EDAT- 2019/08/20 06:00
MHDA- 2019/08/20 06:01
CRDT- 2019/08/18 06:00
PHST- 2019/04/28 00:00 [received]
PHST- 2019/07/20 00:00 [revised]
PHST- 2019/08/02 00:00 [accepted]
PHST- 2019/08/20 06:00 [pubmed]
PHST- 2019/08/20 06:01 [medline]
PHST- 2019/08/18 06:00 [entrez]
AID - S0304-3894(19)30918-5 [pii]
AID - 10.1016/j.jhazmat.2019.120964 [doi]
PST - ppublish
SO  - J Hazard Mater. 2020 Jan 5;381:120964. doi: 10.1016/j.jhazmat.2019.120964. Epub 
      2019 Aug 5.