PMID- 31426197 OWN - NLM STAT- MEDLINE DCOM- 20191203 LR - 20191203 IS - 1879-3363 (Electronic) IS - 0025-326X (Linking) VI - 146 DP - 2019 Sep TI - Application of molecular imprinting polymer anchored on CdTe quantum dots for the detection of sulfadiazine in seawater. PG - 591-597 LID - S0025-326X(19)30541-7 [pii] LID - 10.1016/j.marpolbul.2019.07.010 [doi] AB - A molecularly imprinted polymer (MIP) anchored on the surface of CdTe quantum dots (QDs) was fabricated and used as a fluorescent probe for sulfadiazine (SDZ) detection in seawater. CdTe QDs was used as photoluminescent material, SDZ as the template, 3-aminopropyltriethoxysilane (APTES) as the functional monomer and tetraethyl orthosilicate (TEOS) as the cross-linking agent. Characterizations of MIP-QDs were analyzed by Fourier transform infrared (FT-IR), Transmission electron microscopy (TEM) and Scanning electron microscope (SEM). The conditions were optimized for the detection of MIP-QDs to SDZ. The mechanism of fluorescence quenching was studied by UV-Vis absorption spectroscopy and fluorescence spectroscopy. Under optimal conditions, the fluorescence intensity of MIP-QDs decreased linearly between 4- and 20 muM SDZ with a good correlation coefficient of 0.995. The limit of detection is 0.67 muM and the recovery is between 91.8 and 109.4% with RSD lower than 3.9%. These results indicated that MIP-QDs for SDZ detection in seawater was developed successfully. CI - Copyright (c) 2019 Elsevier Ltd. All rights reserved. FAU - Shi, Tian AU - Shi T AD - Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, Ocean University of China, Qingdao 266100, China. FAU - Tan, Liju AU - Tan L AD - College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100, China. Electronic address: lijutan@ouc.edu.cn. FAU - Fu, Hailu AU - Fu H AD - College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100, China. FAU - Wang, Jiangtao AU - Wang J AD - Key Laboratory of Marine Chemistry Theory and Technology, Ministry of Education, Ocean University of China, Qingdao 266100, China; College of Chemistry and Chemical Engineering, Ocean University of China, Qingdao 266100, China. Electronic address: jtwang@ouc.edu.cn. LA - eng PT - Journal Article DEP - 20190713 PL - England TA - Mar Pollut Bull JT - Marine pollution bulletin JID - 0260231 RN - 0 (Anti-Bacterial Agents) RN - 0 (Cadmium Compounds) RN - 0 (Fluorescent Dyes) RN - 0 (Polymers) RN - 0 (Propylamines) RN - 0 (Silanes) RN - 0 (Water Pollutants, Chemical) RN - 0N7609K889 (Sulfadiazine) RN - 42064KRE49 (tetraethoxysilane) RN - L8S6UBW552 (amino-propyl-triethoxysilane) RN - NQA0O090ZJ (Tellurium) RN - STG188WO13 (cadmium telluride) SB - IM MH - Anti-Bacterial Agents/analysis MH - Cadmium Compounds/*chemistry MH - Fluorescent Dyes/chemistry MH - Limit of Detection MH - Microscopy, Electron, Transmission MH - Molecular Imprinting/methods MH - Polymers/chemical synthesis/chemistry MH - Propylamines/chemistry MH - Quantum Dots/*chemistry MH - Seawater/*analysis MH - Silanes/chemistry MH - Spectrometry, Fluorescence MH - Spectrophotometry, Ultraviolet MH - Spectroscopy, Fourier Transform Infrared MH - Sulfadiazine/*analysis MH - Tellurium/*chemistry MH - Water Pollutants, Chemical/*analysis OTO - NOTNLM OT - Antibiotic residue OT - Fluorescent probe OT - MIP-QDs OT - Seawater OT - Sulfadiazine EDAT- 2019/08/21 06:00 MHDA- 2019/12/04 06:00 CRDT- 2019/08/21 06:00 PHST- 2019/05/10 00:00 [received] PHST- 2019/07/04 00:00 [revised] PHST- 2019/07/04 00:00 [accepted] PHST- 2019/08/21 06:00 [pubmed] PHST- 2019/12/04 06:00 [medline] PHST- 2019/08/21 06:00 [entrez] AID - S0025-326X(19)30541-7 [pii] AID - 10.1016/j.marpolbul.2019.07.010 [doi] PST - ppublish SO - Mar Pollut Bull. 2019 Sep;146:591-597. doi: 10.1016/j.marpolbul.2019.07.010. Epub 2019 Jul 13.