PMID- 31450445
OWN - NLM
STAT- MEDLINE
DCOM- 20200203
LR  - 20200203
IS  - 1873-3573 (Electronic)
IS  - 0039-9140 (Linking)
VI  - 205
DP  - 2019 Dec 1
TI  - Electrospun acrylonitrile butadiene styrene nanofiber film as an efficient 
      nanosorbent for head space thin film microextraction of polycyclic aromatic 
      hydrocarbons from water and urine samples.
PG  - 120080
LID - S0039-9140(19)30705-2 [pii]
LID - 10.1016/j.talanta.2019.06.080 [doi]
AB  - In the present study, acrylonitrile butadiene styrene (ABS) nanofiber film was 
      fabricated on the aluminum foil via a one-step and facile electrospinning 
      strategy. Thereafter, the fabricated film was utilized as a novel and efficient 
      nanosorbent for headspace thin film microextraction (HS-TFME) of polycyclic 
      aromatic hydrocarbons (PAHs). Some properties of the prepared nanofiber film like 
      morphology, chemical structure, stability, wettability, and extraction efficiency 
      were investigated systematically. The fabricated nanofiber films showed a large 
      ratio of surface to volume, high stability, good hydrophobicity and porous 
      fibrous structure; hence an excellent extraction performance has been achieved. 
      The pi-pi and hydrophobic interactions play crucial roles in the tendency of PAHs 
      towards fabricated nanosorbent. The effective parameters on the adsorption 
      performance of the developed headspace thin film microextraction-gas 
      chromatography-mass spectroscopy (HS-TFME-GC-MS) method were optimized. At the 
      optimized conditions of the proposed method, a broad linearity range with high 
      coefficient of determination (R(2)>/=0.998) was obtained and the limit of 
      detections (LODs) were in the range of 0.08-0.2 ng mL(-1) for six PAHs. The 
      developed HS-TFME-GC-MS method has been applied for the measurement of PAHs in 
      drinking and industrial water samples and urine samples of a smoker and also a 
      non-smoker with satisfactory recoveries in the range of 83-98%, with relative 
      standard deviations (RSDs) lower than 8.8%. The proposed HS-TFME-GC-MS method 
      demonstrated to be a sensitive, efficient, uncomplicated, cost-effective and 
      rapid approach, which can be introduced to analyze trace amounts of PAHs in 
      various samples.
CI  - Copyright (c) 2019 Elsevier B.V. All rights reserved.
FAU - Moradi, Ebrahim
AU  - Moradi E
AD  - Department of Chemistry and Pollutants, Shahid Beheshti University, G.C., Evin, 
      P.O. Box 1983969411, Tehran, Iran.
FAU - Ebrahimzadeh, Homeira
AU  - Ebrahimzadeh H
AD  - Department of Chemistry and Pollutants, Shahid Beheshti University, G.C., Evin, 
      P.O. Box 1983969411, Tehran, Iran. Electronic address: h-ebrahim@sbu.ac.ir.
FAU - Mehrani, Zahra
AU  - Mehrani Z
AD  - Department of Chemistry and Pollutants, Shahid Beheshti University, G.C., Evin, 
      P.O. Box 1983969411, Tehran, Iran.
LA  - eng
PT  - Journal Article
DEP - 20190622
PL  - Netherlands
TA  - Talanta
JT  - Talanta
JID - 2984816R
RN  - 0 (Butadienes)
RN  - 0 (Polycyclic Aromatic Hydrocarbons)
RN  - 0 (Water Pollutants, Chemical)
RN  - 44LJ2U959V (Styrene)
RN  - MP1U0D42PE (Acrylonitrile)
SB  - IM
MH  - Acrylonitrile/chemistry
MH  - Butadienes/chemistry
MH  - Gas Chromatography-Mass Spectrometry
MH  - Humans
MH  - Hydrophobic and Hydrophilic Interactions
MH  - Limit of Detection
MH  - Nanofibers/*chemistry
MH  - Nanotechnology/methods
MH  - Polycyclic Aromatic Hydrocarbons/analysis/*isolation & purification/urine
MH  - Reproducibility of Results
MH  - Solid Phase Microextraction/*instrumentation/methods
MH  - Styrene/chemistry
MH  - Water Pollutants, Chemical/analysis/isolation & purification
OTO - NOTNLM
OT  - Acrylonitrile butadiene styrene nanofiber
OT  - Adsorption
OT  - Electrospinning
OT  - Head space thin film microextraction
OT  - Polycyclic aromatic hydrocarbons
EDAT- 2019/08/28 06:00
MHDA- 2020/02/06 06:00
CRDT- 2019/08/28 06:00
PHST- 2019/03/07 00:00 [received]
PHST- 2019/06/18 00:00 [revised]
PHST- 2019/06/20 00:00 [accepted]
PHST- 2019/08/28 06:00 [entrez]
PHST- 2019/08/28 06:00 [pubmed]
PHST- 2020/02/06 06:00 [medline]
AID - S0039-9140(19)30705-2 [pii]
AID - 10.1016/j.talanta.2019.06.080 [doi]
PST - ppublish
SO  - Talanta. 2019 Dec 1;205:120080. doi: 10.1016/j.talanta.2019.06.080. Epub 2019 Jun 
      22.