PMID- 31489944 OWN - NLM STAT- PubMed-not-MEDLINE LR - 20201001 IS - 2073-4360 (Electronic) IS - 2073-4360 (Linking) VI - 11 IP - 9 DP - 2019 Sep 6 TI - Recycling of Polypropylene/Polyethylene Blends: Effect of Chain Structure on the Crystallization Behaviors. LID - 10.3390/polym11091456 [doi] LID - 1456 AB - The combination of high-density polyethylene (HDPE), low-density polyethylene (LDPE) and polypropylene (PP) is frequently found in polymer waste streams. Because of their similar density, they cannot be easily separated from each other in the recycling stream. Blending of PP/ polyethylenes (PEs) in different ratios possibly eliminate the sorting process used in the regular recycling process. PP has fascinating properties such as excellent processability and chemical resistance. However, insufficient flexibility limits its use for specific applications. Blending of PP with relative flexible PEs might improve its flexibility. This is a unique approach for recycling or upcycling, which aims to maintain or improve the properties of recycled materials. The effects of the branched-chain structures of PEs on the crystallization behavior and the related mechanical properties of such blends were investigated. The overall kinetics of crystallization of PP was significantly influenced by the presence of PEs with different branched-chain structures. The presence of LDPE was found to decrease the overall crystallization rate while the addition of HDPE accelerated the crystallization process of the blends. No negative effect on the mechanical performance and the related crystallinity was observed within the studied parameter range. FAU - Aumnate, Chuanchom AU - Aumnate C AUID- ORCID: 0000-0003-4377-333X AD - Metallurgy and Material Sciences Research Institute, Chulalongkorn University, Bangkok 10330, Thailand. Chuanchom.a@chula.ac.th. FAU - Rudolph, Natalie AU - Rudolph N AD - AREVO, Inc., Milpitas, CA 95035, USA. FAU - Sarmadi, Majid AU - Sarmadi M AD - Textile Science, Department of Design Studies and Materials Science Graduate Program, University of Wisconsin-Madison, Madison, WI 53706, USA. LA - eng PT - Journal Article DEP - 20190906 PL - Switzerland TA - Polymers (Basel) JT - Polymers JID - 101545357 PMC - PMC6780393 OTO - NOTNLM OT - crystal structure OT - crystallization OT - kinetics OT - polymer blends and alloys OT - recycling COIS- The authors declare no conflict of interest. EDAT- 2019/09/07 06:00 MHDA- 2019/09/07 06:01 PMCR- 2019/09/06 CRDT- 2019/09/07 06:00 PHST- 2019/08/17 00:00 [received] PHST- 2019/09/04 00:00 [revised] PHST- 2019/09/05 00:00 [accepted] PHST- 2019/09/07 06:00 [entrez] PHST- 2019/09/07 06:00 [pubmed] PHST- 2019/09/07 06:01 [medline] PHST- 2019/09/06 00:00 [pmc-release] AID - polym11091456 [pii] AID - polymers-11-01456 [pii] AID - 10.3390/polym11091456 [doi] PST - epublish SO - Polymers (Basel). 2019 Sep 6;11(9):1456. doi: 10.3390/polym11091456.