PMID- 31460217
OWN - NLM
STAT- PubMed-not-MEDLINE
LR  - 20231013
IS  - 2470-1343 (Electronic)
IS  - 2470-1343 (Linking)
VI  - 4
IP  - 6
DP  - 2019 Jun 30
TI  - Effect of the Ratio of Acetylacetate Groups on the Properties of a Novel 
      Plant-Based Dual-Cure Coating System.
PG  - 11173-11179
LID - 10.1021/acsomega.9b01234 [doi]
AB  - A novel plant-based dual-cure coating system based on a Michael addition reaction 
      between bismaleimide (BDM) and modified acetoacetylated castor oil was developed. 
      The BDM has a high reactivity toward acetylacetate groups, and the catalyst 
      1,4-diazabicyclo[2.2.2]octane (TEDA) was optimized by the rheological viscosity. 
      The gel was characterized by Fourier transform infrared (FTIR) spectroscopy. 
      Then, three films were prepared with the TEDA catalyst and analyzed with 
      solid-state (13)C NMR and FTIR spectroscopy. The thermal and mechanical 
      properties of the three films were characterized by differential mechanical 
      analysis, thermogravimetric analysis, and differential scanning calorimetry. We 
      found that the cross-linking density, glass transition temperature (T (g)), and 
      Young's modulus of the coating films increased with an increase in the ratio of 
      acetylacetate groups from the modified acetoacetylated castor oil. This is the 
      first study of the reaction of BDM with plant-based acetylacetate groups. 
      Importantly, a quantitative ratio of acetylacetate groups can be obtained by a 
      thiol-ene coupling reaction and a transesterification reaction, resulting in the 
      formation of films having excellent performance.
FAU - Xu, Dongdong
AU  - Xu D
AD  - Jiangxi Engineering Laboratory of Waterborne Coating, School of Chemistry and 
      Chemical Engineering, Jiangxi Science & Technology Normal University, Nanchang 
      330013, Jiangxi, P. R. China.
FAU - Cao, Zhiyuan
AU  - Cao Z
AD  - Jiangxi Engineering Laboratory of Waterborne Coating, School of Chemistry and 
      Chemical Engineering, Jiangxi Science & Technology Normal University, Nanchang 
      330013, Jiangxi, P. R. China.
FAU - Wang, Tong
AU  - Wang T
AD  - Jiangxi Engineering Laboratory of Waterborne Coating, School of Chemistry and 
      Chemical Engineering, Jiangxi Science & Technology Normal University, Nanchang 
      330013, Jiangxi, P. R. China.
FAU - Zhao, Jinze
AU  - Zhao J
AD  - Jiangxi Engineering Laboratory of Waterborne Coating, School of Chemistry and 
      Chemical Engineering, Jiangxi Science & Technology Normal University, Nanchang 
      330013, Jiangxi, P. R. China.
FAU - Zhong, Jiang
AU  - Zhong J
AD  - Jiangxi Engineering Laboratory of Waterborne Coating, School of Chemistry and 
      Chemical Engineering, Jiangxi Science & Technology Normal University, Nanchang 
      330013, Jiangxi, P. R. China.
FAU - Xiong, Peng
AU  - Xiong P
AD  - Jiangxi Engineering Laboratory of Waterborne Coating, School of Chemistry and 
      Chemical Engineering, Jiangxi Science & Technology Normal University, Nanchang 
      330013, Jiangxi, P. R. China.
FAU - Wang, Jiahui
AU  - Wang J
AD  - Jiangxi Engineering Laboratory of Waterborne Coating, School of Chemistry and 
      Chemical Engineering, Jiangxi Science & Technology Normal University, Nanchang 
      330013, Jiangxi, P. R. China.
FAU - Gao, Fei
AU  - Gao F
AD  - Jiangxi Engineering Laboratory of Waterborne Coating, School of Chemistry and 
      Chemical Engineering, Jiangxi Science & Technology Normal University, Nanchang 
      330013, Jiangxi, P. R. China.
FAU - Shen, Liang
AU  - Shen L
AD  - Jiangxi Engineering Laboratory of Waterborne Coating, School of Chemistry and 
      Chemical Engineering, Jiangxi Science & Technology Normal University, Nanchang 
      330013, Jiangxi, P. R. China.
LA  - eng
PT  - Journal Article
DEP - 20190626
PL  - United States
TA  - ACS Omega
JT  - ACS omega
JID - 101691658
PMC - PMC6648321
COIS- The authors declare no competing financial interest.
EDAT- 2019/08/29 06:00
MHDA- 2019/08/29 06:01
PMCR- 2019/06/26
CRDT- 2019/08/29 06:00
PHST- 2019/04/30 00:00 [received]
PHST- 2019/06/14 00:00 [accepted]
PHST- 2019/08/29 06:00 [entrez]
PHST- 2019/08/29 06:00 [pubmed]
PHST- 2019/08/29 06:01 [medline]
PHST- 2019/06/26 00:00 [pmc-release]
AID - 10.1021/acsomega.9b01234 [doi]
PST - epublish
SO  - ACS Omega. 2019 Jun 26;4(6):11173-11179. doi: 10.1021/acsomega.9b01234. 
      eCollection 2019 Jun 30.