PMID- 31473310 OWN - NLM STAT- MEDLINE DCOM- 20200512 LR - 20200512 IS - 1879-0003 (Electronic) IS - 0141-8130 (Linking) VI - 141 DP - 2019 Dec 1 TI - Development and characterization of a hydroxypropyl starch/zein bilayer edible film. PG - 1175-1182 LID - S0141-8130(19)31970-1 [pii] LID - 10.1016/j.ijbiomac.2019.08.240 [doi] AB - An edible hydroxypropyl starch (HPS) based bilayer film with a waterproof layer of zein was successfully prepared through a two-step solvent casting method. The morphology, mechanical properties, as well as water barrier properties of the bilayer film were systematically studied. Results showed that bilayer film presented smooth surface morphology with an improved visibility, and there was an adhesion interface between two layers. Water resistance and UV barrier property, as well as mechanical property, were significantly improved. In addition, the interactions between starch and zein through hydrogen bonding were analyzed by Fourier-transform infrared spectroscopy (FTIR) and molecular dynamics (MD) simulation. In MD simulation, the relative trajectories were dynamically presented. Conjunction of starch and zein through hydrogen bonding among the hydroxyl and amino (carboxyl) groups was identified, and stronger affinity with starch mainly rooted from asparagine (ASN) and tyrosine (TYR) residues. CI - Copyright (c) 2019 Elsevier B.V. All rights reserved. FAU - Chen, Xia AU - Chen X AD - School of Food Science and Engineering, South China University of Technology, Guangzhou, China; Guangdong Provincial Key Laboratory of Nutraceuticals and Functional Foods, College of Food Science, South China Agricultural University, Guangzhou, Guangdong, China. FAU - Cui, Feihe AU - Cui F AD - School of Food Science and Engineering, South China University of Technology, Guangzhou, China. FAU - Zi, Hua AU - Zi H AD - School of Food Science and Engineering, South China University of Technology, Guangzhou, China. FAU - Zhou, Yichen AU - Zhou Y AD - School of Food Science and Engineering, South China University of Technology, Guangzhou, China. FAU - Liu, Hongsheng AU - Liu H AD - School of Food Science and Engineering, South China University of Technology, Guangzhou, China; Overseas Expertise Introduction Center for Discipline Innovation of Food Nutrition and Human Health, Guangzhou, China; Sino-Singapore International Joint Research Institute, Guangzhou Knowledge City, China. Electronic address: liuhongsheng@scut.edu.cn. FAU - Xiao, Jie AU - Xiao J AD - Guangdong Provincial Key Laboratory of Nutraceuticals and Functional Foods, College of Food Science, South China Agricultural University, Guangzhou, Guangdong, China. Electronic address: xiaojieacademic@scau.edu.cn. LA - eng PT - Journal Article DEP - 20190829 PL - Netherlands TA - Int J Biol Macromol JT - International journal of biological macromolecules JID - 7909578 RN - 059QF0KO0R (Water) RN - 9005-25-8 (Starch) RN - 9010-66-6 (Zein) SB - IM MH - *Edible Films MH - Hydrogen Bonding MH - Molecular Dynamics Simulation MH - Optical Phenomena MH - Permeability MH - Starch/*chemistry MH - Surface Properties MH - Water/chemistry MH - Zein/*chemistry OTO - NOTNLM OT - Barrier property OT - Bilayer film OT - HPS OT - MD simulation OT - Zein EDAT- 2019/09/02 06:00 MHDA- 2020/05/13 06:00 CRDT- 2019/09/02 06:00 PHST- 2019/03/17 00:00 [received] PHST- 2019/08/22 00:00 [revised] PHST- 2019/08/28 00:00 [accepted] PHST- 2019/09/02 06:00 [pubmed] PHST- 2020/05/13 06:00 [medline] PHST- 2019/09/02 06:00 [entrez] AID - S0141-8130(19)31970-1 [pii] AID - 10.1016/j.ijbiomac.2019.08.240 [doi] PST - ppublish SO - Int J Biol Macromol. 2019 Dec 1;141:1175-1182. doi: 10.1016/j.ijbiomac.2019.08.240. Epub 2019 Aug 29.